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Rebentrost, Patrick

Publications and source records attributed to Rebentrost, Patrick.

Quantum Optimization: Potential, Challenges, and the Path Forward

Recent advances in quantum computers are demonstrating the ability to solve problems at a scale beyond brute force classical simulation. As such, a widespread interest in quantum algorithms has developed in many areas, with optimization being one of the most pronounced domains. Across computer science and physics, there are a number of algorithmic approaches, often with little linkage. This is further complicated by the fragmented nature of the field of mathematical optimization, where major classes of optimization problems, such as combinatorial optimization, convex optimization, non-convex optimization, and stochastic extensions, have devoted communities. With these aspects in mind, this work draws on multiple approaches to study quantum optimization. Provably exact versus heuristic settings are first explained using computational complexity theory — highlighting where quantum advantage is possible in each context. Then, the core building blocks for quantum optimization algorithms are outlined to subsequently define prominent problem classes and identify key open questions that, if answered, will advance the field. The effects of scaling relevant problems on noisy quantum devices are also outlined in detail, alongside meaningful benchmarking problems. We underscore the importance of benchmarking by proposing clear metrics to conduct appropriate comparisons with classical optimization techniques. Lastly, we highlight two domains – finance and sustainability – as rich sources of optimization problems that could be used to benchmark, and eventually validate, the potential real-world impact of quantum optimization.

97 MATHEMATICS AND COMPUTING↗

Room-Temperature Micron-Scale Exciton Migration in a Stabilized Emissive Molecular Aggregate

We report 1.6 ± 1 μm exciton transport in self-assembled supramolecular light-harvesting nanotubes (LHNs) assembled from amphiphillic cyanine dyes. We stabilize LHNs in a sucrose glass matrix, greatly reducing light and oxidative damage and allowing the observation of exciton–exciton annihilation signatures under weak excitation flux. Fitting to a one-dimensional diffusion model, we find an average exciton diffusion constant of 55 ± 20 cm 2 /s, among the highest measured for an organic system. We develop a simple model that uses cryogenic measurements of static and dynamic energetic disorder to estimate a diffusion constant of 32 cm 2 /s, in agreement with experiment. We ascribe large exciton diffusion lengths to low static and dynamic energetic disorder in LHNs. We argue that matrix-stabilized LHNS represent an excellent model system to study coherent excitonic transport.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantum simulator of an open quantum system using superconducting qubits: exciton transport in photosynthetic complexes

Open quantum system approaches are widely used in the description of physical, chemical and biological systems. A famous example is electronic excitation transfer in the initial stage of photosynthesis, where harvested energy is transferred with remarkably high efficiency to a reaction center. This transport is affected by the motion of a structured vibrational environment, which makes simulations on a classical computer very demanding. Here we propose an analog quantum simulator of complex open system dynamics with a precisely engineered quantum environment. Our setup is based on superconducting circuits, a well established technology. As an example, we demonstrate that it is feasible to simulate exciton transport in the Fenna–Matthews–Olson photosynthetic complex. Our approach allows for a controllable single-molecule simulation and the investigation of energy transfer pathways as well as non-Markovian noise-correlation effects.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Forster Coupling in Nanoparticle Excitonic Circuits

Exciton transport in semiconductor nanoparticles underlies recent experiments on electrically controlled nanostructures and proposals for new artificial light-harvesting systems. In this work, we develop a novel method for the numerical evaluation of the Förster matrix element, based on a three-dimensional real space grid and the self-consistent solution of the mesoscopic exciton in a macroscopic dielectric environment. This method enables the study of the role of the nanoparticle shape, spatially varying dielectric environments, and externally applied electric fields. Depending on the orientation of the transition dipole, the Förster coupling is shown to be either increased or decreased as a function of the nanoparticle shape and of the properties of the dielectric environment. In the presence of an electric field, we investigate the relation between excitonic binding and confinement effects. We also study a type II core-shell quantum dot where electron and hole are spatially separated due to a particular configuration of the bandstructure.

77 NANOSCIENCE AND NANOTECHNOLOGY↗