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Pinto, J.

Publications and source records attributed to Pinto, J..

The natural and perturbed troposphere

A quantitative assessment of the chemical and climatic effects of industrial emissions into the atmosphere requires an understanding of the complex interactions of species within the atmosphere and of the atmosphere with other physical systems such as the oceans, lithosphere, and biosphere. The concentration of a particular species is determined by competition between various production and loss processes. The abundances of tropospheric gases are examined. The reactions of the members of the oxygen group are considered along with the models which have been developed to describe the involved relationships. Attention is also given to the natural carbon cycle, perturbations to the carbon cycle, the natural nitrogen cycle, perturbations to the nitrogen cycle, the hydrogen group, the sulfur group, and the halogen group.

Stewart, R. W.

Tropospheric ozone

Photochemical equilibrium models have been used to study the effect of recent revisions in important chemical reaction rates on the calculated tropospheric ozone concentration. Reasonable agreement with observed values is obtained if the NO(x) background is approximately 0.02 to 0.03 ppb, about an order of magnitude less than used in many previous model studies, but consistent with present nitrogen budget considerations and with observations of NO2. Chemical production and loss of ozone may dominate transport terms depending on values of key chemical rate constants and of the NO(x) background. This is consistent with the structure observed in the mean annual latitudinal distribution of ozone since ozone is its own chemical precursor and regions of enhanced stratosphere-troposphere exchange are also regions of enhanced photochemical activity.

Stewart, R. W.