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Sachse, G. W.

Publications and source records attributed to Sachse, G. W..

64 records · Page 4

An intercomparison of results from ferrous sulphate and photolytic converter techniques for measurements of NO(x) made during the NASA GTE/CITE 1 aircraft program

Two techniques designed for measurements of NO(x (NO + NO2) were intercompared during aircraft flights made in the spring of 1984 in the middle free troposphere over the eastern Pacific Ocean and southwestern U.S. One NO chemiluminescence instrument was equipped with a ferrous sulphate converter, another with a photolytic converter. The ferrous sulphate-equipped instrument was apparently much less specific for NO2. It registered levels about three times larger than the photolytic converter and gave NO2/NO ratios that were much larger than photochemical calculations would indicate as reasonable. Additionally, the results imply that active NO(x) was only 10-20 percent of the total odd nitrogen in the middle free troposphere.

Ridley, B. A.↗

Carbon monoxide over the Amazon Basin during the 1985 dry season

During the Amazon Boundary Layer Experiment, approximately 100 hours of in situ carbon monoxide measurements were obtained using a tunable diode laser sensor that provided continuous, fast-response (about 1 s) measurements. This data set, taken on board the NASA Electra between July 12 and August 12, 1985, characterizes the temporal and spatial changes in the CO distribution over the Amazon Basin as meteorological conditions progressed from the early to middle phases of the 1985 day season. Early dry-season CO values of 75-95 ppbv were generally observed in the PBL. As the dry season became well established, biomass burning and a persistent capping inversion at about 3 km profoundly altered the CO distribution, with PBL values typically reaching 150-275 ppbv. Concentrations as high as 800 ppbv were measured within identifiable haze layers. An analysis of satellite imagery shows that biomass burning was occurring along the Amazon River system and in savannah areas located more than 1000 km south of the region sampled.

Sachse, G. W.↗

Biomass-burning emissions and associated haze layers over Amazonia

The characteristics of haze layers, which were visually observed over the central Amazon Basin during many of the Amazon Boundary Layer Experiment 2A flights in July/August 1985, were investigated by remote and in situ measurements, using the broad range of instrumentation and sampling equipment on board the Electra aircraft. It was found that these layers strongly influenced the chemical and optical characteristics of the atmosphere over the eastern Amazon Basin. Relative to the regional background, the concentrations of CO, CO2, O3, and NO were significantly elevated in the plumes and haze layers, with the NO/CO ratio in fresh plumes much higher than in the aged haze layers. The haze aerosol was composed predominantly of organic material, NH4, K(+), NO3(-), SO4(2-), and organic anions (formate, acetate, and oxalate).

Andreae, M. O.↗

An intercomparison of carbon monoxide measurement techniques

Results from an intercomparison of techniques to measure tropospheric levels of carbon monoxide (CO) are discussed. The intercomparison was conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment (GTE) and was held at Wallops Island, VA, in July 1983. Instruments intercompared included a laser differential absorption method and three grab sample/gas chromatograph methods. The intercomparison consisted of simultaneous measurements of ambient levels of CO and controlled injections of CO from a common manifold. Results from the techniques exhibited a high degree of correlation among themselves and with changes in the CO mixing ratio. The results suggested a level of agreement among the techniques of about 15 percent. However, a day-to-day bias between the techniques was observed, which resulted in differences between techniques as large as 38 percent.

Hoell, J. M., Jr.↗

Airborne tunable diode laser system for trace gas measurements

Sachse et al. (1976) have reported the development of an airborne tunable diode laser (TDL) system, named the Differential Absorption CO Monitor (DACOM). The absorption path was 10 m long and located in the free airstream along the fuselage of a C-54 aircraft. The present investigation is concerned with a modification of the DACOM instrument. Differences between the new instrument and the original one are related to a replacement of the external absorption path with a White cell. The instrument has the capability to suppress TDL excess noise. The laser refrigerator has been redesigned to permit an alternative method of cooling the TDL when electric power is not available.

Sachse, G. W.↗

Summary of 1978 Southeastern Virginia Urban Plume study: Aircraft results for carbon monoxide, methane, nonmethane hydrocarbons, and ozone

The characteristics of the Southeastern Virginia urban plume were defined with emphasis on the photon-oxidant species. The measurement area was a rectangle, approximately 150 km by 100 km centered around Cape Charles, Virginia. Included in this area are the cities of Norfolk, Virginia Beach, Chesapeake, Newport News, and Hampton. The area is bounded on the north by Wallops Island, Virginia, and on the south by the Hampton Roads area of Tidewater Virginia. The major axis of the rectangle is oriented in the southwest-northeast direction. The data set includes aircraft measurements for carbon monoxide, methane, nonmethane hydrocarbons, and ozone. The experiment shows that CO can be successfully measured as a tracer gas and used as an index for determining localized and urban plumes. The 1978 data base provided sufficient data to assess an automated chromatograph with flame ionization detection used for measuring methane and nonmethane hydrocarbons in flight.

Hill, G. F.↗

Microwave tunable laser source: A stable, precision tunable heterodyne local oscillator

The development and capabilities of a tunable laser source utilizing a wideband electro-optic modulator and a CO2 laser are described. The precision tunability and high stability of the device are demonstrated with examples of laboratory spectroscopy. Heterodyne measurements are also presented to demonstrate the performance of the laser source as a heterodyne local oscillator. With the use of five CO2 isotope lasers and the 8 to 18 GHz sideband offset tunability of the modulator, calculations indicate that 50 percent spectral coverage in the 9 to 12 micron region is achievable. The wavelength accuracy and stability of this laser source is limited by the CO2 laser and is more than adequate for the measurement of narrow Doppler-broadened line profiles. The room-temperature operating capability and the programmability of the microwave tunable laser source are attractive features for its in-the-field implementation. Although heterodyne measurements indicated some S/N degradation when using the device as a local oscillator, there does not appear to be any fundamental limitation to the heterodyne efficiency of this laser source. Through the use of a lower noise-figure traveling wave tube amplifier and optical matching of the output beam with the photomixer, a substantial increase in the heterodyne S/N is expected.

Sachse, G. W.↗

Differential laser absorption monitoring of the atmosphere

In the airborne detection system of atmospheric constituents and pollutants described, double-ended differential absorption measurement is accomplished by rapidly current tuning the wavelength of a PbSSe diode laser across a single line of the species under consideration. As the laser wavelength sweeps periodically across the absorption line, the laser beam is amplitude modulated and is then synchronously detected. With this technique, a minimum detectable differential transmission of 0.02 percent is obtained for a 1-sec integration time.

Rubin, B.↗

DACOM - A rapid, high sensitivity airborne carbon monoxide monitor

A rapid, high sensitivity differential absorption carbon monoxide monitor (DACOM) has been developed to measure CO from an aircraft. The differential absorption measurement is accomplished by rapidly current tuning the wavelength of a PbSSe diode laser across a single 4.7 micron CO absorption line. As the laser wavelength sweeps periodically across the absorption line, the laser beam is amplitude modulated and is then synchronously detected. With this technique a minimum detectable differential transmission of 0.02% is obtained for a 1 second integration time. This performance is equivalent to a CO sensitivity of 5 ppb for a 10 meter absorption path. The techniques used to achieve this high sensitivity will be discussed. In the aircraft installation a 10 meter absorption path is located in the airstream along the fuselage of a C-54 aircraft. During flight tests of DACOM, a sensitivity of 20 ppb for a 1-second integration time has been achieved.

Sachse, G. W.↗

An investigation of RF sputter etched silicon surfaces using helium ion backscatter

The effect of RF sputter etching on the (111) surface of silicon was studied by observing backscatter spectra from a 2 MeV, He-4(+) beam oriented along the silicon 111 orientation channel. Silicon samples were RF sputter etched in an argon discharge at electrode bias potentials ranging from 0.5 to 2.5 kV. The samples were sputter etched for a time sufficient for the lattice damage to reach saturation. Analysis of these samples revealed that the thickness of this damage layer and the concentration of trapped argon increased with electrode bias potential. An annealing study of these damaged surfaces was carried out to 900 C.

Sachse, G. W.↗