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Samuelson, R. E.

Publications and source records attributed to Samuelson, R. E..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Titan Surface Temperatures During the Cassini Mission

By the close of the Cassini mission in 2017 the Composite Infrared Spectrometer had recorded surface brightnesstemperatures on Titan for 13 yr (almost half a Titan year). We mapped temperatures in latitude from pole to pole inseven time segments from northern mid-winter to northern summer solstice. At the beginning of the mission thewarmest temperatures were centered at 13 S where they peaked at 93.9 K. Temperatures fell off by about 4 Ktoward the north pole and 2 K toward the south pole. As the seasons progressed the warmest temperatures shiftednorthward, tracking the subsolar point, and at northern summer solstice were centered at 24 N. While moving norththe peak temperature decreased by about 1 K, reaching 92.8 K at solstice. At solstice the fall-off toward the northand south poles were 1 K and 3 K, respectively. Thus the temperature range was the same 2 K at the two poles. Ourobserved surface temperatures agree with recent general circulation model results that take account of methanehydrology and imply that hemispherical differences in Titan's topography may play a role in the north?southasymmetry on Titan.

Jennings, D. E.↗
NASA NTRS2019

Detailed Infrared Study of Amorphous to Crystalline Propionitrile Ices Relevant to Observed Spectra of Titan's Stratospheric Ice Clouds

We have conducted a comprehensive study of propionitrile (C2H5CN) ice from the amorphous to crystalline phase in order to provide detailed information on this specific cyanide, which may potentially contribute to the chemical composition of the Haystack ice cloud observed in Titan's stratosphere by the Cassini Composite InfraRed Spectrometer (CIRS). Infrared transmission spectra of thin films of pure propionitrile ices deposited at low temperature (30-160 K) were collected from 50 cm1 to 11,700 cm1 (200-0.85 m). The far-infrared spectral region was specifically targeted to compare with CIRS far-infrared limb spectra. The temperature and time evolution of C2H5CN ice was thoroughly investigated to better understand discrepancies reported in pre- viously published laboratory studies on the crystalline phase of C2H5CN. Specifically, we observe peculiar temperature and time-driven ice phase transitions, revealed by significant spectral variations in the ice, which stabilizes once a complete crystalline phase is achieved. From these results, the crystalline phase of propionitrile ice was identified at deposition temperatures greater than or equal to 135 K and < 140 K. Our findings corro- borate previous studies that ruled out pure propionitrile ice as the sole chemical identity of Titan's observed Haystack emission feature. In order to understand and identify the Haystack cloud, we have initiated co-de- position experiments that incorporate mixtures of Titan-relevant organics, many of which have corresponding vapors that are abundantly present in Titan's stratosphere. In this paper, we present the result of one example of a co-deposited ternary ice mixture containing 16% hydrogen cyanide (HCN), 23% C2H5CN, and 61% benzene (C6H6). Although this co-condensed ice mixture is the best fit thus far obtained to match the broad width of the Haystack, it is still not the appropriate chemical candidate. However, it reveals an intriguing result: the strong lattice mode of pure C2H5CN ice is drastically altered by the surrounding molecules as a result of mixing in a co- condensed phase. The laboratory results reported here on propionitrile ice may help to further constrain the chemical identification of Titan's stratospheric Haystack ice cloud, as well as improve on the current state of knowledge of Titan's stratospheric ice cloud chemistry.

Nna-Mvondo, Delphine↗
NASA NTRS2018

Organic Ices in Titan's Stratosphere

Titan's stratospheric ice clouds are by far the most complex of any observed in the solar system, with over a dozen organic vapors condensing out to form a suite of pure and co-condensed ices, typically observed at high winter polar latitudes. Once these stratospheric ices are formed, they will diffuse throughout Titan's lower atmosphere and most will eventually precipitate to the surface, where they are expected to contribute to Titan's regolith.

Stratospheric composition↗
NASA NTRS2018

The SPECTRAL Ice Chamber: Application to Titan's Stratospheric Ice Clouds

An ice chamber for obtaining thin-film transmission spectra of Titan-relevant organic ices between 50 and 11,700 cm−1 (200–0.85 μm) is described in detail in this work. The ice chamber, called the SPECtroscopy of Titan-Related ice AnaLogs chamber, is located in the Spectroscopy for Planetary ICes Environments laboratory at NASA Goddard Space Flight Center. Organic vapors are typically deposited between 30 and 150 K via a variable leak valve onto a chemical vapor deposition diamond substrate, where condensation directly into the solid state occurs. Quantitative thin-film infrared transmission spectra of the given ice or ice mixture are then measured, from which optical constants (complex indices of refraction) are computed. These optical constants in turn provide the necessary input for interpreting radiative transfer analyses of Cassini’s Composite InfraRed Spectrometer observations of Titan’s organic stratospheric ice clouds to determine their chemical compositions, abundances, and vertical distributions as functions of Titan latitude and season.

Anderson, C. M.↗
NASA NTRS2016

Solid-State Photochemistry as a Formation Mechanism for Titan's Stratospheric C4N2 Ice Clouds

We propose that C4N2 ice clouds observed in Titan's springtime polar stratosphere arise due to solid-state photochemistry occurring within extant ice cloud particles of HCN-HC3N mixtures. This formation process resembles the halogen-induced ice particle surface chemistry that leads to condensed nitric acid trihydrate (NAT) particles and ozone depletion in Earth's polar stratosphere. As our analysis of the Cassini Composite Infrared Spectrometer 478 per centimeter ice emission feature demonstrates, this solid-state photochemistry mechanism eliminates the need for the relatively high C4N2 saturation vapor pressures required (even though they are not observed) when the ice is produced through the usual procedure of direct condensation from the vapor.

Titan's stratosphere↗
NASA NTRS2016

Surface Temperatures on Titan During Northern Winter and Spring

Meridional brightness temperatures were measured on the surface of Titan during the 2004-2014 portion of the Cassini mission by the Composite Infrared Spectrometer. Temperatures mapped from pole to pole during five two year periods show a marked seasonal dependence. The surface temperature near the south pole over this time decreased by 2 K from 91.7 plus or minus 0.3 to 89.7 plus or minus 0.5 K while at the north pole the temperature increased by 1 K from 90.7 plus or minus 0.5 to 91.5 plus or minus 0.2 K. The latitude of maximum temperature moved from 19 S to 16 N, tracking the subsolar latitude. As the latitude changed, the maximum temperature remained constant at 93.65 plus or minus 0.15 K. In 2010 our temperatures repeated the north-south symmetry seen by Voyager one Titan year earlier in 1980. Early in the mission, temperatures at all latitudes had agreed with GCM predictions, but by 2014 temperatures in the north were lower than modeled by 1 K. The temperature rise in the north may be delayed by cooling of sea surfaces and moist ground brought on by seasonal methane precipitation and evaporation.

Cassini↗
NASA NTRS2012

Titan's Tropopause Temperatures from CIRS: Implications for Stratospheric Methane Cloud Formation

Analysis of Cassini Composite Infrared Spectrometer (CIRS) far-IR spectra enable the construction of Titan's temperature profile in the altitude region containing the tropopause. Whereas the methane V4 band at 1306/cm (7.7 microns) is the primary opacity source for deducing thermal structure between 100 km and 500 km, N2-N2 collision-induced absorption between 70 and 140/cm (143 microns and 71 microns) is utilized to determine temperatures at Titan's tropopause. Additional opacity due to aerosol and nitrile ices must also be taken into account in this part of the far-IR spectral region. The spectral characteristics of these particulate opacities have been deduced from CIRS limb data at 58degS, 15degS, 15degN, and 85degN. Empirically, the spectral shapes of these opacities appear to be independent of both latitude and altitude below 300 km (Anderson and Samuelson, 2011, Icarus 212, 762-778), justifying the extension of these spectral properties to all latitudes. We find that Titan's tropopause temperature is cooler than the HAS! value of 70.5K by approx. 6K. This leads to the possibility that subsidence at high northern latitudes can cause methane condensation in the winter polar stratosphere. A search for methane clouds in this region is in progress.

Anderson, C. M.↗
NASA NTRS2011

Aromatic Structure in Simulates Titan Aerosol

Observations of Titan by the Cassini Composite Infrared Spectrometer (CIRS) between 560 and 20 per centimeter (approximately 18 to 500 micrometers) have been used to infer the vertical variations of Titan's ice abundances, as well as those of the aerosol from the surface to an altitude of 300 km [1]. The aerosol has a broad emission feature centered approximately at 140 per centimeter (71 micrometers). As seen in Figure 1, this feature cannot be reproduced using currently available optical constants from laboratory-generated Titan aerosol analogs [2]. The far-IR is uniquely qualified for investigating low-energy vibrational motions within the lattice structures of COITIDlex aerosol. The feature observed by CIRS is broad, and does not likely arise from individual molecules, but rather is representative of the skeletal movements of macromolecules. Since Cassini's arrival at Titan, benzene (C6H6) has been detected in the atmosphere at ppm levels as well as ions that may be polycyclic aromatic hydrocarbons (PAHs) [3]. We speculate that the feature may be a blended composite that can be identified with low-energy vibrations of two-dimensional lattice structures of large molecules, such as PAHs or nitrogenated aromatics. Such structures do not dominate the composition of analog materials generated from CH4 and N2 irradiation. We are performing studies forming aerosol analog via UV irradiation of aromatic precursors - specifically C6H6 - to understand how the unique chemical architecture of the products will influence the observable aerosol characteristics. The optical and chemical properties of the aromatic analog will be compared to those formed from CH4/N2 mixtures, with a focus on the as-yet unidentified far-IR absorbance feature. Preliminary results indicate that the photochemically-formed aromatic aerosol has distinct chemical composition, and may incorporate nitrogen either into the ring structure or adjoined chemical groups. These compositional differences are demonstrated in the aerosol mass spectra shown in Figure 2. The aromatic aerosol also demonstrates strong chemical reactivity when exposed to laboratory air, indicating substantial stored chemical potential. Oxidatoin and solubility studies wil be presented and implicatoins for prebiotic chemistry o nTitan will be discussed.

Trainer, Melissa G.↗
NASA NTRS2011

Seasonal Changes in Titan's Surface Temperatures

Seasonal changes in Titan's surface brightness temperatures have been observed by Cassini in the thermal infrared. The Composite Infrared Spectrometer (CIRS) measured surface radiances at 19 micron in two time periods: one in late northern winter (Ls = 335d eg) and another centered on northern spring equinox (Ls = 0 deg). In both periods we constructed pole-to-pole maps of zonally averaged brightness temperatures corrected for effects of the atmosphere. Between late northern winter and northern spring equinox a shift occurred in the temperature distribution, characterized by a warming of approximately 0.5 K in the north and a cooling by about the same amount in the south. At equinox the polar surface temperatures were both near 91 K and the equator was 93.4 K. We measured a seasonal lag of delta Ls approximately 9 in the meridional surface temperature distribution, consistent with the post-equinox results of Voyager 1 as well as with predictions from general circulation modeling. A slightly elevated temperature is observed at 65 deg S in the relatively cloud-free zone between the mid-latitude and southern cloud regions.

Jennins, Donald E.↗
NASA NTRS2010

Particle Size and Abundance of HC3N Ice in Titan's Lower Stratosphere at High Northern Latitudes

Up to now, there has been no corroboration from Cassini CIRS of the Voyager IRIS-discovery of cyanoacetylene (HC3N) ice in Titan's thermal infrared spectrum. We report the first compelling spectral evidence from CIRS for the v6 HC3N ice feature at 506 per centimeter at latitudes 62 deg. N and 70 deg. N, from which we derive particle sizes and column abundances in Titan's lower stratosphere. We find mean particle radii of 3.0 micrometers and 2.3 micrometers for condensed HC3N at 62 deg. N and 70 deg. N, respectively, and corresponding ice phase molecular column abundances in the range 1-10 x 10(exp 16) mol per square centimeter. Only upper limits for cloud abundances can be established at latitudes of 85 deg. N, 55 deg. N, 30 deg. N, 10 deg. N, and 15 deg. S. Under the assumption that cloud tops coincide with the uppermost levels at which HC3N vapor saturates, we infer geometric thicknesses for the clouds equivalent to 10-20 km or so, with tops at 165 km and 150 km at 70 deg. N and 62 Deg. N, respectively.

Anderson, C. M.↗
NASA NTRS2008

Cassini/CIRS Observations of Water Vapor in Titan's Stratosphere

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained spectra of Titan during most of the 44 flybys of the Cassini prime mission. Water vapor on Titan was first detected using whole-disk observations from the Infrared Space Observatory (Coustenis et al 1998, Astron. Astrophys. 336, L85-L89). CIRS data permlt the retrieval of the latitudinal variation of water on Titan and some limited information on its vertical profile. Emission lines of H2O on Titan are very weak in the CIRS data. Thus, large spectral averages as well as improvements in calibration are necessary to detect water vapor. Water abundances were retrieved in nadir spectra at 55 South, the Equator, and at 19 North. Limb spectra of the Equator were also modeled to constrain the vertical distribution of water. Stratospheric temperatures in the 0.5 - 4.0 mbar range were obtained by inverting spectra of CH4 in the v4 band centered at 1304/cm. The temperature in the lower stratosphere (4 - 20 mbar) was derived from fitting pure rotation lines of CH4 between 80 and 160/cm. The origin of H2O and CO2 is believed to be from the ablation of micrometeorites containing water ice, followed by photochemistry. This external source of water originates either within the Saturn system or from the interplanetary medium. Recently, Horst et al (J. Geophys. Res. 2008, in press) developed a photochemical model of Titan in which there are two external sources of oxygen. Oxygen ions (probably from Enceladus) precipitate into Titan's atmosphere to form CO at very high altitudes (1100 km). Water ice ablation at lower altitudes (700 km) forms H2O and subsequent chemistry produces CO2. CIRS measurements of CO, CO2, and now of H2O will provide valuable constraints to these photochemical models and - improve our understanding of oxygen chemistry on Titan.

Bjoraker, Gordon L.↗
NASA NTRS2008

Titan's Surface Brightness Temperatures and H2 Mole Fraction from Cassini CIRS

The atmosphere of Titan has a spectral window of low opacity around 530/cm in the thermal infrared where radiation from the surface can be detected from space. The Composite Infrared spectrometer1 (CIRS) uses this window to measure the surface brightness temperature of Titan. By combining all observations from the Cassini tour it is possible to go beyond previous Voyager IRIS studies in latitude mapping of surface temperature. CIRS finds an average equatorial surface brightness temperature of 93.7+/-0.6 K, which is close to the 93.65+/-0.25 K value measured at the surface by Huygens HASi. The temperature decreases toward the poles, reaching 91.6+/-0.7 K at 90 S and 90.0+/-1.0 K at 87 N. The temperature distribution is centered in latitude at approximately 12 S, consistent with Titan's season of late northern winter. Near the equator the temperature varies with longitude and is higher in the trailing hemisphere, where the lower albedo may lead to relatively greater surface heating5. Modeling of radiances at 590/cm constrains the atmospheric H2 mole fraction to 0.12+/-0.06 %, in agreement with results from Voyager iris.

Jennings, Donald E.↗
NASA NTRS2008

Titan's Surface Temperatures Measured by Cassini CIRS

A large fraction of 19-micron thermal radiation from the surface of Titan reaches space through a spectral window of low atmospheric opacity. The emergent radiance, after removing the effect of the atmosphere, gives the brightness temperature of the surface. This atmospheric window is covered by the far-infrared channel of the Composite Infrared spectrometer1 (CIRS) on Cassini. In mapping Titan surface temperatures, CIRS is able to improve upon results of Voyager IRIS, by taking advantage of improved latitude coverage and a much larger dataset. Observations are from a wide range of emission angles and thereby provide constraints on the atmospheric opacity and radiance that are used to derive the surface temperature. CIRS finds an average equatorial surface brightness temperature of 93.7+/-0.6 K, virtually identical to the HASI temperature at the Huygens landing site. Mapping in latitude shows that the surface temperature decreases toward the poles by about 2 K in the south and 3 K in the north. This surface temperature distribution is consistent with the formation of lakes seen at high latitudes on Titan.

Jennings, Donald E.↗
NASA NTRS1997

ISO observations of Titan with SWS/grating

The observations of Titan performed by the Infrared Space Observatory (ISO) short wavelength spectrometer (SWS), in the 2 micrometer to 45 micrometer region using the grating mode, are reported on. Special attention is given to data from Titan concerning 7 micrometer to 45 micrometer spectral resolution. Future work for improving Titan's spectra investigation is suggested.

Coustenis, A.↗
NASA NTRS1993

Constraints on N2 in Neptune's atmosphere from Voyager measurements

It is shown that N2 may be present in the troposphere of Neptune in an amount difficult to evaluate but which could easily be as high as 0.003, while there is no evidence that it is present in the atmosphere of Uranus. The estimate of the helium abundance depends on the assumed value for N2. If there is no N2 in the observed region of the atmosphere of Uranus and an N2 mole fraction of 0.003 on Neptune, the central value of the estimates of the helium abundance are equal to 0.26 by mass in both planets, which is close to the protosolar value of 0.28. This would imply that the He/H2 ratios measured in the outer atmospheres of Uranus and Neptune are representative of the ratio in the primitive solar nebula and thus were not modified during planetary formation.

Conrath, B. J.↗
NASA NTRS1992

Exploration of the solar system by infrared remote sensing

The remote sensing of objects in the solar system using infrared radiation is discussed. Theories of radiative transfer, molecular spectroscopy, and atmospheric physics are used to show how infrared spectra of model planetary atmospheres are calculated. Instrumental techniques are described and the effect of instruments on the measurement of the emerging radiation field is addressed. Techniques that allow the retrieval of atmospheric and surface parameters from observations are examined. All the planets except Pluto are studied, and many of the planetary satellites.

Hanel, R. A.↗
NASA NTRS1991

The helium abundance of Neptune from Voyager measurements

The He abundance in the Neptunian atmosphere is estimated using results from Voyager radio occultation and IR spectrometer measurements. It is found that the shape of the measured spectrum cannot be matched by spectra calculated from atmospheric models that include only gaseous opacity, indicating that there might exist an additional opacity source associated with clouds or hazes. The data obtained could be fit with either of the two general classes of horizontally homogeneous cloud opacity models: (1) a model consisting of a tropospheric cloud with an optical thickness at 200/cm between 1 and 8; and (2) a stratospheric cloud with an optical thickness between 0.2 and 0.8.

Conrath, B. J.↗