Quasi-equilibrium analysis of the reaction of atomic and molecular fluorine with tungsten.
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Engineering topics
Publications and source records attributed to Stickney, R. E..
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Current analytical and experimental investigations of the influence of surface processes on the rate of permeation of gases through solids are summarized. A brief description is presented of an analytical model that provides an approximate prediction of the dependence of the permeation rate on the rates of surface processes relative to the rate of the diffusion process. Results of experiments indicate that the desorption process of hydrogen from various materials is influenced by surface impurities to the degree that substantial changes in the spatial distribution of the desorbed molecules are observed when the impurities are varied. Except possibly for H-Nb, the permeation measurements indicate that the desorption process is not influenced to the degree that detectable changes in the permeation rates are observed when the impurities and temperatures are varied. On the basis of analysis, it is unlikely that the desorption process will be the rate-controlling step under the conditions of the present experiments.
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A quasi-equilibrium model which provides semiquantitative predictions of the oxygen reaction with refractory metals was developed at high temperature and low pressure. Extensive experimental data was obtained on adsorption and work function properties for a wide variety of adsorbates (Cs, K, Na, I, Br, Cl, and O) on several refractory metals (W, Ta, Mo, and Re). Conclusions and recommendations for research on alkali metal adsorption, oxygen adsorption, and adsorption of cesium - oxygen mixtures are included.
Quasi-equilibrium prediction of rate of volatilization /erosion/ of solid tungsten by reaction with gaseous oxygen at high temperature and low pressure
Pumping effect in oxygen reaction with hot tungsten cathode, and spectrometic measurements of formation energies for volatile species in gas-solid chemical reactions
Contact potential measurements of work function dependence on adsorption of alkali metals on Ta/110/ and W/100/ crystals under ultrahigh vacuum
Critique of paper on electron diffraction study of Ce adsorption on W surface, discussing electron work function changes and data discrepancies
Near-free molecular flow through orifice measured for velocity distribution dependence on Knudsen number and angular position using time-of-flight technique
Quasi-equilibrium treatment of heterogeneous reactions applied to evaporation rate /desorption/ computation for volatile species formed in oxygen reactions with W, Mo and graphite
Quasi-equilibrium treatment of heterogeneous reactions applied to flash desorption data for oxygen reaction with tungsten surface, discussing species desorption dependence on adsorption temperature
Work function measurement for adsorption of diatomic I, Br and Cl on W crystal using electron beam retarding potential method
Thermodynamics and kinetics of sublimation, catalytic, and oxidation reactions
Thermionic properties of tungsten surfaces partially covered with adsorbed cesium atoms
Oxygen adsorption and desorption on single crystal W filament from thermionic emission microscope measurements, discussing gas pressure and filament temperature effects
Adsorption and desorption of oxygen on polycrystalline W, Mo, Ta and Re filaments, using thermionic emission measurements
Work function and desorption energy measurements of alkali metals from metallic substrates with modulated molecular beam, noting surface contamination
Electron beam retarding potential method to measure work function changes resulting from Cs, oxygen and hydrogen adsorption on /110/ Ta single crystal