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Riccitiello, S. R.

Publications and source records attributed to Riccitiello, S. R..

At least 37 records · Page 2

Intumescent coatings based on 4,4 prime-dinitrosulfanilide

Nitroaromatic amine-based intumescent coatings which offer improved thermal protection to a substrate by reducing the backface temperature rise have been developed. The intumescent monomer agent is 4,4 prime-dinitrosulfanilide. This agent has an intumescent temperature of 220 deg C, compared with 300 deg C for the ammonium salt of 1,4-nitroaniline-2-sulfonic acid and offers a twelve-fold reduction in water solubility over this compound. On the basis of differential thermal analysis and screening tests, a chlorinated polyolifin epoxy-reactive butadiene acrylonitrile rubber blend was selected as a flame quenching binder.

Sawko, P. M.↗

An improved automotive brake lining using fibrous potassium titanate

Simultaneous fade reduction and wear improvement of a commercial automotive brake lining were achieved by adding fibrous potassium titanate. The dependence of friction and wear characteristics on quantitative variations in potassium titanate, asbestos, phenolic binder, and organic and inorganic modifiers was evaluated.

Mansfield, J. A.↗

Polymeric foams stable at high temperatures

Crosslinked poly(N-arylenebenzimidazoles) are stable up to 370 C. Polymers are made by mixing appropriate stoichiometric amounts of tetramine and aromatic dicarboxylic acid anhydride with phenol or alkyl-substituted phenol.

Riccitiello, S. R.↗

Developments in new aircraft tire tread materials

Comparative laboratory and field tests were conducted on experimental and state-of-the-art aircraft tire tread materials in a program aimed at seeking new elastomeric materials which would provide improved aircraft tire tread wear, traction, and blowout resistance in the interests of operational safety and economy. The experimental stock was formulated of natural rubber and amorphous vinyl polybutadiene to provide high thermal-oxidative resistance, a characteristic pursued on the premise that thermal oxidation is involved both in the normal abrasion or wear of tire treads and probably in the chain of events leading to blowout failures. Results from the tests demonstrate that the experimental stock provided better heat buildup (hysteresis) and fatigue properties, at least equal wet and dry traction, and greater wear resistance than the state-of-the-art stock.

Yager, T. J.↗

An effective and practical fire-protection system

A high-performance sandwich-type fire protection system comprising a steel outer sheath and insulation combined in various configurations is described. An inherent advantage of the sheath system over coatings is that it eliminates problems of weatherability, materials strength, adhesion, and chemical attack. An experimental comparison between the protection performance of state-of-the-art coatings and the sheath system is presented, with emphasis on the protection of certain types of steel tanks for fuel storage and transport. Sheath systems are thought to be more expensive than coatings in initial implementation, although they are less expensive per year for sufficiently long applications.

Mansfield, J. A.↗

Intumescent coating modeling

A thermal response mathematical model for an intumescent coating system is developed. The model predicts indepth temperature profiles of the solid as a function of the fundamental kinetic, mass, and heat-transfer properties of the original coating system. In the model, swelling is based on an empirical function of the paint's weight loss. The model is used to describe the effectiveness of the coating for thermal protection. Using the thermal response time at the backface of the material as a criterion, a sensitivity analysis is made with respect to variation in individual properties, such as total expansion, to provide a guide for designing improved intumescing agents. The sensitivity analysis shows that total expansion and rate of expansion, along with other material properties, are important parameters for providing thermal protection. Finally, backface temperature histories are predicted and compared to experimental data obtained from a representative fire environment. Predicted temperatures agree within a maximum error of plus or minus 20%.

Cagliostro, D. E.↗

Intumescent composition, foamed product prepared therewith and process for making same

An intumescent composition and the foamed product prepared by heating the composition are provided. The composition comprises the reaction product of para-benzoquinone dioxime and a concentrated mineral acid such as sulfuric acid, phosphoric acid, and polyphosphoric acid. The composition is useful as an intumescent agent either by itself or when combined with other materials. A fire-resistant and heat-insulating composition is provided by heating the intumescent composition above its intumescent temperature.

Riccitiello, S. R.↗

Flexible fire retardant polyisocyanate modified neoprene foam

Lightweight, fire resistant foams have been developed through the modification of conventional neoprene-isocyanate foams by the addition of an alkyl halide polymer. Extensive tests have shown that the modified/neoprene-isocyanate foams are much superior in heat protection properties than the foams heretofore employed both for ballistic and ablative purposes.

Parker, J. A.↗

The application of space program fire retardant technology to housing

A review of the NASA fire research and developed fire retardant materials is presented with the objective to analyze and evaluate the concepts and materials to determine the practical applicability to the housing industry. The report presents the NASA materials, their performance in a fire environment and areas where further evaluation is required. The review establishes where advancements in the state of the art have been achieved and points out reasons why these advancements can not be directly applied to the housing industry in the near future.

Riccitiello, S. R.↗

Intumescent composition, foamed product prepared therewith, and process for making same

An intumescent composition and the foamed product prepared by heating are discussed wherein the composition comprises the reaction product of para-benzoquinone dioxime and a concentrated mineral acid such as sulfuric acid, phosphoric acid, and polyphosphoric acid. The composition is useful as an intumescent agent either by itself or when combined with other materials. A fire-resistant and heat-insulating composition is provided by heating the intumescent composition above its intumescent temperature.

Riccitiello, S. R.↗

An intumescent coating for improved fuel fire protection of heat sensitive articles.

Intumescent coating compositions have been prepared using the ammonium salt of 4-nitroaniline-2-sulfonic acid and a copolymer of polysulfide-epoxy resin as the binder, into which have been dispersed various fillers. The fillers used in the study were low density microballoons for density control and fibers for controlled intumescence on contoured substrates. The filler effect on the thermal-physical efficiency of coatings has been measured. The coating utilizing short length silica fibers has been shown to have superior mechanical, environmental, and thermal properties. The coating applied to the exterior of loaded weapons has increased the time-to-detonation from three minutes for the unprotected weapon to 10-13 minutes.

Sawko, P. M.↗

Fire retardant polyisocyanurate foam

Fire retardant properties of low density polymer foam are increased. Foam has pendant nitrile groups which form thermally-stable heterocyclic structures at temperature below degradation temperature of urethane linkages.

Riccitiello, S. R.↗

Intumescence: An in situ approach to thermal protection

The thermal protection of flammable structures with intumescent protective coatings is discussed. Various materials which have demonstrated an ability to provide protection through intumecence are described. Materials tests for intumescent coatings are presented and physical properties of various materials are included.

Fohlen, G. M.↗