Engineering topics
Robinson, J.
Publications and source records attributed to Robinson, J..
Clocking Auger electrons
Intense X-ray free-electron lasers (XFELs) can rapidly excite matter, leaving it in inherently unstable states that decay on femtosecond timescales. The relaxation occurs primarily via Auger emission, so excited-state observations are constrained by Auger decay. In situ measurement of this process is therefore crucial, yet it has thus far remained elusive in XFELs owing to inherent timing and phase jitter, which can be orders of magnitude larger than the timescale of Auger decay. Here we develop an approach termed ‘self-referenced attosecond streaking’ that provides subfemtosecond resolution in spite of jitter, enabling time-domain measurement of the delay between photoemission and Auger emission in atomic neon excited by intense, femtosecond pulses from an XFEL. FUrthermore, using a fully quantum-mechanical description that treats the ionization, core-hole formation and Auger emission as a single process, the observed delay yields an Auger decay lifetime of \(2.2_{ - 0.3}^{ + 0.2}\) fs for the KLL decay channel.
Megahertz-compatible angular streaking with few-femtosecond resolution at x-ray free-electron lasers
Highly brilliant, coherent, femtosecond x-ray pulses delivered by free-electron lasers (FELs) constitute one of the pillars of modern ultrafast science. Next generation FEL facilities provide up to megahertz repetition rates and pulse durations down to the attosecond regime utilizing self-amplification of spontaneous emission. However, the stochastic nature of this generation mechanism demands single-shot pulse characterization to perform meaningful experiments. Here we demonstrate a fast yet robust online analysis technique capable of megahertz-rate mapping of the temporal intensity structure and arrival time of x-ray FEL pulses with few-femtosecond resolution. We performed angular streaking measurements of both neon photo- and Auger electrons and show their applicability for a direct time-domain feedback system during ongoing experiments. Here, the fidelity of the real-time pulse characterization algorithm is corroborated by resolving isolated x-ray pulses and double pulse trains with few-femtosecond substructure, thus paving the way for x-ray-pump–x-ray-probe FEL science at repetition rates compatible with the demands of LCLS-II and European XFEL.
Advanced Multilayer Coatings for National Security
This project advanced the state-of-the-art in multilayer interference coatings with customtailored properties for national security applications, by understanding and overcoming limitations in the physical properties of these coatings. We focused on improving the properties of two major types of multilayers: the reflectance of hard x-ray aperiodic multilayer coatings (MLs) and the laser damage resistance of dielectric multilayer coatings (MLDs). We developed a new class of hard x-ray MLs for imaging in the 17 – 59 keV photon energy range for applications including target diagnostics and astrophysics. We elucidated the physical and chemical properties of nanoscale layers of ML materials and their interfaces and developed generalized protocols for aperiodic ML design and deposition. We revealed the origin of important laser damage-prone precursors and the underlying mechanism upon exposure to high energy and intensity nanosecond (ns) lasers in the ultraviolet (UV) region. In both ML and MLD coatings, we investigated the relationships between deposition conditions and performance. We then applied deposition process modifications specific to each type of ML and MLD coatings to dramatically improve the ML reflective performance and the MLD laser-damage resistance.
An x-ray optic calibration facility for high energy density diagnostics
A facility to calibrate x-ray imaging optics was built at Lawrence Livermore National Laboratory to support high energy density (HED) and inertial confinement fusion (ICF) diagnostics such as those at the National Ignition Facility and the Sandia Z-Machine. Calibration of the spectral reflectivity and resolution of these x-ray diagnostics enable absolute determination of the x-ray flux and wavelengths generated in the HED and ICF experiments. Measurement of the optic point spread function is used to determine spatial resolution of the optic. This facility was constructed to measure (1) the x-ray reflectivity to ±5% over a spectral range from 5 to 60 keV; (2) point spread functions with a resolution of 50 μm (currently) and 13 μm (future) in the image plane; and (3) optic distance relative to the x-ray source and detector to within ±100 μm in each dimension. Here, this article describes the capabilities of the calibration facility, concept of operations, and initial data from selected x-ray optics.
Evaluating microstructure evolution in an SOFC electrode using digital volume correlation
Degradation mechanisms within solid oxide fuel cells (SOFC) during thermal cycling limit operational start-up times and cell lifetime, and must therefore be better understood and mitigated. This work explores such mechanisms using digital volume correlation (DVC) techniques applied to lab-based X-ray tomograms where the microstructural evolution is evaluated during the operational cycling of a Ni–YSZ/YSZ cell. To emulate reduced start-up times, five tomograms were collected over four operational thermal cycles to 750 °C at various ramp-rates: 3, 10, 20 and 30 °C min –1 . Two key features are observed in the 3D strain profiles. Firstly, during low ramp-rates the material produces microscopic channels towards cluster-points. This is thought to be caused by the ceramic skeleton inhibiting the effects of sintering. Secondly, previously unseen macroscopic ‘waves’ developed after high-rate cycling, consisting of linear regions of compression and tension throughout the sample. These wave features decay away from a heterogeneous defect which is thought to be responsible for the non-uniform strain profile. This work demonstrates the first use of sub-micron DVC computations applied to an SOFC exposed to operationally relevant temperatures. Lastly, these findings will assist in the development of new electrode materials from their fabrication to operation, ultimately supporting commercial viability of SOFCs.
Hard X-ray induced fast secondary electron cascading processes in solids
Recent studies confirmed that the materials used in the extreme UV and soft X-ray regime for precise characterization of intense free-electron laser pulses (e.g., Si 3 N 4 ) do not work efficiently in the hard X-ray regime, which is due to the fact that the impact of a hard X-ray photon is followed by a series of electron cascading processes. Following theoretical indication, we show that this limitation can be circumvented and the cascading time can be significantly reduced if the X-ray photon energy is double the ionization energy. We investigate an alternative material for pulse diagnostics, SnO 2 , using the Linac Coherent Light Source at photon energies of 5 keV and 9 keV. We prove the validity of the concept and show that it has a large potential for practical applications. In conclusion, by applying the proposed criteria, the temporal accuracy of the non-invasive pulse diagnostic tools can be improved in current and emerging hard X-ray facilities.
Delayed Onset of Nonthermal Melting in Single-Crystal Silicon Pumped with Hard X Rays
Here, we monitor the onset of nonthermal melting in single-crystal silicon by implementing an x-ray pump–x-ray probe scheme. Using the ultrashort pulses provided by the Linac Coherent Light Source (SLAC) and a custom-built split-and-delay line for hard x rays, we achieve the temporal resolution needed to detect the onset of the transition. Our data show no loss of long-range order up to 150 ± 40 fs from photoabsorption, which we interpret as the time needed for the electronic system to equilibrate at or above the critical nonthermal melting temperature. Once such equilibration is reached, the loss of long-range atomic order proceeds inertially and is completed within 315 ± 40 fs from photoabsorption.
Attosecond time–energy structure of X-ray free-electron laser pulses
Here, the time–energy information of ultrashort X-ray free-electron laser pulses generated by the Linac Coherent Light Source is measured with attosecond resolution via angular streaking of neon 1s photoelectrons. The X-ray pulses promote electrons from the neon core level into an ionization continuum, where they are dressed with the electric field of a circularly polarized infrared laser. This induces characteristic modulations of the resulting photoelectron energy and angular distribution. From these modulations we recover the single-shot attosecond intensity structure and chirp of arbitrary X-ray pulses based on self-amplified spontaneous emission, which have eluded direct measurement so far. We characterize individual attosecond pulses, including their instantaneous frequency, and identify double pulses with well-defined delays and spectral properties, thus paving the way for X-ray pump/X-ray probe attosecond free-electron laser science.
Introduction to Medical Extensible Dynamic Probabilistic Risk Assessment Tool (MEDPRAT)
A key component in the development of NASA Human Research Programs (HRP) next generation risk model, the Medical Extensible Dynamic Probabilistic Risk Assessment Tool (MEDPRAT) intends to deliver a means to quantify how HRP products impact astronaut medical and health risks. MEDPRAT is extensible to the majority of exploration missions. Similar to other risk models, the tool utilizes the available space and terrestrial medical data. MEDPRAT is designed to be extended with additional human health research information, medical equipment, space and terrestrial standards and practices to assess space flight medical risk in a manner consistent with other risk measures used in spacecraft and mission design. This tool provides risk-based medical system design information necessary to evaluate new technologies, procedures, research insights and mission plans.
Gamma-ray mirror technology for NDA of spent fuel
Direct measurements of gamma rays emitted by fissile material have been proposed as an alternative to measurements of the gamma rays from fission products. From a safeguards applications perspective, direct detection of uranium (U) and plutonium (Pu) K-shell fluorescence emission lines and specific lines from some of their isotopes could lead to improved shipper-receiver difference or input accountability at the start of Pu reprocessing. However, these measurements are difficult to implement when the spent fuel is in the line-of-sight of the detector, as the detector is exposed to high rates dominated by fission product emissions. To overcome the combination of high rates and high background, grazing incidence multilayer mirrors have been proposed as a solution to selectively reflect U and Pu hard X-ray and soft gamma rays in the 90 to 420 keV energy into a high-purity germanium (HPGe) detector shielded from the direct line-of-sight of spent fuel. Several groups demonstrated that K-shell fluorescence lines of U and Pu in spent fuel could be detected with Ge detectors. In the field of hard X-ray optics the performance of reflective multilayer coated reflective optics was demonstrated up to 645 keV at the European Synchrotron Radiation Facility. Initial measurements conducted at Oak Ridge National Laboratory with sealed sources and scoping experiments conducted at the ORNL Irradiated Fuels Examination Laboratory (IFEL) with spent nuclear fuel further demonstrated the pass-band properties of multilayer mirrors for reflecting specific emission lines into 1D and 2D HPGe detectors, respectively.
Ultraviolet laser transverse profile shaping for improving x-ray free electron laser performance
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Study of η and η ′ Photoproduction at MAMI
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Measurement of the ω → π 0 e + e - and η → e + e - γ Dalitz decays with the A2 setup at the Mainz Microtron
The Dalitz decays η → e + e - γ and ω → π 0 e + e - have been measured in the γp → ηp and γp → ωp reactions, respectively, with the A2 tagged-photon facility at the Mainz Microtron. The value obtained for the slope parameter of the electromagnetic transition form factor of η, Λ$-2\atop{η}$ = (1.97 ± 0.11 tot ) GeV -2 , is in good agreement with previous measurements of the η → e + e - γ and η → μ + μ - γ decays. The uncertainty obtained in the value of Λ$-2\atop{η}$ is lower than in previous results based on the η → e + e - γ decay. The value obtained for the ω slope parameter, Λ$-2\atop{ωπ^0}$ = (1.99 ± 0.21 tot ) GeV -2 , is somewhat lower than previous measurements based on ω → π 0 μ + μ - , but the results for the ω transition form factor are in better agreement with theoretical calculations, compared to earlier experiments.
Self-referenced coherent diffraction x-ray movie of Angstrom- and femtosecond-scale atomic motion
Abstract Not Provided
Measurement of the π 0 → e + e - γ Dalitz decay at the Mainz Microtron
The Dalitz decay π 0 → e + e - γ has been measured in the γp → π 0 p reaction with the A2 tagged-photon facility at the Mainz Microtron, MAMI. The value obtained for the slope parameter of the π 0 electromagnetic transition form factor, a π = 0.030 ± 0.010 tot , is in agreement with existing measurements of this decay and with recent theoretical calculations. The uncertainty obtained in the value of a π is lower than in previous results based on the π 0 → e + e - γ decay.
Photon asymmetry measurements of $\overrightarrow{\gamma}p \rightarrow \pi^{0} p$ γ → p → π 0 p for $E_{\gamma}=$ 320-650 MeV
High-statistics measurements of the photon asymmetry Σ for the $\overrightarrow{\gamma}p \rightarrow \pi^{0} p$ reaction have been made in the center-of-mass energy range W = 1214–1450 MeV. The data were measured with the MAMI A2 real photon beam and Crystal Ball/TAPS detector systems in Mainz, Germany. The resulting measurements significantly improve the existing world data and are shown to be in good agreement with previous measurements, and with the MAID, SAID, and Bonn-Gatchina predictions. We have also combined the photon asymmetry results with recent cross-section measurements from Mainz to calculate the profile functions, $\check{Σ}$ (= σ 0 Σ), and perform a moment analysis. Comparison with calculations from the Bonn-Gatchina model shows that the precision of the data is good enough to further constrain the higher partial waves, and there is an indication of interference between the very small F-waves and the N(1520)3/2 - and N(1535)1/2 - resonances.