Long-wavelength ultraviolet photoproduction of amino acids on the primitive earth
Long wavelength UV photoproduction of amino acids on primitive earth, using hydrogen sulfide as photon acceptor
Engineering topics
Publications and source records attributed to Sagan, C..
Long wavelength UV photoproduction of amino acids on primitive earth, using hydrogen sulfide as photon acceptor
In a simulation of interstellar organic chemistry in dense interstellar clouds or on grain surfaces, formaldehyde, water vapor, ammonia and ethane are deposited on a quartz cold finger and ultraviolet-irradiated in high vacuum at 77K. The HCHO photolytic pathway which produces an aldehyde radical and a superthermal hydrogen atom initiates solid phase chain reactions leading to a range of new compounds, including methanol, ethanol, acetaldehyde, acetonitrile, acetone, methyl formate, and possibly formic acid. Higher nitriles are anticipated. Genetic relations among these interstellar organic molecules (e.g., the Cannizzaro and Tischenko reactions) must exist. Some of them, rather than being synthesized from smaller molecules, may be degradation products of larger organic molecules, such as hexamethylene tetramine, which are candidate consitituents of the interstellar grains. The experiments reported here may also be relevant to cometary chemistry.
Martian surface topography effects on mean wind from time independent and frictionless thermal wind equation solution for radiative-convective atmospheres at scaling analysis level
Effects of UV selection pressure on evolutionary development patterns of early organisms
Function of UV light in evolution of contemporary ribosomes
Mars microwave spectrum, discussing brightness temperature increase towards short wavelengths in terms of surface material thermal, electrical or chemical properties
Exobiological survey of solar system beyond Mars, considering asteroids, Jovian planets and moons, Pluto and comets
A single pulse shock tube of a uniform bore was used in the experiments. The reaction mixture consisted of 3.3 per cent methane, 11 per cent ethane, and 5.6 per cent ammonia, diluted with ultra-pure argon. The formation of glycine, alanine, valine, and leucine under conditions of shock heating was observed. Thermodynamic relations are discussed together with questions of conversion efficiency.
Thermogravimetric analysis of goethite-rich sample of Mars type limonite, considering sorption process relation to Mars environment and polar caps
Amino acids produced by long UV irradiation of gas mixtures using hydrogen sulfide as initial photon acceptor, simulating prebiological earth conditions
Amino acid synthesis in simulated primitive environments, discussing possible effects of meteoric kinetic energy and lightning-associated shock waves
A study of several thousand photos indicated approximately 1% of Gemini and Apollo photographs of the earth at 100 m resolution revealed signs of life; rectangular arrays due to human agricultural and urban territoriality, roads, canals, jet contrails, and industrial pollution. Potential false positives such as dunes, sand bars, and jet stream clouds abound. A curve was derived for the detectivity of contemporary life on earth, in a plot of ground resolution versus global coverage. A comparable biology on Mars would not have been detected by all observations of Mars through Mariner 7. Forthcoming Mars orbiter and lander imaging experiments hold significant promise of detecting life on Mars of contemporary terrestrial extent and advancement, should such life exist.
Thermogravimetric study of physically and chemically bound water in ferric oxides of limonite with application to goethite on Mars
Primitive earth prebiological organic synthesis via amino acids shock heating in atmosphere-simulating gas mixture, suggesting energy sources from atmospheric entry
Mars surface, environment and electrical, thermal and mechanical properties
Mars craters and crater-like objects catalog from Mariner 4 photographs, statistically analyzing diameter-frequency relations
Figure and inhomogeneities relationship for moon, Mercury, Venus, Mars and earth, discussing circular basins and mascons