Engineering topics

Russell, James

Publications and source records attributed to Russell, James.

7 records

DOE OSTI2024

Comparative clumped isotope temperature relationships in freshwater carbonates

Lacustrine, riverine and spring carbonates represent archives of terrestrial climates and their geochemistry has been used to study palaeoenvironments. Clumped isotope thermometry is an emerging tool that has been applied to freshwater carbonates. Limited work has been done to evaluate comparative relationships between clumped isotopes and temperature in different types of modern freshwater carbonates. This study assembles an extensive calibration data set with 135 samples of modern freshwater carbonates from 96 sites and constrains the relationship between independent observations of water temperature and the clumped isotopic composition of carbonates (denoted by Δ 47 ), including new measurements, and recalculates published data in accordance with current community-defined standard values. For temperature reconstruction, the study reports a composite freshwater calibration and material-specific calibrations for biogenic carbonates (freshwater gastropods and bivalves), fine-grained carbonate (e.g. micrites), biologically mediated carbonates (microbialites and tufas) and travertines. Material-specific calibration trends show a convergence of slopes that are in agreement with recently published syntheses, but statistically significant differences in intercepts occur between some materials (e.g. some biogenics, fine-grained carbonates). These differences may arise due to unresolved seasonal biases, kinetic isotope effects and/or varying degrees of biological influence. The impact of different calibrations is shown through application to new data for glacial and deglacial age travertines from Austria and published data sets. While material-specific calibrations may yield more accurate results for biogenic and fine-grained carbonate samples, the use of material-specific and the composite freshwater calibrations generally produces values within 1.0–1.5°C of each other, and typically fall within calibration uncertainty given limitations of precision.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

WACCM6 Projections of Polar Mesospheric Cloud Abundance Over the 21st Century

Polar mesospheric clouds (PMC), or noctilucent clouds, can be observed over high latitudes with the naked eye from the ground or from space near the summer solstice. PMC are considered a direct and sensitive indicator of climate change and have been reported to appear more frequently in recent decades. How PMC will change in the future under the influence of natural variability and anthropogenic forcing is uncertain. In this study, we utilize model output from the Whole Atmosphere Community Climate Model under several shared socioeconomic pathway (SSP) scenarios and input the water vapor, temperature, and pressure information into a 0-d PMC model to project the trend and variation of PMC over the 21st century, and their relationship to future changes of temperature, water vapor, and the solar cycle. The 0-d model calculations indicate that PMC ice water content (IWC) will increase and PMC will extend to lower latitudes under high SSP scenarios. Under these scenarios, more mesospheric water vapor leads to an increased IWC of PMC over the polar region, and colder mesopause temperature leads to more PMC over the mid-latitudes. There is a significant anti-correlation between the solar cycle and PMC IWC over the 21st century, but the anti-correlation is not always significant on the decadal scale. Finally, methane oxidation in the stratosphere and water vapor entering from the troposphere are both responsible for future changes in mesospheric water vapor and thus PMC.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

Small Molecule Sorting: A Fluorescence Study of Microemulsions

The application of microemulsions to a wide range of industries relies on their ability to solubilize small molecules with vastly different structures. Herein, we use multiple fluorescence techniques to probe ionic (rhodamine 6g, r6g), polar (coumarin 153, c153), nonpolar (diphenylanthracene, DPA), and amphiphilic (laurdan) small molecules in a nonionic, bicontinuous microemulsion of varying hydration. All fluorophores investigated were found to associate with the surfactant region despite their different structures and properties. The hydration of the surfactant layer was found to increase linearly with water addition, but while this initially increases the fluidity of the surfactant layer, fluorescence anisotropy of c153 and r6g indicates a stiffening of the surfactant at water content >60%. This stiffening of the surfactant layer at higher water content correlates with a morphological change in the microemulsion from a bicontinuous structure to droplets. In contrast, the nonpolar DPA shows a change in partitioning as hydration changes, increasing its association with the oil domain. Altogether, these studies elucidate not only the capability of these microemulsions to host a range of small molecules in the surfactant layer with tunable position but also the ability to probe the driving force of bulk structural changes in these heterogeneous fluids.

25 ENERGY STORAGE↗

DOE OSTI2022

Variability of Water Vapor in the Tropical Middle Atmosphere Observed From Satellites and Interpreted Using SD-WACCM Simulations

Water vapor in the middle atmosphere plays an essential role in global warming, ozone depletion, and the formation of polar stratospheric and mesospheric clouds. We show that tropical middle atmospheric water vapor simulated with the specified-dynamics version of the Whole Atmosphere Community Climate Model (SD-WACCM) is consistent with changes observed in a merged satellite data set, which encompasses the period 1993–2020. Consistent with previous work, we find no significant trend in the stratosphere in either the observations or the simulation; in the mesosphere, we find a long-term trend of 0.1 ppmv per decade, but only in the observations. We also analyze an SD-WACCM simulation for the longer period 1980–2019 to quantify the contribution of various factors to the decadal variation of middle atmospheric water vapor. Over 1980–1995, the simulated water vapor in the upper stratosphere and mesosphere, averaged zonally and over ±30° latitude, increases by 0.30 ppmv per decade due to increasing methane emissions. After 1995, a significant abrupt decrease of water vapor of 0.37 ppmv per decade and then a gradual increase of 0.33 ppmv per decade result from changes in stratospheric cold point temperature. The cold-point temperature is strongly influenced by the strength of the Brewer-Dobson circulation. The acceleration of the Brewer-Dobson circulation before about 2003 leads to a cooler tropical tropopause and a decrease of water vapor, and the deceleration thereafter leads to corresponding warming of the tropopause and an increase in water vapor.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2006

SABER (TIMED) and MLS (UARS) Temperature Observations of Mesospheric and Stratospheric QBO and Related Tidal Variations

More than three years of temperature observations from the SABER (TIMED) and MLS WARS) instruments are analyzed to study the annual and inter-annual variations extending from the stratosphere into the upper mesosphere. The SABER measurements provide data from a wide altitude range (15 to 95 km) for the years 2002 to 2004, while the MLS data were taken in the 16 to 55 km altitude range a decade earlier. Because of the sampling properties of SABER and MLS, the variations with local solar time must be accounted for when estimating the zonal mean variations. An algorithm is thus applied that delineates with Fourier analysis the year-long variations of the migrating tides and zonal mean component. The amplitude of the diurnal tide near the equator shows a strong semiannual periodicity with maxima near equinox, which vary from year to year to indicate the influence from the Quasi-biennial Oscillation (QBO) in the zonal circulation. The zonal mean QBO temperature variations are analyzed over a range of latitudes and altitudes, and the results are presented for latitudes from 48"s to 48"N. New results are obtained for the QBO, especially in the upper stratosphere and mesosphere, and at mid-latitudes. At Equatorial latitudes, the QBO amplitudes show local peaks, albeit small, that occur at different altitudes. From about 20 to 40 km, and within about 15" of the Equator, the amplitudes can approach 3S K for the stratospheric QBO or SQBO. For the mesospheric QBO or MQBO, we find peaks near 70 km, with temperature amplitudes reaching 3.5"K, and near 85 km, the amplitudes approach 2.5OK. Morphologically, the amplitude and phase variations derived from the SABER and MLS measurements are in qualitative agreement. The QBO amplitudes tend to peak at the Equator but then increase again pole-ward of about 15" to 20'. The phase progression with altitude varies more gradually at the Equator than at mid-latitudes. A comparison of the observations with results from the Numerical Spectral Model (NSM) reveals that there is qualitative agreement. The NSM generates the QBO extending from the stratosphere into the upper mesosphere, with temperature variations extending to mid latitudes, but the predicted amplitudes are smaller than those observed.

Huang, Frank T.↗

NASA NTRS2005

Zonal-Mean Temperature Variations Inferred from SABER Measurements on TIMED Compared with UARS Observations

In the Numerical Spectral Model (NSM, Mayr et al., 2003), small-scale gravity waves propagating in the north/south direction can generate zonal mean (m = 0) meridional wind oscillations with periods between 2 and 4 months. These oscillations tend to be confined to low latitudes and have been interpreted to be the meridional counterpart of the wave-driven Quasi Biennial Oscillation in the zonal circulation. Wave driven meridional winds across the equator should generate, due to dynamical heating and cooling, temperature oscillations with opposite phase in the two hemispheres. We have analyzed SABER temperature measurements in the altitude range between 55 and 95 km to investigate the existence such variations. Because there are also strong tidal signatures (up to approximately 20 K) in the data, our algorithm estimates both mean values and tides together from the data. Based on SABER temperature data, the intra-annual variations with periods between 2 and 4 months can have amplitudes up to 5 K or more, depending on the altitude. Their amplitudes are in qualitative agreement with those inferred Erom UARS data (from different years). The SABER temperature variations also reveal pronounced hemispherical asymmetries, which are qualitatively consistent with wave driven meridional wind oscillations across the equator. Oscillations with similar periods have been seen in the meridional winds based on UARS data (Huang and Reber, 2003).

Huang, Frank T.↗

NASA NTRS2005

Comparison between the Temperature Measurements by TIMED/SABER and Lidar in the Mid-Latitude

Comparisons of monthly-mean nighttime temperature profiles observed by the Sodium Lidar at Colorado State University and TIMED/SABER over passes are made. In the altitude range from 85 km to about 100 km, the two observations are in excellent agreement. Though within each other s error bars, important differences occur below 85 km in the entire year and above 100 km in the summer season. Possible reasons for these difference are high photon noise below 85 km in lidar observations, and less than accurate assumptions in the concentration of important chemical species like oxygen (and its quenching rate) in the SABER retrieval above 100 km. However, the two techniques both show the two-level mesopause thermal structure, with the times of change from one level to the other in excellent agreement. Comparison indicates that the high-level (winter) mesopause altitudes are also in excellent agreement between the two observations, though some difference may exist in the low-level (summer) mesopause altitudes between ground-based and satellite-borne data.

Xu, Jiyao↗