The nu 2 spectrum of NH3
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Engineering topics
Publications and source records attributed to Poynter, R. L..
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The entire set of Voyager plasma wave observations at Saturn is summarized and attention is focused on several specific problem areas. The topics that are emphasized include (1) the size and location of the Saturn foreshock, (2) possible detection of the Jovian magnetic tail after the Saturn encounter, (3) pitch angle scattering of electrons by equatorial whistler mode emissions, and (4) the detection of dust impact signals near the ring plane and at other locations in the magnetosphere.
The new edition of the AFGL trace gas compilation is described. The latest version provides the necessary parameters for the computation of absorption or emission spectra of major bands of twenty-one gases in the region from 0 to 10,000 per cm. Emphasis in this edition has been on the addition of numerous millimeter and submillimeter transitions, the inclusion of bands of significance in upper atmospheric processes, and strong IR bands of trace constituents likely to be used for remote detection. The sources for the additions and modifications of the absorption parameters are summarized.
The NH3 far infrared spectrum is particularly useful for the study of planetary composition and atmospheric dynamics. Studies of this spectrum were conducted by Dowling (1969), Helminger et al. (1971), and Urban et al. (1981). Sattler et al. (1981) have reported measurements of a few nu2 lines with tunable diode lasers. By using simple sum rules, these lines and accurate ground state inversion lines considered by Poynter and Kakar (1975) have been employed in the present investigation to deduce a few of the far infrared ground state transitions. An extensive set of high signal/noise, high resolution (0.0048 per cm) scans of the nu2 bands of NH3 from about 600 per cm through about 1300 per cm ait a series of low pressures have been made in order to accurately determine both the line positions and strengths. The obtained data provide line positions with an absolute accuracy of about 0.0001 per cm in the more favorable cases.
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The first inbound Voyager 2 crossing of Saturn's bow shock (at 31.7 Saturn radii near local noon) and the last outbound crossing (at 87.4 Saturn radii near local dawn) had similar plasma wave signatures. However, many other aspects of the plasma wave measurements differed considerably during the inbound and outbound passes, suggesting the presence of effects associated with significant north-south or noon-dawn asymmetries, or temporal variations. Within Saturn's magnetosphere, the plasma wave instrument detected electron plasma oscillations, upper hybrid resonance emissions, half-gyrofrequency harmonics, hiss and chorus, narrowband electromagnetic emissions and broadband Saturn radio noise, and noise bursts with characteristics of static. At the ring plane crossing, the plasma wave instrument also detected a large number of intense impulses that were interpreted in terms of ring particle impacts on Voyager 2.
The electron density measurements obtained in the Jovian magnetosphere from the plasma wave instruments on the Voyager 1 and 2 spacecraft are summarized. Three basic techniques for determining the electron density are discussed. They are (1) local measurements from the low-frequency cutoff of continuum radiation, (2) local measurements from the frequency of upper hybrid resonance emissions, and (3) integral measurements from the dispersion of whistlers. The limitations and advantages of each technique are reviewed.
Observations of locally trapped nonthermal continuum radiation and distant encounters with the Jovian magnetotail are reported. An attempt is made to deduce information on the morphology of the distant tail of Jupiter. It is noted that the observations of continuum radiation trapped in low-density regions of the solar wind suggest that Voyager may at times be connected to the distant tail by a low-density trough which acts as a wave guide and allows radiation from the tail to reach the spacecraft.
The line widths, pressure-induced shifts, and center frequency of the J = 1-0, K = 0 phosphine transition at 266.9 GHz have been determined. The widths and shifts are reported for collisions with phosphine, H2, and He.
A computer accessible catalogue of submillimeter, millimeter and microwave spectral lines in the frequency range between 0 and 3000 GHZ (i.e., wavelengths longer than 100 mu m) is presented which can be used a planning guide or as an aid in the identification and analysis of observed spectral lines. The information listed for each spectral line includes the frequency and its estimated error, the intensity, lower state energy, and quantum number assignment. The catalogue was constructed by using theoretical least squares fits of published spectral lines to accepted molecular models. The associated predictions and their estimated errors are based upon the resultant fitted parameters and their covariances. Future versions of this catalogue will add more atoms and molecules and update the present listings (133 species) as new data appear. The catalogue is available as a magnetic tape recorded in card images and as a set of microfiche records.
Sulfur dioxide has a strong and complex rotational spectrum in the microwave and far infrared regions. The microwave absorption due to SO2 in a CO2 mixture is calculated for conditions applicable to the Venus atmosphere. It is shown that at the concentrations detected by Pioneer-Venus in situ measurements, SO2 may be expected to contribute significantly to the microwave opacity of the Venus atmosphere. In particular, SO2 might provide the major source of opacity in the atmospheric region immediately below the main sulfuric acid cloud deck. The spectrum is largely nonresonant at the pressures where SO2 is expected to occur, however.
A computer accessible catalogue of submillimeter, millimeter, and microwave spectral lines in the frequency range between O and 3000 GHz (such as; wavelengths longer than 100 m) is discussed. The catalogue was used as a planning guide and as an aid in the identification and analysis of observed spectral lines. The information listed for each spectral line includes the frequency and its estimated error, the intensity, lower state energy, and quantum number assignment. The catalogue was constructed by using theoretical least squares fits of published spectral lines to accepted molecular models. The associated predictions and their estimated errors are based upon the resultant fitted parameters and their covariances.
A new component of the Jovian radio spectrum has been observed by the plasma wave instruments on Voyager 1 and 2 at frequencies ranging from about 10 to 56 kHz or higher. This Jovian kilometric radiation is characterized by storms of emissions lasting typically 45 minutes at 56.2 kHz, however some events persist for as long as four hours. The storms usually exhibit impulsive bursts with time scales of a few seconds to several minutes, although some events show smoothly varying intensities as a function of time. High resolution frequency-time spectrograms reveal a continuum-like background with more intense, narrowband features superimposed. The narrowband, or discrete, features tend to decrease in frequency with increasing time, falling about 1 kHz in 5 to 60 seconds. The maximum power emitted assuming an isotropic radiator near Jupiter and a bandwidth for the most intense bursts of about 10 kHz is about 10 to the 19th watts. The Jovian kilometric radiation is most likely observed within + or - 45 deg of 200 deg System III longitude, lambda III, although there is a secondary maximum near lambda III = 25 deg.
Voyager 1 measurements of wave-particle interactions of Jupiter's bow shock are reported. Some of the wave phenomena detected during the spacecraft's third inbound passage are discussed. The results indicate that the Jovian magnetosheath was characterized by a virtual absence of detectable plasma wave turbulence after passage through the bow shock and that there were impulsive wave structures within the shock with durations as small as 1, 2, or 3 sec.
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It is shown through the use of weighting functions that Jupiter's brightness temperature in the wavelength range 0.8-1.5 cm contains information on the thermal structure and abundance of ammonia in and above the tropopause in Jupiter's atmosphere. We present new data of Jupiter's brightness temperature in this wavelength range, and compare the results with theoretical spectra. The pressure in the Jovian atmosphere is estimated from these data to be 0.48 atm at 130 K.
Hydroxyl free radical microwave spectrum definition by doubling transitions frequency predictions, noting radio astronomy applicability
Microwave spectrum of all monosubstituted carbon and boron isotopic forms and one disubstituted boron isotopic form of 2,4-dicarbaheptaborane