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Segre, Philip N.

Publications and source records attributed to Segre, Philip N..

Origin of Stability in Particle Sedimentation

Particle Image Velocimetry (PIV) is used to study the slow settling motions of spheres in suspensions ranging from dilute to highly concentrated, 0.0001 less than phi less than 0.50. During sedimentation, particle velocity fluctuations are found to be organized into regions of characteristic size xi approximately 11 a phi (exp -1/3). A simple model, based upon buoyant mass fluctuations DELTAm given by random density fluctuations in a region of size xi, accurately predicts the magnitudes of the velocity fluctuations DELTAV. We also find a new universal relation for particle diffusion during sedimentation. It can be written in a Stokes-Einstein form as Dapproximately(DELTAmxi)/(6pietaxi), where the effective temperature DELTAmgxi is the gravitational potential energy of density fluctuations. In addition related experiments examining inertial effects and transient states, that are aimed at uncovering the origin of the new lengthscale xi, will also be given.

Segre, Philip N.↗

Effective Gravitational Temperature in Sedimentation

Particle Image Velocimetry (PIV) is used to study the slow settling motions of spheres in suspensions ranging from dilute to highly concentrated, 0.0001 less than phi less than 0.50. During sedimentation, particle velocity fluctuations are found to be organized into regions of characteristic size xi approx. parallel to (alpha)phi(sup -1/3). A simple model, based upon buoyant mass fluctuations (Delta)m given by random density fluctuations in a region of size xi, accurately predicts the magnitudes of the velocity fluctuations (Delta)V. We also find a new universal relation for particle diffusion during sedimentation. It can be written in a Stokes-Einstein form as D approx. (Delta m g xi)/(6pi eta xi), where the effective temperature Delta m g xi is the gravitational potential energy of density fluctuations. In addition related experiments examining inertial effects and transient states, that are aimed at uncovering the origin of the new length-scale xi, will also be given.

Segre, Philip N.↗

Effective Gravitational Temperature in Sedimentation

Particle Image Velocimetry (PIV) is used to study the slow settling motions of spheres in suspensions ranging from dilute to highly concentrated, 0.05 less than phi less than 0.50. During sedimentation, velocity fluctuations are found to be organized into regions of characteristic size L approximately 11 a phi(exp-1/3) and buoyant mass DELTA m given by the rms density fluctuations in a region of size L(sup 3) assuming random statistics with excluded volume effects. A simple model accurately predicts the magnitudes of the velocity fluctuations DELTA V. Finally, we find a new universal relation for particle diffusion during sedimentation that can be written in a Stokes-Einstein type form as D approximately (DELTA mg L)/(6 pi eta L), where the effective temperature DELTA mg L is the gravitational potential energy of density fluctuations.

Segre, Philip N.↗

Correlations and Gravitational Temperature in Settling Suspensions

Particle Image Velocimetry (PIV) is used to study the slow settling motions of spheres in suspensions ranging from dilute to highly concentrated, 0.05 less than phi less than 0.50. During sedimentation, velocity fluctuations are found to be organized into regions of characteristic size L approximately equal to 11 a phi(exp -1/3) and buoyant mass DELTA m given by the rms density fluctuations in a region of size L(exp 3) assuming random statistics. A simple model incorporating the suspension viscosity and excluded volume effects accurately predicts the magnitudes of the observed velocity fluctuations DELTA V. These lead to a universal relation for particle diffusion that can be written in a Stokes-Einstein type form as D approximately equal to (DELTA m gL)/(6 pi (eta)L).

Segre, Philip N.↗

Glass/Jamming Transition in Colloidal Aggregation

We have studied colloidal aggregation in a model colloid plus polymer system with short-range attractive interactions. By varying the colloid concentration and the strength of the attraction, we explored regions where the equilibrium phase is expected to consist of colloidal crystallites in coexistance with colloidal gas (i.e. monomers). This occurs for moderate values of the potential depth, U approximately equal to 2-5 kT. Crystallization was not always observed. Rather, over an extended sub-region two new metastable phases appear, one fluid-like and one solid-like. These were examined in detail with light scattering and microscopy techniques. Both phases consist of a near uniform distribution of small irregular shaped clusters of colloidal particles. The dynamical and structural characteristics of the ergodic-nonergodic transition between the two phases share much in common with the colloidal hard sphere glass transition.

Segre, Philip N.↗