Engineering topics

Pan, Bo

Publications and source records attributed to Pan, Bo.

4 records

DOE OSTI2024

The Mobility of Mo during Microbially Mediated Ferrihydrite Phase Transformation

Molybdenum (Mo) is an essential nutrient for almost all organisms. However, at high concentrations, it can be toxic to animals and plants. This study investigated the interactions of Mo(VI) with iron oxyhydroxides during ferrihydrite bioreduction in the presence of the Fe(III)- reducing Geobacter sulfurreducens. Here, in this study, we showed that Mo concentration controlled ferrihydrite phase transformation, leading to Mo release. With the biotic reduction of ferrihydrite and Fe(II) production, Mo(VI) reduction and Mo(IV)O 2 formation were observed for the first time, which further immobilised Mo after surface adsorption of Mo(VI). At low Mo levels (Mo/Fe molar ratios of 1-2 %), sufficient Fe(II) adsorption onto ferrihydrite resulted in its transformation into magnetite nanoparticles (>80%, ~25 nm) which catalysed the reduction of Mo(VI) to form Mo(IV)O 2 and immobilised Mo. Contrastingly, at high Mo concentrations (Mo/Fe molar ratios of 5-10%), Mo(VI)O 4 2- adsorption onto ferrihydrite limited Fe(II) adsorption, subsequently less magnetite (<8-12%) formed while more goethite (~30- 50%, width & length > 15 & 100 nm, respectively) and siderite (~20-30%, width & length > 100 & 200 nm, respectively) with larger particle sizes formed instead, causing Mo(VI) release due to lower Mo adsorption. This study provides a comprehensive understanding of the interaction mechanisms among Geobacter sulfurreducens, Mo(VI), and iron oxyhydroxides, enabling predictions and controls of long-term Mo mobility and Fe mineral transformation under a variety of biogeochemical scenarios.

Geobacter sulfurreducens↗

DOE OSTI2024

MaterialsMap: A CALPHAD-based tool to design composition pathways through feasibility map for desired dissimilar materials, demonstrated with resistance spot welding joining of Ag-Al-Cu

Assembly of dissimilar metals can be achieved by different methods, for example, casting, welding, and additive manufacturing (AM). However, undesired phases formed in liquid-phase assembling processes due to solute segregation during solidification diminish mechanical and other properties of the processed parts. In the present work, an open-source software named MaterialsMap, has been developed based on the CALculation of Phase Diagrams (CALPHAD) approach. The primary objective of MaterialsMap is to facilitate the design of an optimal composition pathway for assembling dissimilar alloys with liquid-phases based on the formation of desired and undesired phases along the pathway. In MaterialsMap, equilibrium thermodynamic calculations are used to predict equilibrium phases formed at slow cooling rate, while Scheil-Gulliver simulations are employed to predict non-equilibrium phases formed during rapid cooling. Additionally, by combining these two simulations, MaterialsMap offers a thorough guide for understanding phase formation in various manufacturing processes, assisting users in making informed decisions during material selection and production. As a demonstration of this approach, a compositional pathway was designed from pure Al to pure Cu through Ag using MaterialsMap. The design was experimentally verified using resistance spot welding (RSW).

36 MATERIALS SCIENCE↗

DOE OSTI2023

Corrosion of Al-Fe self-pierce riveting joints with multiphysics-based modeling and experiments

Self-piercing riveting (SPR) is an extensively used joining technique to assemble dissimilar materials. However, this joining of the dissimilar materials can generate galvanic/crevice corrosion, which can drastically impact the mechanical properties and the service life of the joint. In this study, a multiphysics-based hybrid modeling approach is developed for the galvanic corrosion of the Al-Fe SPR joints, which can consider the corrosion initiation and corrosion evaluation jointly. Experimental studies are first performed to extract information regarding the corrosion initiation sites, corrosion evolution and overall corrosion induced material loss in SPR joints. The initiation information is then passed onto the multiphysics FE model thus making it a hybrid model. This model can help understand the influences of metal microstructure on the corrosion propagation while the morphology changes can also be analyzed. Using the developed hybrid modeling approach, thorough parametric studies can be performed to explore the coupled impacts of multiple corrosion factors on the corrosion behavior of the joints. The developed hybrid model is validated on the prediction of galvanic corrosion for the SPR joints by comparing with experimental observations.

36 MATERIALS SCIENCE↗

NASA NTRS1997

Finite Element Analysis of Magnetic Damping Effects on G-Jitter Induced Fluid Flow

This paper reports some interim results on numerical modeling and analyses of magnetic damping of g-jitter driven fluid flow in microgravity. A finite element model is developed to represent the fluid flow, thermal and solute transport phenomena in a 2-D cavity under g-jitter conditions with and without an applied magnetic field. The numerical model is checked by comparing with analytical solutions obtained for a simple parallel plate channel flow driven by g-jitter in a transverse magnetic field. The model is then applied to study the effect of steady state g-jitter induced oscillation and on the solute redistribution in the liquid that bears direct relevance to the Bridgman-Stockbarger single crystal growth processes. A selection of computed results is presented and the results indicate that an applied magnetic field can effectively damp the velocity caused by g-jitter and help to reduce the time variation of solute redistribution.

Pan, Bo↗