Engineering topics

Pendleton, Y. J.

Publications and source records attributed to Pendleton, Y. J..

At least 19 records

NASA NTRS2019

Prebiotic Chemistry of Pluto

We present the case for the presence of complex organic molecules, such as amino acids and nucleobases, formed by abiotic processes on the surface and in near-subsurface regions of Pluto. Pluto's surface is tinted with a range of non-ice substances with colors ranging from light yellow to red to dark brown; the colors match those of laboratory organic residues called tholins. Tholins are broadly characterized as complex, macromolecular organic solids consisting of a network of aromatic structures connected by aliphatic bridging units (e.g., Imanaka et al.,2004; Materese et al.,2014, 2015). The synthesis of tholins in planetary atmospheres and in surface ices has been explored in numerous laboratory experiments, and both gas- and solid-phase varieties are found on Pluto. A third variety of tholins, exposed at a site of tectonic surface fracturing called Virgil Fossae, appears to have come from a reservoir in the subsurface. Eruptions of tholin-laden liquid H2O from a subsurface aqueous repository appear to have covered portions of Virgil Fossae and its surroundings with a uniquely colored deposit (D.P. Cruikshank, personal communication) that is geographically correlated with an exposure of H2O ice that includes spectroscopically detected NH3 (C.M. Dalle Ore, personal communication). The subsurface organic material could have been derived from presolar or solar nebula processes, or might have formed in situ. Photolysis and radiolysis of a mixture of ices relevant to Pluto's surface composition (N2, CH4, CO) have produced strongly colored, complex organics with a significant aromatic content having a high degree of nitrogen substitution similar to the aromatic heterocycles pyrimidine and purine (Materese et al.,2014, 2015; Cruikshank et al.,2016). Experiments with pyrimidines and purines frozen in H2O-NH3 ice resulted in the formation of numerous nucleobases, including the biologically relevant guanine, cytosine, adenine, uracil, and thymine (Materese et al.,2017). The red material associated with the H2O ice may contain nucleobases resulting from energetic processing on Pluto's surface or in the interior. Some other Kuiper Belt objects also exhibit red colors similar to those found on Pluto and may therefore carry similar inventories of complex organic materials. The widespread and ubiquitous nature of similarly complex organic materials observed in a variety of astronomical settings drives the need for additional laboratory and modeling efforts to explain the origin and evolution of organic molecules. Pluto observations reveal complex organics on a small body that remains close to its place of origin in the outermost regions of the Solar System.

Cruikshank, D. P.↗

NASA NTRS2017

Organics and Ices in the Outer Solar System: Connections to the Interstellar Medium

The solar nebula, that aggregate of gas and dust that formed the birthplace of the Sun, planets and plethora of small bodies comprising the Solar System, originated in a molecular cloud that is thought to have spawned numerous additional stars, some with their own planets and attendant small bodies. The question of the chemical and physical reprocessing of the original interstellar materials in the solar nebula has challenged both theory and observations. The acquisition and analysis of samples of comet and asteroid solids, and a growing suite of in-situ and close-up analyses of relatively unaltered small Solar System bodies now adds critical new dimensions to the study of the origin and evolution of the early solar nebula. Better understanding the original composition of the material from which our solar nebula formed, and the processing that material experienced, will aid in formulations of chemistry that might occur in other solar systems. While we seek to understand the compositional history of planetary bodies in our own Solar System, we will inevitably learn more about the materials that comprise exoplanets and their surrounding systems.

SOLAR NEBULA↗

NASA NTRS2016

NASA's Solar System Exploration Research Virtual Institute: Merging Science and Exploration

NASA's Solar System Exploration Research Virtual Institute (SSERVI) represents a close collaboration between science, technology and exploration, and was created to enable a deeper understanding of the Moon and other airless bodies. SSERVI is supported jointly by NASA's Science Mission Directorate and Human Exploration and Operations Mission Directorate. The institute currently focuses on the scientific aspects of exploration as they pertain to the Moon, Near Earth Asteroids (NEAs) and the moons of Mars, but the institute goals may expand, depending on NASA's needs, in the future. The 9 initial teams, selected in late 2013 and funded from 2014-2019, have expertise across the broad spectrum of lunar, NEA, and Martian moon sciences. Their research includes various aspects of the surface, interior, exosphere, near-space environments, and dynamics of these bodies. NASA anticipates a small number of additional teams to be selected within the next two years, with a Cooperative Agreement Notice (CAN) likely to be released in 2016. Calls for proposals are issued every 2-3 years to allow overlap between generations of institute teams, but the intent for each team is to provide a stable base of funding for a five year period. SSERVI's mission includes acting as a bridge between several groups, joining together researchers from: 1) scientific and exploration communities, 2) multiple disciplines across a wide range of planetary sciences, and 3) domestic and international communities and partnerships. The SSERVI central office is located at NASA Ames Research Center in Mountain View, CA. The administrative staff at the central office forms the organizational hub for the domestic and international teams and enables the virtual collaborative environment. Interactions with geographically dispersed teams across the U.S., and global partners, occur easily and frequently in a collaborative virtual environment. This poster will provide an overview of the 9 current US teams and international partners, as well as information about outreach efforts and future opportunities to participate in SSERVI.

technology↗

NASA NTRS2015

Exploring the Solar System from Wherever You Are

NASA's Solar System Exploration Research Virtual Institute (SSERVI) represents a close collaboration between science, technology and exploration that will enable deeper understanding of the Moon and other airless bodies as we move further out of low-Earth orbit. The Solar System Exploration Research Virtual Institute (SSERVI) focuses on the scientific aspects of exploration as they pertain to the Moon, Near Earth Asteroids (NEA's) and the moons of Mars. The Institute research areas are centered on interdisciplinary, exploration-related science of airless bodies targeted as potential human destinations. Areas of study represent the broad spectrum of lunar, NEA, and Martian moon sciences encompassing investigations of the surface, interior, exosphere, and near-space environments as well as science uniquely enabled from these bodies.The SSERVI central office is based at NASA Ames in Silicon Valley a hot spot for innovative and cost-savings approaches to space exploration and rapid advances in technology development. The administrative staff at the central office forms the organizational hub for the domestic and international teams and enables the virtual collaborative environment. The SSERVI teams are supported jointly from NASA's Science Mission Directorate and Human Exploration and Operations Mission Directorate. Teams are funded for five years. Calls for proposals are issued every 2-3 years to allow overlap between generations of institute teams. Interactions with geographically dispersed teams across the U.S., and global partners, occur easily and frequently in a collaborative virtual environment. This talk will provide a closer look at research being conducted by the current US teams, our 8 international partners and information about future opportunities to participate in SSERVI.

Pendleton, Y. J.↗

NASA NTRS2014

Interstellar Organics, the Solar Nebula, and Saturn's Satellite Phoebe

The diffuse interstellar medium inventory of organic material (Pendleton et al. 1994, Pendleton & Allamandola 2002) was likely incorporated into the molecular cloud in which the solar nebula condensed. This provided the feedstock for the formation of the Sun, major planets, and the smaller icy bodies in the region outside Neptune's orbit (transneptunian objects, or TNOs). Saturn's satellites Phoebe, Iapetus, and Hyperion open a window to the composition of one class of TNO as revealed by the near-infrared mapping spectrometer (VIMS) on the Cassini spacecraft at Saturn. Phoebe (mean diameter 213 km) is a former TNO now orbiting Saurn. VIMS spaectral maps of PHoebe's surface reveal a complex organic spectral signature consisting of prominent aromatic (CH) and alophatic hydrocarbon (CH2, CH3) absorption bands (3.2-3.6 micrometers). Phoebe is the source of a huge debris ring encircling Saturn, and from which particles (approximately 5-20 micrometer size) spiral inward toward Saturn. They encounter Iapetus and Hperion where they mix with and blanket the native H2O ice of those two bodies. Quantitative analysis of the hydrocarbon bands on Iapetus demonstrates that aromatic CH is approximately 10 times as abundant as aliphatic CH2+CH3, significantly exceeding the strength of the aromatic signature in interplanetary dust particles, comet particles, ad in carbonaceous meteorites (Cruikshank et al. 2013). A similar excess of aromatics over aliphatics is seen in the qualitative analysis of Hyperion and Phoebe itself (Dalle Ore et al. 2012). The Iapetus aliphatic hydrocarbons show CH2/CH3 approximately 4, which is larger than the value found in the diffuse ISM (approximately 2-2.5). In so far as Phoebe is a primitive body that formed in the outer regions of the solar nebula and has preserved some of the original nebula inventory, it can be key to understanding the content and degree of procesing of the nebular material. There are other Phoebe-like TNOs that are presently beyond our ability to study in the organic spectral region, but JWST will open that possibility for a number of objects. We now need to explore and understand the connection of this organic-bearing Solar System material to the solar nebula the the inventory of ISM materials incorporated therein.

Interstellar↗

NASA NTRS2011

On the Formation of Interstellar Water Ice: Constraints from a Search for Hydrogen Peroxide Ice in Molecular Clouds

Recent surface chemistry experiments have shown that the hydrogenation of molecular oxygen on interstellar dust grains is a plausible formation mechanism, via hydrogen peroxide (H2O2), for the production of water (H2O) ice mantles in the dense interstellar medium. Theoretical chemistry models also predict the formation of a significant abundance of H2O2 ice in grain mantles by this route. At their upper limits, the predicted and experimental abundances are sufficiently high that H2O2 should be detectable in molecular cloud ice spectra. To investigate this further, laboratory spectra have been obtained for H2O2/H2O ice films between 2.5 and 200 micron, from 10 to 180 K, containing 3%, 30%, and 97% H2O2 ice. Integrated absorbances for all the absorption features in low-temperature H2O2 ice have been derived from these spectra. For identifying H2O2 ice, the key results are the presence of unique features near 3.5, 7.0, and 11.3 micron. Comparing the laboratory spectra with the spectra of a group of 24 protostars and field stars, all of which have strong H2O ice absorption bands, no absorption features are found that can definitely be identified with H2O2 ice. In the absence of definite H2O2 features, the H2O2 abundance is constrained by its possible contribution to the weak absorption feature near 3.47 micron found on the long-wavelength wing of the 3 micron H2O ice band. This gives an average upper limit for H2O2, as a percentage of H2O, of 9% +/- 4%. This is a strong constraint on parameters for surface chemistry experiments and dense cloud chemistry models.

Smith, R. G.↗

NASA NTRS2000

R-O-C(triple bond)N species produced by ion irradiation of ice mixtures: comparison with astronomical observations

We have investigated the effects induced by ion bombardment of mixtures containing nitrogen-bearing compounds at low temperatures. The results show the formation of a band at 2080 cm-1 in binary mixtures, NH3:CH4 and N2:CH4, which we attribute to HCN embedded in the organic residue formed by ion irradiation. In addition to this band, ternary mixtures containing an oxygen-bearing species (i.e., H2O) form a compound with a prominent absorption band at about 2165 cm-1 (4.62 microns). We ascribe this band to a nitrile compound containing O that is bonded to the organic residue. A detailed comparison of the laboratory results with astronomical data of the 4.62 microns absorption band in protostellar spectra shows good agreement in peak position and profile. Our experimental studies show that N2, which is a more likely interstellar ice component than NH3, can be the molecular progenitor of the carrier of the interstellar band. This is an alternative to the pathway by which UV photolysis of NH3-containing ices produces the 4.62 microns band and implies that ion bombardment may well play an important role in the evolution of interstellar ices. Here, we discuss the implications of our studies for the chemical route by which the carrier of the 4.62 microns band is formed in these laboratory experiments.

NASA Discipline Exobiology↗

NASA NTRS1999

The interstellar 4.62 micron band

We present new 4.5-5.1 micron (2210-1970 cm-1) spectra of embedded protostars, W33 A, AFGL 961 E, AFGL 2136, NGC 7538 IRS 9, and Mon R2 IRS 2, which contain a broad absorption feature located near 4.62 micron (2165 cm-1), commonly referred to in the literature as the "X-C triple bond N" band. The observed peak positions and widths of the interstellar band agree to within 2.5 cm-1 and 5 cm-1, respectively. The strengths of the interstellar 4.62 micrometers band and the ice absorption features in these spectra are not correlated, which suggests a diversity of environmental conditions for the ices we are observing. We explore several possible carriers of the interstellar band and review possible production pathways through far-ultraviolet photolysis (FUV), ion bombardment of interstellar ice analog mixtures, and acid-base reactions. Good fits to the interstellar spectra are obtained with an organic residue produced through ion bombardment of nitrogen-containing ices or with the OCN- ion produced either through acid-base reactions or FUV photolysis of NH3-containing ices.

NASA Center ARC↗

NASA NTRS1998

Near-infrared spectroscopy of the proto-planetary nebula CRL 618 and the origin of the hydrocarbon dust component in the interstellar medium

A new 2.8-3.8 micrometers spectrum of the carbon-rich protoplanetary nebula CRL 618 confirms the previous detection of a circumstellar 3.4 micrometers absorption feature in this object (Lequeux & Jourdain de Muizon). The high resolution and high signal-to-noise ratio of our spectrum allow us to derive the detailed profile of this absorption feature, which is very similar to that observed in the spectrum of the Galactic center and also resembles the strong 3.4 micrometers emission feature in some post-asymptotic giant branch stars. A weak 3.3 micrometers unidentified infrared band, marginally detected in the CRL 618 spectrum of Lequeux & Jourdain de Muizon, is present in our spectrum. The existence of the 3.4 micrometers feature implies the presence of relatively short-chained, aliphatic hydrocarbon materials (-CH2-/-CH3 approximately = 2-2.5) in the circumstellar environment around CRL 618. It also implies that the carriers of the interstellar 3.4 micrometers feature are produced at least in part in circumstellar material, and it calls into question whether any are produced by the processing of interstellar ices in dense interstellar clouds, as has been previously proposed. Other features in the spectrum are recombination lines of hydrogen, rotational and vibration-rotation lines of molecular hydrogen, and a broad absorption probably due to a blend of HCN and C2H2 bands.

Spectroscopy, Near-Infrared↗

NASA NTRS1998

Processing of icy mantles in protostellar envelopes

We have obtained CO absorption profiles of several young stellar objects (YSOs), spanning a range of mass and luminosity, in order to investigate their ice mantle composition. We present the first detection of CO toward the class I YSO L1489 IRS in the Taurus dark cloud. In general, the CO profiles for YSOs show evidence for both processed and pristine ices in the same line of sight, strong indirect evidence for CO, is suggested in R CrA IRS 7, L1489 IRS, Elias 18, and GL 961E. Toward other sources (R CrA IRS 1, IRS 2, W33A, NGC 7538 IRS 9, Mon R2 IRS 2) CO is present in (nearly) pure form. We propose an evolutionary scenario to explain the chemical diversity of the icy mantles toward these objects.

Extraterrestrial Environment↗

NASA NTRS1998

The Composition of Centaur 5145 Pholus

We present a new spectrum of the Centaur object 5145 Pholus between 1.15 and 2.4 micro meters. We model this, and the previously published (0.4- to 1.0- micrometer) spectrum, using Hapke scattering theory. Seen in absorption are the 2.04- micrometer band of H2O ice and a strong band at 2.27 micrometer, interpreted as frozen methanol and/or a photolytic product of methanol having small molecular weight. The presence of small molecules is indicative of a chemically primitive surface, since heating and other processes remove the light hydrocarbons in favor of macromolecular carbon of the kind found in carbonaceous meteorites. The unusually red slope of Pholus' spectrum is matched by fine grains of a refractory organic solid (tholin). Olivine (which we model with Fo 82) also appears to be present on Pholus. We present a five-component model for the composite spectrum of all spectroscopic and photometric data available for 5145 Pholus and conclude that this is a primitive object which has not yet been substantially processed by solar heat. The properties of Pholus are those of the nucleus of a large comet that has never been active.

Cruikshank, D. P.↗

NASA NTRS1998

Spectroscopy of Kuiper Belt Objects and Centaurs

Recent near-infrared spectroscopy of Kuiper Belt objects and Centaurs indicates considerable spectral diversity among them. Some have entirely bland spectra with no discernible spectral features (e.g., Chiron), while 5145 Pholus has a very active spectrum with absorption bands of H2O, CH3OH, and probably the mineral olivine present. In addition, the strong red color of Pholus indicates the presence of organic solids. Among the KBOs, 1993 SC has an active spectrum with the probably presence of hydrocarbons and possibly the ices of H2O and N2. The diversity among these spectra and the implications that such diversity has for models of the formation of the formation of the planets will be discussed.

Cruikshank, Dale P.↗

NASA NTRS1997

Life: a cosmic imperative?

No abstract available

NASA Discipline Exobiology↗

NASA NTRS1996

Titan's 5 micrometers spectral window: carbon monoxide and the albedo of the surface

We have measured the spectrum of Titan near 5 micrometers and have found it to be dominated by absorption from the carbon monoxide 1-0 vibration-rotation band. The position of the band edge allows us to constrain the abundance of CO in the atmosphere and/or the location of the reflecting layer in the atmosphere. In the most likely case, 5 micrometers radiation is reflected from the surface and the mole fraction of CO in the atmosphere is qCO=10(+10/-5) ppm, significantly lower than previous estimates for tropospheric CO. The albedo of the reflecting layer is approximately 0.07(+0.02/-0.01) in the 5 micrometers continuum outside the CO band. The 5 micrometers albedo is consistent with a surface of mixed ice and silicates similar to the icy Galilean satellites. Organic solids formed in simulated Titan conditions can also produce similar albedos at 5 micrometers.

Saturn↗

NASA NTRS1996

From Stardust to Planetesimals: Contributed Papers

On June 24 through 26, 1996, a scientific conference entitled From Stardust to Planetesimals was held at the Westin Hotel, Santa Clara, California, as part of the 108th annual meeting of the Astronomical Society of the Pacific. Over the last decade, our understanding of the formation and early evolution of the solar system has advanced considerably due to progress that has been made simultaneously on many fronts. Stardust has been isolated in meteorites and interplanetary dust particles (IDP's), providing us with sample materials which predate the solar system and which offer clues to the processing that has occurred. At the same time, infrared studies have led to a better characterization of the composition of interstellar dust, which is now readily accepted as an important component of the interstellar medium infrared observations have also provided a much better view of the star-formation process and the role of dust therein. Recently, the presence of Kuiper Belt planetesimals has been confirmed and spectroscopy of these rather pristine objects may soon become available. Analysis of spacecraft data from the Comet Halley flybys has yielded a wealth of information on the composition of this comet. These observational advances have changed our understanding of planetesimal processing. The launch of the Infrared Space Observatory, the opening of 10-meter class telescopes, and, in the longer term, the Rosetta mission, promise to continue to broaden and deepen our understanding of the evolution from stardust to planetesimals. For these reasons we considered it timely to organize a meeting focused on the processes that connect stardust and planetesimals. The goal of this meeting was, therefore, to bring together astronomers interested in star- and planet-formation, planetary scientists studying early solar system relics, laboratory scientists studying the processing of analogs, and scientists analyzing meteorites and interplanetary dust particles, grain by grain. As a result of this endeavor, over 200 participants, including 153 scientists from 14 different countries, gathered to discuss the origin and evolution of stardust. We hope that this encounter in Santa Clara will foster an ongoing interchange of information and ideas within this diverse group of scientists. A major aim of this meeting was to produce conference proceedings which reflect the current situation regarding the evolution from stardust to planetesimals.

Kress, M. E.↗

NASA NTRS1996

The Composition of Planetesimal 5145 Pholus

We present a new spectrum of 5145 Pholus between 1.15 and 2.4 microns. We model this, and the previously published (0.4-1.0 microns) spectrum, using Hapke scattering theory. The 2.04 micron band of H2O ice is seen in absorption, as well as a strong band at 2.27 Am, interpreted as frozen methanol and/or the methanol photo product hexamethylenetetramine (HMT). The presence of small molecules is indicative of a chemically primitive surface, since heating removes the light hydrocarbons in favor of macromolecular carbon typically found in carbonaceous meteorites. The unusually red slope of Pholus' spectrum is matched by fine grains of Titan tholin, as found previously. Object 1993 HA2, which has an orbit similar to that of 5145 Pholus, is similarly red, but there are as yet no observations of absorption bands in its spectrum. We present a model for the composite spectrum of all spectroscopic and photometric data available for 5145 Pholus and conclude that this is a primitive object which has yet to be substantially processed by solar heat.

Cruikshank, D. P.↗

NASA NTRS1995

The temporal evolution of the 1-5 micron spectrum of V1974 CYGNI (Nova Cygni 1992)

We present 1-5 micrometer moderate- and high-resolution infrared spectra of the ONeMg nova V1974 (Nova Cygni 1992) obtained at multiple epochs during an approximately 500 day period after outburst. During the first 80 days, the spectra exhibited continuum emission from thermal bremsstrahlung (free-free radiation) with prominent recombination line emission from hydrogen, helium, nitrogen, and oxygen. The measurement Full Width at Half Maximum (FWHM) of these recombination lines suggests that the initial velocity of the ejecta was approximately equals 2400-3400 km/s. We estimate from the hydrogen recombination line ratios that the density of the ionized shell at this epoch was approximately equals 10(exp 9), with an effective electron temperature of approximately equals 5 x 10(exp 3) K. As the temporal evolution of the ejecta progressed, the hydrogen and helium lines diminished in intensity, and coronal lines of aluminum, calcium, magnesium, neon, and sulfur appeared by approximately day 80. The coronal line emission phase persisted for over 400 days. During this epoch, no significant dust formation occurred. We find that the ejecta of V1974 Cyg were overabundant in aluminum with respect to silicon by a factor of approximately equals 5 and in magnesium with respect to silicon by a factor of greater than or equal to 3 relative to the solar photosphere. Comparison of our observed overabundances with recent model predictions of elemental synthesis in ONeMg outbursts suggests that the accreted envelope on V1974 Cyg was close to solar composition and that the precursor ONeMg white dwarf had a mass of approximately equals 1 solar mass.

Woodward, Charles E.↗

NASA NTRS1995

Processing Mechanisms for Interstellar Ices: Connections to the Solar System

The organic component of the interstellar medium, which has revealed itself through the ubiquitous 3.4 micrometers hydrocarbon absorption feature, is widespread throughout the disk of our galaxy and has been attributed to dust grains residing in the diffuse interstellar medium. The absorption band positions near 3.4 micrometers are characteristic of C-H stretching vibrations in the -CH3 and -CH2- groups of saturated aliphatic hydrocarbons associated with perturbing chemical groups. The production of complex molecules is thought to occur within dense molecular clouds when ice-mantled grains are processed by various energetic mechanisms. Studies of the processing of interstellar ices and the subsequent production of organic residues have relevance to studies of ices in the solar system, because primitive, icy solar system bodies such as those in the Kuiper belt are likely reservoirs of organic material, either preserved from the interstellar medium or produced in situ. Connections between the interstellar medium and the early solar nebula have long been a source of interest. A comparison of the interstellar organics and the Murchison meteorite illustrates the importance of probing the interstellar connection to the solar system, because although the carbonaceous meteorites are undoubtedly highly processed, they do retain specific interstellar signatures (such as diamonds, SiC grains, graphite and enriched D/H). The organic component, while not proven interstellar, has a remarkable similarity to the interstellar organics observed in over a dozen sightlines through our galaxy. This paper compares spectra from laboratory organics produced through the processing of interstellar ice analog materials with the high resolution infrared observations of the interstellar medium in order to investigate the mechanisms (such as ion bombardment, plasma processing, and UV photolysis) that may be producing the organics in the ISM.

Pendleton, Y. J.↗