Engineering topics
Rodriguez, Jose
Publications and source records attributed to Rodriguez, Jose.
Accurate de novo design of membrane-traversing macrocycles
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De novo determination of mosquitocidal Cry11Aa and Cry11Ba structures from naturally-occurring nanocrystals
Abstract Cry11Aa and Cry11Ba are the two most potent toxins produced by mosquitocidal Bacillus thuringiensis subsp. israelensis and jegathesan , respectively. The toxins naturally crystallize within the host; however, the crystals are too small for structure determination at synchrotron sources. Therefore, we applied serial femtosecond crystallography at X-ray free electron lasers to in vivo-grown nanocrystals of these toxins. The structure of Cry11Aa was determined de novo using the single-wavelength anomalous dispersion method, which in turn enabled the determination of the Cry11Ba structure by molecular replacement. The two structures reveal a new pattern for in vivo crystallization of Cry toxins, whereby each of their three domains packs with a symmetrically identical domain, and a cleavable crystal packing motif is located within the protoxin rather than at the termini. The diversity of in vivo crystallization patterns suggests explanations for their varied levels of toxicity and rational approaches to improve these toxins for mosquito control.
Surface Biology and Geology (SBG) Visible to Short Wavelength Infrared (VSWIR) Wide Swath Instrument Concept
The 2017 Decadal Survey: Thriving on Our Changing Planet, A Decadal Strategy for Earth Observation from Space has called new observations including global coverage Visible to Short Wavelength Infrared (VSWIR) Wide Swath (WS) imaging spectroscopy measurements as part of the Surface Biology and Geology (SBG) Designated Observable. The SBG VSWIR-WS along with the companion SBG Thermal Infrared (TIR) imager is an important element of NASA’s larger Earth System Observatory (ESO).
Surface Biology and Geology (SBG) Visible to Short Wavelength Infrared (VSWIR) Wide Swath Instrument Concept
The 2017 Decadal Survey: Thriving on Our Changing Planet, A Decadal Strategy for Earth Observation from Space has called new observations including global coverage VSWIR Wide Swath (VSWIR-WS) imaging spectroscopy measurements as part of the Surface Biology and Geology (SBG) Designated Observable. The SBG VSWIR-WS along with the companion SBG Thermal Infrared (TIR) imager is an important element of NASA’s larger Earth System Observatory (ESO).
The rippled [beta]-sheet layer configuration?a novel supramolecular architecture based on prediction
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Scalable Parallel Nonlinear Optimization with PyNumero and Parapint.
Abstract not provided.
Data for Validating Models for PV Module Performance
This data encompasses performance data measured for flat-plate photovoltaic (PV) modules installed in Cocoa, Florida; Eugene, Oregon; and Golden, Colorado. The data include PV module current-voltage curves and associated meteorological data for approximately one-year periods. The data was acquired with the NREL Performance and Energy Rating Testbed (PERT) and the mobile Performance and Energy Rating Testbed (mPERT).
Europa Environmental Testing of Thermal Hardware for the Mapping Imaging Spectrometer for Europa (MISE) Instrument
The Europa Clipper spacecraft, scheduled for launch in June 2022, hosts a suite of instruments including the Mapping Imaging Spectrometer for Europa (MISE). MISE is a high-optical through-put pushbroom infrared imaging spectrometer that can collect measurements within Europa’s challenging radiation environment. It is externally mounted to the spacecraft and as a result is exposed to high radiation levels and cold temperatures. The instrument consists of a scan mirror assembly, an optical bench including a Dyson spectrometer and a telescope, and a structure that supports a cryocooler and a radiator. The cryocooler is used to actively cool the focal plane array and the spectrometer. The heat from the cryocooler is rejected through pyrolytic graphite sheet thermal straps to a honeycomb radiator. MISE will implement thermal hardware that will either not be used on other parts of the spacecraft or have a more extreme environment than the spacecraft. As a result, the MISE instrument performed numerous environmental tests on its thermal hardware. This paper discusses the results of the thermal cycling and radiation tests performed on the MISE thermal hardware including a Lockheed Martin Micro1-2 cryocooler, Pyrolytic graphite sheet thermal straps, Annealed pyrolytic graphite K-Core, Rosemount Platinum Resistance Thermometers, Tayco Kapton Thermofoil heaters, Dale Ohm resistors, and aluminum honeycomb and facesheets.
Characterization Testing of Space-Flight Lockheed Martin Micro1-2 Cryocooler for the Mapping Imaging Spectrometer for Europa (MISE)
The Mapping Imaging Spectrometer for Europa (MISE) instrument on the Europa Clipper mission uses a Lockheed Martin “high-power” Micro1-2 pulse tube cryocooler with a heat rejection temperature around 220 K to provide cooling at 80 K. This paper describes the thermal performance and exported forces characterization testing and results of the space-flight Lockheed Martin Micro1-2 cooler optimized for these conditions. Prior to these characterization tests, the cooler passed random vibration and thermal vacuum cycling at Lockheed Martin.
In-situ Characterization of Metal/Oxide Catalysts for CO2 Conversion: From Fundamental Aspects to Real Catalysts Design
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Surface Chemistry Dependence on Aluminum Doping in Ni-rich LiNi 0.8 Co 0.2-y Al y O 2 Cathodes
Aluminum is a common dopant across oxide cathodes for improving the bulk and cathode-electrolyte interface (CEI) stability. Aluminum in the bulk is known to enhance structural and thermal stability, yet the exact influence of aluminum at the CEI remains unclear. To address this, we utilized a combination of X-ray photoelectron and absorption spectroscopy to identify aluminum surface environments and extent of transition metal reduction for Ni-rich LiNi 0.8 Co 0.2-y Al y O 2 (0%, 5%, or 20% Al) layered oxide cathodes tested at 4.75 V under thermal stress (60 °C). For these tests, we compared the conventional LiPF6 salt with the more thermally stable LiBF 4 salt. The CEI layers are inherently different between these two electrolyte salts, particularly for the highest level of Al-doping (20%) where a thicker (thinner) CEI layer is found for LiPF 6 (LiBF 4 ). Focusing on the aluminum environment, we reveal the type of surface aluminum species are dependent on the electrolyte salt, as Al-O-F- and Al-F-like species form when using LiPF 6 and LiBF 4 , respectively. In both cases, we find cathode-electrolyte reactions drive the formation of a protective Al-F-like barrier at the CEI in Al-doped oxide cathodes.