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Robb, Kevin R.

Publications and source records attributed to Robb, Kevin R..

At least 19 records

Density Measurements of Molten LiF–BeF 2 and LiF–BeF 2 –LaF 3 Salt Mixtures by Neutron Radiography

The densities of eutectic (LiF) 2 –BeF 2 and mixtures of this salt (FLiBe) with LaF 3 were measured by dilatometry and by neutron attenuation from 673 K to 1,073 K. Because LaF 3 has a limited solubility in FLiBe, it was necessary to determine the amount of LaF 3 in solution before the density could be determined. The FLiBe density determination was favorably benchmarked against the literature data. A simple comparison was not available for the LaF 3 –FLiBe mixtures, so extrapolation of published data was necessary based on analysis using the Molten Salt Thermal Properties Database-Thermochemistry, or MSTDB-TC, developed by the US Department of Energy. Solubilities for LaF 3 in FLiBe ranged from 1 to 4 mol % over 673 to 1,073 K. The salt system was heated and cooled over 24 h to evaluate potential changes in composition and hysteresis during the measurement. Changes in the meniscus were observed, and these were included in the correction for density determinations. Salt surface tension may have led to supersaturation of LaF 3 in the salt because the solubility curve was nonlinear with respect to the inverse temperature, as would be expected for an ideal system. Surface tension measurements are currently underway to test this hypothesis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Start-up Operation Experience with a Liquid Fluoride Salt Forced Convection Loop

A liquid fluoride salt forced convection test loop was constructed at Oak Ridge National Laboratory. Its unique features include a pebble bed test section, high-temperature instrumentation, a noncontact rotating gas seal for the pump, a silicon carbide flow tube, and a unique inductive heating technique. Initial startup and shake-down testing has been completed. This paper describes how several of the systems performed, highlights those that worked well, and discusses issues that arose during the start-up process. This discussion should be of interest to those who intend to develop molten salt technologies and who are interested in some of the specific techniques used in this experiment.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

The effect of interfacial phenomena on gas solubility measurements in molten salts

The behavior of fission gases in molten fuel salt reactors governs activity transport from the reactor and can also affect the performance of the reactor itself. The gas solubility can be described thermodynamically by Henry’s law. However, the coupling of the condensed and gas phases depends on the interfacial area, which is difficult to measure or even to estimate. Surfaces of materials in the reactor will include disperse phases in the salt and porosity within the structural materials, covering a range of compositions and sizes. These attributes can affect measurements of fundamental properties such as gas solubility. Methods to obtain gas solubility, surface tension, interfacial energies, and bubble gas transport are reviewed. Recent data from manometric experiments are interpreted based on xenon sorption onto salt-wetted quartz.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Material Selection and Corrosion Studies of Candidate Bearing Materials for Use in Molten Chloride Salt

Molten chloride salts are being given strong consideration for use in heat transfer and storage in concentrating solar power (CSP) systems as well as in some nuclear reactor applications. Containment of the molten salt, particularly at the highest temperatures, is a major material concern and has received considerable study. Another material issue is the pumps that will be required to move the molten salt along with the bearing materials that will be required to have sufficient corrosion resistance as well as wear resistance in the high temperature salt. A pair of coordinated studies in our laboratory has addressed the corrosion, and the wear issues of candidate bearing materials including the selection of candidate materials as well as their performance in a molten sodium chloride-potassium chloride-magnesium chloride salt environment. This work addresses the selection of candidate materials and their chemical compatibility with the molten salt. The studies have identified material pairs that have suitable properties for use as bearings that would be immersed in molten chloride salt.

14 SOLAR ENERGY↗

Engineering-Scale Batch Purification of Ternary MgCl 2 -KCl-NaCl Salt Using Thermal and Magnesium Contact Treatment

High-temperature molten chloride salts are a desirable heat transfer and energy storage media. The NaCl-KCl-MgCl 2 is of particular interest because of its low melting point and relatively inexpensive constituents. Moisture and hydroxides must be removed from the salt to control corrosion at high temperatures. Previous studies have developed and demonstrated various techniques for bench-scale salt purifications. This paper details the system, process, and insight gained in the purification of a 200 kg scale batch of NaCl-KCl-MgCl 2 salt at Oak Ridge National Laboratory.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Chloride Salt Purification by Reaction With Thionyl Chloride Vapors to Remove Oxygen, Oxygenated Compounds, and Hydroxides

Molten chloride salts (including MgCl 2 , KCl, NaCl, and ZnCl 2 ) are being considered for heat transfer media for renewable (solar) and nuclear power generators, as fuel carrier for nuclear reactors, and as thermal energy storage media. Impurities such as oxygen, hydroxides, moisture, and sulfur are known to negatively influence the corrosion of materials in contact with the salt (e.g., structural metals). Commercially available chloride salts come with a range of impurities. Before using the chloride salts at high temperature, it is desirable to remove the impurities to increase the performance of the salt and reduce corrosion. In this study, we tested the use of thionyl chloride vaporized into a stream of argon to react with oxygenated impurities in a mixture of MgCl 2 -KCl-NaCl, removing them as HCl and SO 2 . The reagent was bubbled through the salt when both above and below the melting point. The reaction was followed using thermocouple data from the salt and by Fourier transform infrared (FTIR) spectroscopy on the exhaust of the reactor. The reaction kinetics were followed by comparing the peaks from SO 2 product to SOCl 2 reagent in the FTIR spectra. The purity of the salt was assessed at the end of the purification process by x-ray diffraction and inductively coupled plasma analysis. Although the process was effective in removing the oxygen content of the mixture, ternary compounds were formed in the process, including KNiCl 3 and KMgCl 3 . The nickel in KNiCl 3 came from the reaction between the salt and the nickel vessel. Thus, these experiments suggest that improvements to the process must be made before using SOCl 2 vapors for the purification of chloride salts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Simplified High-Temperature Molten Salt CSP Plant Preconceptual Design

State of the art concentrating solar power plants generally rely on a two-tank system with a large central tower. These plants employ nitrate salts that are limited to approximately 565°C in practice. A novel system arrangement is proposed using molten salt as the heat transfer and energy storage media in a single thermocline storage tank with an integral heat exchanger to the power cycle. The system has unique features that enable temperatures higher than 565°C while reducing costs. This study explores the considerations for the concept and presents a preconceptual point design for a 5 MWt system capable of generating 100 MWt per day with 12 hours of thermal energy storage. This study also examines the potential operation of the system with nitrate and higher temperature chloride salts. Both salt systems appear promising and future concept maturation is recommended.

14 SOLAR ENERGY↗

Corrosion of 316H Stainless Steel Specimens in Two FLiBe (LiF-BeF 2 ) Salt Batches

This milestone was originally envisioned for completion in FY21 and was delayed due to the COVID-19 response and difficulties in fabricating fluoride salts. To complete the milestone, commercial FLiBe was compared to a batch of FLiBe produced by the conventional hydrofluorination process. However, the batch was stopped early due to an HF leak and the salt did not undergo the final H2 sparging. Subsequent static compatibility testing of 316H specimens in 316H capsules resulted in small mass losses for the commercial FLiBe and much larger mass losses for the 2nd batch of FLiBe.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Effects of Particle Size and Concentration of Magnesium Oxide on the Lubricating Performance of a Chloride Molten Salt for Concentrating Solar Power

One engineering challenge for the next-generation concentrating solar power (CSP) is to identify appropriate heat transfer and thermal energy storage media. A chloride salt mixture (20 wt % NaCl + 40 wt % MgCl 2 + 40 wt % KCl) in a molten phase is proposed as a potential fluid for carrying the heat as well as lubricating the CSP pump bearings. Due to the hygroscopic nature of MgCl 2 , the presence of magnesium oxide (MgO) particles is inevitable. In order to understand the impact of MgO particles, this study investigated the tribological behavior of the molten chloride salt mixture containing MgO of various particle sizes and concentrations. Tests were conducted at 750 °C in a dry Ar environment using a zirconia ball sliding against a Haynes 244 alloy disc lubricated by the molten salt. There was a clear trend of the increased friction coefficient and wear loss for a larger particle size and/or a higher concentration of MgO. Distinct wear mechanisms were identified for the ceramic ball and alloy disc. Results provide fundamental insights for this new research avenue of molten salt lubrication for CSP.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

RELAP-7 Application and Enhancement for FLEX Strategies and ATF Behavior under Extended Loss of AC Power Conditions

This report summarizes the results of a three-year research project sponsored by the U.S. Department of Energy (DOE) Nuclear Energy University Program (NEUP) to enhance and apply the RELAP-7 code by adding and improving several important components (e.g., a mechanistic Reactor Core Isolation Cooling (RCIC) system model) for thermal hydraulic studies of LWRs under ELAP conditions and evaluating the time available for transition to portable FLEX equipment. The project team included University of Massachusetts–Lowell, The Ohio State University, Texas A&M University, Idaho National Laboratory and Oak Ridge National Laboratory. In the Fukushima accident, it was found that the RCIC system played a crucial role in delaying core meltdown by almost three days in Fukushima Daiichi Unit 2, because of self-regulated operation of the steam driven RCIC turbine-pump injection system. Steam flow in the convergent-divergent nozzles of the RCIC Terry turbine is two-phase non-equilibrium transonic flow with homogenous nucleation condensation. To more accurately predict the dynamic process and behavior of the transonic compressible steam flow, a one-dimensional transient two-phase analytical model is presented. A simplified four-fluid model was employed in the present work with the consideration of four separate fluid fields: vapor, liquid film, entrained droplets and condensed droplets. The mass, momentum and energy interactions between the fluids were considered and modeled. An extended seven-equation non-equilibrium critical flow model was developed to obtain the critical pressure and velocities of each phase at the nozzle throat. To predict the wetness in the divergent section, a mechanistic nucleation condensation model was integrated in the nozzle analysis model, considering the generation and consequent growth of droplets. The governing differential equations on a staggered grid were discretized using the second-order Lax-Wendroff scheme with a flux limiter, and the Semi-Implicit Method for Pressure-Linked Equation (SIMPLE) algorithm was employed to solve the discrete linear system. To demonstrate the predictability and reliability of the physical models and the numerical method proposed in the present work, three representative nozzles were modeled and simulated. The results show good agreement with the available experimental data, even for condensation shock. Then, the 1D nozzle model was employed to obtain nozzle flow tables of the Terry turbine nozzle for different working pressures which can cover the operation pressure range of the RCIC system. A mechanistic RCIC turbine-pump system model was developed and implemented in the system code TRACE to simulate dynamic responses of the RCIC system under Beyond Design Basis Accident (BDBA) conditions. The turbine-pump governing equations are based on the control volume approach of the angular momentum balance. The physics based mechanistic RCIC model was developed using the TRACE control system components (i.e., signal variables, control blocks, and tables), and incorporated into a TRACE boiling water reactor (BWR) model. The TRACE model in this report has a detailed nodalization of the reactor pressure vessel (RPV), and all of the major flow paths and system components, including the safety relief valves (SRVs) and the containment suppression pool and drywell. Based on the nozzle flow tables generated from the 1D nozzle model developed, the turbine drive torque can be calculated from table lookup. Since the detailed specifications of the RCIC pump are unavailable, the homologous curves for a Bingham pump were used in the current pump component. A station black-out (SBO) accident test problem was selected to demonstrate the TRACE RCIC model. The short-term SBO simulations were performed for two cladding materials: Zircaloy and FeCrAl, to demonstrate the effect of the accident tolerant fuel cladding on fuel heat-up under BDBA accident conditions. The wetwell plays a vital safety role in SBO and other BWR accident scenarios in that it can reduce containment pressure and supply additional core make-up water. The suppression pool temperature distribution has a very large impact on both RPV and containment pressure. Thus, another novel contribution of the project comes mainly from an improved, systems-level wetwell model which can capture buoyancy-induced thermal stratification effects due to steam injection and condensation. A two-zone stratified wetwell model has been implemented in RELAP-7 and some results from that model are presented. This wetwell model is capable of simulating thermal stratification due to a low steam mass injection rate. With a low mass flow rate, the model assumes that all the steam condenses within the pipe and the resulting plume can be approximated with a purely buoyant, heat-source driven model. The wetwell model developed with these assumptions is adequate to simulate slow transients such as extended SBO transients.

42 ENGINEERING↗

Facility to Alleviate Salt Technology Risks (FASTR): Preliminary Design Report with Failure Modes and Effects Analysis

The Facility to Alleviate Salt Technology Risks (FASTR) is a versatile, high-temperature (>600°C) molten chloride salt test facility designed to enable a variety of testing to advance the Generation 3 (Gen 3) Concentrated Solar Power (CSP) molten salt technology. FASTR includes a salt preparation system and a forced flow test loop with a suite of instrumentation. The FASTR loop is capable of 725°C operation, flow rates of 3–7 kg/s, includes heated and cooled sections, and swappable components to enable testing of future vendor-supplied hardware. The salt preparation system supplies large batches (e.g., 200 kg) of clean salt for use in the FASTR forced convection loop. This report summarizes the planned design and capabilities of FASTR. In addition, a failure modes and effects analysis of the system is reported.

42 ENGINEERING↗

External Cooling of the BWR Mark I and II Drywell Head as a Potential Accident Mitigation Measure – Expanded Scoping Assessment

This report documents a scoping assessment of a potential accident mitigation action applicable to the US fleet of boiling water reactors with Mark I and II containments. The mitigation action is to externally flood the primary containment vessel drywell head using portable pumps or other means. A scoping assessment of the potential benefits of this mitigation action was conducted focusing on the ability to (1) passively remove heat from containment, (2) prevent or delay leakage through the drywell head seal (due to high temperatures and/or pressure), and (3) scrub radionuclide releases if the drywell head seal leaks. This report is an expanded revision of ORNL/TM-2017/457 and includes an analysis of (1) the delay in initiating drywell head cavity flooding from 2 hours to 8 hours after accident scenario initiation and (2) the effectiveness of including additional drywell head heat transfer area.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Design and analysis of oxidation tests to inform FeCrAl ATF severe accident models

Iron-chromium-aluminum (FeCrAl) alloys are being considered as advanced fuel cladding concepts with enhan ced accident tolerance. At high temperatures, FeCrAl alloys have slower oxidation kinetics and higher strength compared with zirconium-based alloys. FeCrAl could be used for fuel cladding and spacer or mixing vane grids in light water reactors and/or as ch annel box material in boiling water reactors (BWRs). There is a need to assess the potential gains afforded by the FeCrAl accident-tolerant-fuel (ATF) concept over the existing zirconium-based materials employed today. To accurately assess the response of FeCrAl aloys under severe accident conditions, a number of FeCrAl properties and characteristics are required. These include thermophysical properties as well as burst characteristics, oxidation kinetics, possible eutectic interactions, and failure temperatures. These properties can vary among different FeCrAl alloys.

36 MATERIALS SCIENCE↗

Simulation of QUENCH-15 and Preliminary Pre-Test Predictions for QUENCH-19

Iron Chromium Aluminum alloys (FeCrAl) have been developed at Oak Ridge National Laboratory as an advanced fuel cladding for light water reactors (LWR). In contrast to zirconium-based alloys employed today, FeCrAl has slower oxidation kinetics and higher strength. A test (QUENCH-19) at Karlsruhe Institute of Technology’s QUENCH facility is planned to test and demonstrate the performance of FeCrAl cladding under postulated accident conditions. This test will replicate the previous QUENCH-15 test but will use FeCrAl instead of zirconium-based materials. During these tests, a small bundle of fuel rod simulators is electrically heated in a steam and argon environment. The temperature history, oxidation thickness, and in-situ hydrogen generation are the primary measurements of interest.The CORA/BWR code was previously developed and utilized in the 1980’s and 1990’s to simulate BWR bundle degradation during the CORA test series. A modified version of the CORA/BWR code, named CORA/BWR-QUENCH, has been developed to model the QUENCH test facility. The CORA/BWR-QUENCH code was used to model the QUENCH-15 test which used zirconium-based materials. The code predictions and test data were found to be in good agreement. The code was then used to model the planned QUENCH-19 test utilizing FeCrAl cladding, shroud, and spacer grids. The simulation predicts the peak cladding temperature to be 1620 K (~1347°C) for QUENCH-19 which is significantly lower than that during QUENCH-15 with the zirconium-based alloy. The predicted hydrogen generation is also significantly lower for the FeCrAl clad QUENCH-19 as compared to QUENCH-15: ~1.7 g versus ~48.8 g. These results align with expectations given the much slower oxidation kinetics of FeCrAl alloys.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Development of Streamlined Nuclear Safety Analysis Tool for Spent Nuclear Fuel Applications

To understand the changing nuclear and mechanical characteristics of spent nuclear fuel (SNF) or used nuclear fuel (UNF) and the different storage, transportation, and disposal systems at various stages within the waste management system, different types of analyses are required. These analyses require the use of assorted tools and numerous types of data. Using the appropriate modeling and simulation (M&S) parameters and selecting from the diversity of analytic tools to conduct SNF analyses can be a tedious, error-prone, and time-consuming undertaking for analysts and reviewers alike. A new, integrated data and analysis system was designed to simplify and automate performance of accurate, efficient evaluations for characterizing the input to the overall U.S. nuclear waste management system—the UNF-Storage, Transportation & Disposal Analysis Resource and Data System (UNF-ST&DARDS). A relational database has been assembled to provide a standard means by which UNF-ST&DARDS can succinctly store and retrieve M&S parameters for specific SNF analysis. A library of various analysis model templates is used to communicate M&S parameters for the most appropriate M&S application. A process manager facilitates performance of actual as-loaded, assembly-specific, and cask-specific evaluations. Interactive visualization capabilities facilitate data analysis and results interpretation. To date, UNF-ST&DARDS has completed (1) explicit depletion and decay analysis of every fuel assembly (~245 000) discharged from commercial U.S. reactors through June 2013, with 13 cooling time steps (results include isotopic compositions for 142 isotopes, and radiation and thermal source terms); (2) SNF radiation dose rate evaluations at 1 m for all the fuel assemblies discharged through June 2013; and (3) criticality, shielding, thermal, and containment analyses of hundreds of loaded casks. In conclusion, UNF-ST&DARDS also provides various automated report generation capabilities with dynamic figure and table update capabilities based on changes to the Unified Database.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Thermal Analysis Capability of UNF-ST&DARDS

In the United States, approximately 2,500 casks are loaded with commercial spent nuclear fuel (SNF) that has transitioned from wet storage (spent fuel pools) to dry storage. The number of loaded dry storage casks is increasing by approximately 200 each year. Over time, cask designs have evolved to enhance safety and to accommodate more fuel and higher heat loads. Also, higher burnup fuel is being transitioned into dry storage. The SNF is being stored in dry casks for longer times than specified in the original certification period. Several degradation mechanisms related to fuel assemblies and canisters are affected by temperature. For the cladding, temperature-dependent phenomena include creep and annealing, hydride reorientation and embrittlement, and the ductile-to-brittle transition. Temperature can also influence phenomena that affect the long-term integrity of the storage system, including deliquescence, corrosion, and stress-corrosion cracking. Therefore, accurate determination of the temperatures of various components is needed to evaluate potential safety-related issues during transportation after extended storage and to ensure SNF retrievability. The Used Nuclear Fuel-Storage, Transportation & Disposal Analysis Resource and Data System (UNF ST&DARDS) is being developed for the US Department of Energy Office of Nuclear Energy to streamline analyses for the waste management system [1]. Lastly, the thermal analysis capability within UNF-ST&DARDS and example results are discussed herein.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

External Cooling of the BWR Mark I and II Drywell Head as a Potential Accident Mitigation Measure – Scoping Assessment

This report documents a scoping assessment of a potential accident mitigation action applicable to the US fleet of boiling water reactors with Mark I and II containments. The mitigation action is to externally flood the primary containment vessel drywell head using portable pumps or other means. A scoping assessment of the potential benefits of this mitigation action was conducted focusing on the ability to (1) passively remove heat from containment, (2) prevent or delay leakage through the drywell head seal (due to high temperatures and/or pressure), and (3) scrub radionuclide releases if the drywell head seal leaks.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗