Engineering topics

Pickering, Kenneth E.

Publications and source records attributed to Pickering, Kenneth E..

44 records · Page 3

NASA NTRS1993

Upper tropospheric ozone production following mesoscale convection during STEP/EMEX

The chemistry and dynamics of a convective system observed on February 2, 1987 in the EMEX and STEP campaigns are analyzed. Chemical and thermodynamic profiles in undisturbed air near the EMEX 9 system indicate that the troposphere was well mixed by previous convection. As a consequence there was little direct transport from the boundary layer to the upper troposphere and air transported upward was detrained throughout the middle and upper troposphere. There was minimal effect on O3 production. Other convective complexes located 800-900 km upstream produced greater perturbations on trace gas profile immediately below the tropopause. Ozone production was reduced by about 0.25 ppbv/d at these altitudes, representing a reduction in P(O3) of 15-20 percent over the column from 14.5 to 17 km. P(O3) from 12 to 17 km in a region distant from active convection and subject to lightning was 2-3 times higher than it would have been without lightning.

Pickering, Kenneth E.↗

NASA NTRS1992

Free tropospheric ozone production following entrainment of urban plumes into deep convection

It is shown that rapid vertical transport of air from urban plumes through deep convective clouds can cause substantial enhancement of the rate of O3 production in the free troposphere. Simulation of convective redistribution and subsequent photochemistry of an urban plume from Oklahoma City during the 1985 PRESTORM campaign shows enhancement of O3 production in the free tropospheric cloud outflow layer by a factor of almost 4. In contrast, simulation of convective transport of an urban plume from Manaus, Brazil, into a prestine free troposphere during GTE/ABLE 2B (1987), followed by a photochemical simulation, showed enhancement of O3 production by a factor of 35. The reasons for the different enhancements are (1) intensity of cloud vertical motion; (2) initial boundary layer O3 precursor concentrations; and (3) initial amount of background free tropospheric NO(x). Convective transport of ozone precursors to the middle and upper troposphere allows the resulting O3 to spread over large geographic regions, rather than being confined to the lower troposphere where loss processes are much more rapid. Conversely, as air with lower NO descends and replaces more polluted air, there is greater O3 production efficiency per molecule of NO in the boundary layer following convective transport. As a result, over 30 percent more ozone could be produced in the entire tropospheric column in the first 24 hours following convective transport of urban plumes.

Pickering, Kenneth E.↗

NASA NTRS1992

Ozone production potential following convective redistribution of biomass burning emissions

The effects of deep convection on the potential for forming ozone in the free troposphere have been simulated for regions where the trace gas composition is influenced by biomass burning. Cloud photochemical and dynamic simulations based on observations in the 1980 and 1985 Brazilian campaigns form the basis of a sensitivity study of the ozone production potential under differing conditions. It is seen that there is considerably more ozone formed in the middle and upper troposphere when convection has redistributed hydrocarbons, NO(x), and CO compared to the example of no convection.

Pickering, Kenneth E.↗

NASA NTRS1992

A regional estimate of convective transport of CO from biomass burning

A regional-scale estimate of the fraction of biomass burning emissions that are transported to the free troposphere by deep convection is presented. The focus is on CO and the study region is a part of Brazil that underwent intensive deforestation in the 1980s. The method of calculation is stepwise, scaling up from a prototype convective event, the dynamics of which are well-characterized, to the vertical mass flux of carbon monoxide over the region. Given uncertainties in CO emissions from biomass burning and the representativeness of the prototype event, it is estimated that 10-40 percent of CO emissions from the burning region may be rapidly transported to the free troposphere over the burning region. These relatively fresh emissions will produce O3 efficiently in the free troposphere where O3 has a longer lifetime than in the boundary layer.

Pickering, Kenneth E.↗

NASA NTRS1991

Photochemical ozone production in tropical squall line convection during NASA Global Tropospheric Experiment/Amazon Boundary Layer Experiment 2A

The role of convection was examined in trace gas transport and ozone production in a tropical dry season squall line sampled on August 3, 1985, during NASA Global Tropospheric Experiment/Amazon Boundary Layer Experiment 2A (NASA GTE/ABLE 2A) in Amazonia, Brazil. Two types of analyses were performed. Transient effects within the cloud are examined with a combination of two-dimensional cloud and one-dimensional photochemical modeling. Tracer analyses using the cloud model wind fields yield a series of cross sections of NO(x), CO, and O3 distribution during the lifetime of the cloud; these fields are used in the photochemical model to compute the net rate of O3 production. At noon, when the cloud was mature, the instantaneous ozone production potential in the cloud is between 50 and 60 percent less than in no-cloud conditions due to reduced photolysis and cloud scavenging of radicals. Analysis of cloud inflows and outflows is used to differentiate between air that is undisturbed and air that has been modified by the storm. These profiles are used in the photochemical model to examine the aftereffects of convective redistribution in the 24-hour period following the storm. Total tropospheric column O3 production changed little due to convection because so little NO(x) was available in the lower troposphere. However, the integrated O3 production potential in the 5- to 13-km layer changed from net destruction to net production as a result of the convection. The conditions of the August 3, 1985, event may be typical of the early part of the dry season in Amazonia, when only minimal amounts of pollution from biomass burning have been transported into the region.

Pickering, Kenneth E.↗

NASA NTRS1990

Cloud draft structure and trace gas transport

During the second Amazon Boundary Layer Experiment (ABLE 2B), meteorological observations, chemical measurements, and model simulations are utilized in order to interpret convective cloud draft structure and to analyze its role in transport and vertical distribution of trace gases. One-dimensional photochemical model results suggest that the observed poststorm changes in ozone concentration can be attributed to convective transports rather than photochemical production and the results of a two-dimensional time-dependent cloud model simulation are presented for the May 6, 1987 squall system. The mesoscale convective system exhibited evidence of significant midlevel detrainment in addition to transports to anvil heights. Chemical measurements of O3 and CO obtained in the convective environment are used to predict photochemical production within the troposphere and to corroborate the cloud model results.

Scala, John R.↗

NASA NTRS1990

Model calculations of tropospheric ozone production potential following observed convective events

The profiles of CO, NO, O3, water vapor, and temperature, observed in 1985 during and after a series of convective events over rural areas of the south-central United States, were used to model the nonurban ozone production rates and to evaluate the effects of convective clouds on the tropospheric trace-gas chemistry. A comparison of trace-gas profiles measured in and around a large cumulonimbus during its dissipation showed that ozone production in the upper troposphere may be increased fourfold by convection relative to undisturbed air. The convective enhancement of O3 production for the entire tropospheric comlumn was found to be about 50 percent.

Pickering, Kenneth E.↗

NASA NTRS1989

Model estimates of enhanced photochemical production of ozone resulting from convective transport of precursors

Vertical profiles of net photochemical ozone production rates and total tropospheric column production rates were estimated using two models, a simple photochemical box model and a time-dependent one-dimensional transport/kinetics model. Photochemical production of ozone is found to dominate over destruction throughout the vertical extent of the troposphere over the central United States during typical summertime convective conditions. The column net production can be enhanced by the transport of the ozone precursors NO and NMHC from the boundary layer to the free troposphere by convective activity.

Pickering, Kenneth E.↗