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Sengers, J. V.

Publications and source records attributed to Sengers, J. V..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Representative equations for the thermodynamic and transport properties of fluids near the gas-liquid critical point

A survey is presented of representative equations for various thermophysical properties of fluids in the critical region. Representative equations for the transport properties are included. Semi-empirical modifications of the theoretically predicted asymtotic critical behavior that yield simple and practical representations of the fluid properties in the critical region are emphasized.

Sengers, J. V.↗
NASA NTRS1980

Toward the use of similarity theory in two-phase choked flows

Comparison of two phase choked flows in normalized coordinates were made between pure components and available data using a reference fluid to compute the thermophysical properties. The results are favorable. Solution of the governing equations for two LNG mixtures show some possible similarities between the normalized choked flows of the two mixtures, but the departures from the pure component loci are significant.

Hendericks, R. C.↗
NASA NTRS1980

Toward the use of similarity theory in two-phase choked flows

Comparison of two-phase choked flows in normalized coordinates were made between pure components and available data using a reference fluid to compute the thermophysical properties. The results are favorable. Solution of the governing equations for two LNG mixtures show some possible similarities between the normalized choked flows of the two mixtures, but the departures from the pure component locii are significant.

Hendricks, R. C.↗
NASA NTRS1979

Application of the principle of similarity fluid mechanics

Possible applications of the principle of similarity to fluid mechanics is described and illustrated. In correlating thermophysical properties of fluids, the similarity principle transcends the traditional corresponding states principle. In fluid mechanics the similarity principle is useful in correlating flow processes that can be modeled adequately with one independent variable (i.e., one-dimensional flows). In this paper we explore the concept of transforming the conservation equations by combining similarity principles for thermophysical properties with those for fluid flow. We illustrate the usefulness of the procedure by applying such a transformation to calculate two phase critical mass flow through a nozzle.

Hendricks, R. C.↗
NASA NTRS1979

Application of the principle of similarity fluid mechanics

The principle of similarity applied to fluid mechanics is described and illustrated. The concept of transforming the conservation equations by combining similarity principles for thermophysical properties with those for fluid flow is examined. The usefulness of the procedure is illustrated by applying such a transformation to calculate two phase critical mass flow through a nozzle.

Hendericks, R. C.↗
NASA NTRS1978

Viscosity of nitrogen near the critical point

The formulation of a quantitative description of the critical enhancement in the shear viscosity of fluids near the gas-liquid critical point is considered. The critical point is a point of marginal thermodynamic stability. In the vicinity of the critical point, large-scale density fluctuations are present in the fluid. The critical enhancement of the transport properties is related to the correlation length. The correlation length is related to the compressibility, thus providing consistency between the equations for the transport properties and the equation of state in the critical region. The critical region parameters for nitrogen are presented in a table. It is found that the critical viscosity enhancement observed by Zozulya and Blagoi (1974) for nitrogen is consistent with current theoretical predictions

Basu, R. S.↗
NASA NTRS1978

Critical phenomena experiments in space

The paper analyzes several types of critical phenomena in fluids, shows how they are affected by the presence of gravity, and describes how experiments conducted in an orbiting laboratory under low gravity conditions could extend the range of measurements needed to study critical phenomena. Future experiments are proposed. One would be a careful measurement of the dielectric constant in a low gravity environment. Two basic problems that can benefit especially from space experiments are the specific heat near the critical point and the shear viscosity at the gas-liquid critical point.

Sengers, J. V.↗
NASA NTRS1978

Two-scale-factor universality near the critical point of fluids

Thermodynamic data from interferometric density profile studies and light-scattering experiments near the critical isochore of Xe, CO2 and SF6 provide a basis for examining the hypothesized two-scale-factor universality for the correlation function of fluids near the gas-liquid critical point. For the investigation, three-scale-factor universality is assumed, with Ising-like critical exponent values obtained through the renormalization group technique. The two thermodynamic scale factors are found from the density profiles, while the scale factor for the correlation length is obtained from the light-scattering data.

Sengers, J. V.↗
NASA NTRS1978

Critical phenomena in a low gravity environment

Various types of critical point phenomena are discussed including the gas-liquid phase transition of a fluid, the spontaneous magnetization of a ferromagnet below the Curie temperature, and structural phase transitions of solid materials. The interrelation of thermodynamic properties by scaling laws is considered noting theories for the validity of scaling laws and the principle of universality. Gravity effects are reviewed noting that in earth-based experiments the phenomena are significantly influenced by the earth's gravitational field and that fluid samples that are spatially homogeneous cannot be realized near the gas-liquid critical point.

Sengers, J. V.↗
NASA NTRS1977

Concepts and methods for describing critical phenomena in fluids

The predictions of theoretical models for a critical-point phase transistion in fluids, namely the classical equation with third-degree critical isotherm, that with fifth-degree critical isotherm, and the lattice gas, are reviewed. The renormalization group theory of critical phenomena and the hypothesis of universality of critical behavior supported by this theory are discussed as well as the nature of gravity effects and how they affect cricital-region experimentation in fluids. The behavior of the thermodynamic properties and the correlation function is formulated in terms of scaling laws. The predictions of these scaling laws and of the hypothesis of universality of critical behavior are compared with experimental data for one-component fluids and it is indicated how the methods can be extended to describe critical phenomena in fluid mixtures.

Sengers, J. V.↗
NASA NTRS1977

Thermal conductivity of steam in the critical region

The thermal conductivity of fluids exhibits an anomalous enhancement in a large range of densities and temperatures around the critical point. We formulate an equation for the thermal conductivity that connects the anomalous behavior in the vicinity of the critical point with the normal behavior of the thermal conductivity away from the critical point. The critical thermal conductivity enhancement is related to the anomalous behavior of the isothermal compressibility which in turn is represented by a scaled equation of state. The method is used to analyze experimental thermal conductivity data in the critical region of steam.

Basu, R. S.↗
NASA NTRS1976

Spacelab experiment definition study on phase transition and critical phenomena in fluids: Interim report on experimental justification

Pure fluids and fluid mixtures near critical points are identified and are related to the progress of several disciplines. Consideration is given to thermodynamic properties, transport properties, and the complex nonlinear phenomena which occur when fluids undergo phase transitions in the critical region. The distinction is made between practical limits which may be extended by advances in technology and intrinsic ones which arise from the modification of fluid properties by the earth's gravitational field. The kinds of experiments near critical points which could best exploit the low gravity environment of an orbiting laboratory are identified. These include studies of the index of refraction, constant volume specific heat, and phase separation.

Moldover, M. R.↗
NASA NTRS1976

On estimating thermal conductivity coefficients in the critical region of gases

The thermal conductivity of a fluid exhibits a pronounced anomalous increase in a large range of densities and temperatures around the gas-liquid critical point. In this paper we discuss an attempt to estimate the thermal conductivity in the critical region of fluids from a knowledge of the equilibrium properties and the regular behavior of the transport properties outside the critical region.

Hanley, H. J. M.↗
NASA NTRS1976

Scaled equation of state parameters for gases in the critical region

In the light of recent theoretical developments, the paper presents an accurate characterization of anomalous thermodynamic behavior of xenon, helium 4, helium 3, carbon dioxide, steam and oxygen in the critical region. This behavior is associated with long range fluctuations in the system and the physical properties depend primarily on a single variable, namely, the correlation length. A description of the thermodynamic behavior of fluids in terms of scaling laws is formulated, and the two successfully used scaled equations of state (NBS equation and Linear Model parametric equation) are compared. Methods for fitting both equations to experimental equation of state data are developed and formulated, and the optimum fit for each of the two scaled equations of the above gases are presented and the results are compared. By extending the experimental data for the above one-component fluids to partially miscible binary liquids, superfluid liquid helium, ferromagnets and solids exhibiting order-disorder transitions, the principle of universality is concluded. Finally by using this principle, the critical regions for nine additional fluids are described.

Sengers, J. M. H. L.↗
NASA NTRS1975

Fluid physics, thermodynamics, and heat transfer experiments in space

An overstudy committee was formed to study and recommend fundamental experiments in fluid physics, thermodynamics, and heat transfer for experimentation in orbit, using the space shuttle system and a space laboratory. The space environment, particularly the low-gravity condition, is an indispensable requirement for all the recommended experiments. The experiments fell broadly into five groups: critical-point thermophysical phenomena, fluid surface dynamics and capillarity, convection at reduced gravity, non-heated multiphase mixtures, and multiphase heat transfer. The Committee attempted to assess the effects of g-jitter and other perturbations of the gravitational field on the conduct of the experiments. A series of ground-based experiments are recommended to define some of the phenomena and to develop reliable instrumentation.

Dodge, F. T.↗
NASA NTRS1974

Viscosity and thermal conductivity coefficients of gaseous and liquid oxygen

Equations and tables are presented for the viscosity and thermal conductivity coefficients of gaseous and liquid oxygen at temperatures between 80 K and 400 K for pressures up to 200 atm. and at temperatures between 80 K and 2000 K for the dilute gas. A description of the anomalous behavior of the thermal conductivity in the critical region is included. The tabulated coefficients are reliable to within about 15% except for a region in the immediate vicinity of the critical point. Some possibilities for future improvements of this reliability are discussed.

Hanley, H. J. M.↗
NASA NTRS1974

Scaled parametric equation of state for oxygen in the critical region

Thermodynamic properties show an anomalous nonanalytic behavior in the critical region that cannot be represented by analytic equations used in engineering correlations. The formulation of scaling laws is discussed, taking into account an approach proposed by Schofield et al. (1969). A procedure for data analysis is described. The model considered has been found to give satisfactory results in tests conducted with a number of gases. The application of the described approach to density profiles is discussed. Attention is given to the model parameters, the critical exponents, and the coefficients for oxygen.

Levelt Sengers, J. M. H.↗