Engineering topics
Publications and source records attributed to Ronney, Paul D..
A diffusive-thermal high Lewis number (Le) gas-phase oscillator has been observed in premixed flames using a lean mixture of butane and oxygen diluted with helium (Le approx. 3.0). This reactive-diffusive system exhibits both propagating radial pulsations and rotating spiral waves perhaps,analogous to those observed in other excitable media such as the Belousov-Zhabotinsky reaction.
It is well known that radiative heat transport influences many types of buoyant flows due to its effect on the temperature and thus density field in the fluid medium. It is of interest to study gaseous flows driven solely by radiation in the absence of buoyancy, particularly because of its application to astrophysical flows that are well known from astronomical observations and numerical simulation. However, no laboratory-scale experiments of this phenomenon have ever been conducted. To study the possibility of obtaining such flows in the laboratory, an apparatus was built to produce large temperature differences (Delta T) up to 300 K in a gas confined between flat parallel plates. SF6 was used as the radiatively-active gas because its Planck absorption length is much shorter than that of any other common non-reactive gas. The NASA-Lewis 2.2 second drop tower was used to obtain reduced gravity in order to suppress buoyancy effects. To image the resulting flows, a laser shearing interferometer was employed. Initial results indicate the presence of flow that does not appear to be attributable to the residual flow resulting from buoyancy influences before the drop. For Delta T greater than 70 K, slight deformations in the interferometer fringes seen at lower Delta T became large unsteady swirls. Such behavior did not occur for radiatively-inactive gases, suggesting that a flow driven solely by radiation was obtained in SF6 and to a lesser extent in CO2 This was more pronounced at higher pressures and plate spacings, consistent with our scaling predictions.
Flame propagation in both the optically thin and the optically thick regime of radiative transport was studied experimentally using particle-laden gas mixtures. Data on flame shapes, propagation rates, peak pressure, maximum rate of pressure rise, and thermal decay in the burned gases are consistent with the hypothesis that, at low particle loadings, the particles act to increase the radiative loss from the gases, whereas at higher loadings, reabsorption of emitted radiation becomes significant. The reabsorption acts to decrease the net radiative loss and augment conductive heat transport. It is speculated that, in sufficiently large systems, in which the absorption length is much smaller than the system size, flammability limits might not exist at microgravity conditions because emitted radiation would not constitute a loss mechanism.
A two and one-half year experimental and theoretical research program on the properties of laminar and turbulent premixed gas flames at microgravity was conducted. Progress during this program is identified and avenues for future studies are discussed.
The work of the Principal Investigator (PI) has encompassed four topics related to the experimental and theoretical study of combustion limits in premixed flames at microgravity, as discussed in the following sections. These topics include: (1) radiation effects on premixed gas flames; (2) flame structure and stability at low Lewis number; (3) flame propagation and extinction is cylindrical tubes; and (4) experimental simulation of combustion processes using autocatalytic chemical reactions.
Observations of the effect of the addition of fine solid particles to weakly combustible methane-air mixtures are reported. Burning rates, pressure rise, and thermal characteristics are found to exhibit nonmonotonic trends with increasing particle loading. These results are interpreted in terms of the effects of augmentation of radiant loss at small particle loadings and re-absorption of emitted radiation at larger loadings. It is suggested that in sufficiently large systems, flammability limits might not exist because of this reabsorption effect.
A study of the mechanisms of flammability limits and the dynamics of flame extinguishment in premixed gas flames is described, a novel feature of which is the use of diluent gases having a wide range of radiative and diffusive transport properties. This feature enables an assessment of the importance of volumetric heat losses and Lewis number effects on these mechanisms. Additionally, effects of flame dynamics and flame front curvature are studied by employing spherically expanding flames obtained in a microgravity environment whereby natural convection is eliminated. New diagnostics include chamber pressure measurements and the first reported species concentration measurements in a microgravity combustion experiment. The limit mechanisms and extinguishment phenomena are found to be strongly influenced by the combined effects of radiant heat loss, Lewis number and flame curvature. Two new and as yet not well understood phenomena are reported: 'double flames' in rich H2-O2-CO2 mixtures and an 'inverse flammability region' in rich C3H8-O2-CO2 mixtures.
A three-year experimental and theoretical research program on the mechanisms of combustion limits of premixed gasflames at microgravity was conducted. Progress during this program is identified and avenues for future studies are discussed.
The characteristics of premixed gas flames in mixtures with low Lewis numbers near flammability limits were studied experimentally using a low-gravity environment to reduce buoyant convection. The behavior of such flames was found to be dominated by diffusive-thermal instabilities. For sufficiently reactive mixtures, cellular structures resulting from these instabilities were observed and found to spawn new cells in regular patterns. For less reactive mixtures, cells formed shortly after ignition but did not spawn new cells; instead these cells evolved into a flame structure composed of stationary, apparently stable spherical flamelets. Experimental observations are found to be in qualitative agreement with elementary analytical models based on the interaction of heat release due to chemical reaction, differential diffusion of thermal energy and mass, flame front curvature, and volumetric heat losses due to gas and/or soot radiation.
The characteristics of premixed gas flames in mixtures with low Lewis numbers, free of natural convection effects, were investigated and found to be dominated by diffusive-thermal instabilities. For sufficiently reactive mixtures, cellular structures resulting from these instabilities were observed and found to spawn new cells in regular patterns. For less reactive mixtures, cells formed shortly after ignition but did not spawn new cells; instead these cells evolved into a flame structure composed of stationary, apparently stable spherical flamelets. As a result of these phenomena, well-defined flammability limits were not observed. The experimental results are found to be in qualitative agreement with a simple analytical model based on the interaction of heat release due to chemical reaction, differential diffusion of thermal energy and mass, flame front curvature, and heat losses due to gas radiation.
The requirements for a nonintrusive optical diagnostic facility for Space Station are assessed by examining the needs of current and future combustion experiments to be flown aboard the Space Station. Requirements for test section geometry and size, spatial and temporal resolution, species type and concentration range, and temperature range are reviewed. The feasibility of the development of this system is also addressed. The suitability of this facility to non-combustion experiments in gases and liquids is also considered.