Engineering topics
Publications and source records attributed to Owen, T..
A brief review of the history of Jovian satellite nomenclature is given to indicate the background for the names proposed for the numbered satellites. The new names are consistent with established tradition and should cause minimal confusion with other named objects in the solar system.
High-resolution laboratory spectra of large pressure path-lengths of methane have been acquired in the region of the 6825-A band. The intensities, spacings, and splitting of the absorption features appearing in this band are not compatible with a previous suggestion that they are rotational manifolds of the 5 nu 3 band of methane.
The composition of the Martian atmosphere was determined by the mass spectrometer in the molecular analysis experiment. The presence of argon and nitrogen was confirmed and a value of 1 to 2750 plus or minus 500 for the ratio of argon-36 to argon-40 was established. A preliminary interpretation of these results suggests that Mars had a slightly more massive atmosphere in the past, but that much less total outgassing has occurred on Mars than on earth.
Predictions for the total inventory of outgassed volatiles on Mars can be developed by studying volatiles in meteorites, terrestrial rocks, and the atmospheres of Venus, the moon, and the earth. Two models are presented, following the basic assumption that the devolatilization of Mars has been analogous to that of the earth. The recent discovery of a high abundance of argon in the Martian atmosphere appears to indicate that Mars has outgassed as completely as the earth, but present uncertainties and lacunae in the essential data set permit several other interpretations.
This paper reports laboratory studies of the visible spectrum of methane at column densities between 0.4 and 5 km-am and confirms the identification of bands at 4410, 4590, 4860, 5090, 5430, 5760, and 5970 A as caused by methane. Detailed equivalent-width measurements at 15 different pressure path lengths are employed to determine curves of growth and band strengths for the bands at 4410, 4860, 5430, and 5760 A. Using the curve-of-growth measurements in the reduction of planetary observations, the methane abundances in the atmospheres of Jupiter and Saturn are found to be between a factor of 3 and 4 larger than previously accepted values based on the analysis of the 3 nu(3) band at 1.1 microns, while the amount on Titan is significantly less than that obtained from an analysis of the same band with the assumption of a pure methane atmosphere. The present results, when combined with the band analysis, suggest a surface pressure on Titan of at least 0.4 atm. Extrapolation of these laboratory data to observations of Uranus and Neptune lead to single-air-mass column densities of 5.8 and 7.6 km-am of methane, respectively.
A comprehensive review is given of the chemistry and spectroscopic studies of the Jovian atmosphere. Thermochemical equilibrium models for determining atmospheric composition are considered along with possible disequilibrating processes, and studies of the photochemistry of H2, CH4, NH3, H2S, and PH3 using the modeling methods are summarized. It is shown that photodissociation and advection are the major disequilibrating processes in Jupiter's atmosphere, that lightning and charged-particle bombardment are relatively minor factors in the planet's bulk chemistry, and that the existence of living organisms on the planet is highly improbable. Spectroscopic investigations of Jupiter are discussed, emphasizing recent observations of absorption bands due to CH4, NH3, H2, He, and D. Spectroscopic abundance determinations are examined for H2, HD, CH4, CH3D, NH3, C2H6, C2H2, and PH3. Upper limits are given for the abundances of several unobserved gases in the visible atmosphere, including H2S, HCl, SiH4, benzene, purines, pyrimidines, and their derivatives.
Recent results on the composition and structure of the atmospheres of Jupiter, Saturn, Uranus, Neptune, Pluto, and their satellites are summarized with an orientation toward topics of particular interest to the subject of exobiology. The need for an accurate Jovian temperature profile is noted, and current values are given for the known H2, NH3, and CH4 abundances of each planet as well as Titan and Triton. Trace constituents and chromophores in the Jovian atmosphere are discussed, the role of comets as a link between chemical evolution in the solar system and the chemistry of the interstellar medium is examined, and some features in the IR spectrum of Titan are interpreted. The hope is expressed that Titan will remain a useful proving ground for theories of low-temperature abiogenic organic-compound production
Explore the source record for details and available documents.
New spectra of Jupiter, Saturn, and Titan show weak methane bands in the region below 6000 A which have been known for many years in the spectra of Uranus and Neptune. Adopting the known abundance of methane on Jupiter, we have used a band model to determine CH4 abundances and broadening pressures for the other objects. The results indicate high values of the CH4 to H2 concentration ratio for Uranus and Neptune; for Titan, a surface pressure in excess of 1 atm is implied.
Infrared photometry of Titan, Saturn, and Saturn's Rings at 3.5, 4.9, 17.8, and 18.4 microns is reported. Comparison of the albedo of Titan in the 4.9 micron 'window' with the albedo of the rings and with laboratory spectra suggests that frost, possibly water ice, could be a major constituent. If thick clouds are present they must be very dark at 4.9 microns. The 17.8 and 18.4 micron data are not consistent with a clear, dense molecular hydrogen atmosphere.
Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures with protons are discussed. As in previous experiments, colored polymers were produced. An important feature of the present work is the presence or absence of absorption at 5 microns in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.
Spectra of Mars and the moon in the spectral region from 4000 to 5000 A were recorded on October 15, 1973. The effective resolution was approximately 4 A. A ratio spectrum (Mars/Moon) was obtained by computer. No absorption features could be detected in the considered region of the Martian spectrum. An upper limit for the total column density of nitrogen dioxide on Mars was derived. It appears on the basis of the investigation that the upper limit reported by Marshall (1964) for the nitrogen dioxide abundance in the Martian atmosphere is completely valid.
From recent spectra of Jupiter, Saturn and Titan in the 6450-A band of NH3, new values of the abundance of ammonia are derived for Jupiter and Saturn. NH3 abundances of 13 plus or minus 3 m-Am on Jupiter and 2 plus or minus 1 m-Am on Saturn were found. High resolution profiles of NH3 lines on Jupiter are used to estimate a pressure of 2.1 atm at the line formation level in the Jovian atmosphere. In the case of Titan, an NH3 abundance of less than 2 m-Am was found. The implications of these results are discussed.
Ground-based observations and the Pioneer 10 mission have led to new discoveries and revisions of previous ideas about the outer solar system. Among these are the discovery of atmospheres on Io and Ganymede, emission from sodium and hydrogen in a cloud around Io, and the presence of acetylene, ethane, and phosphine in the atmosphere of Jupiter. Titan, the largest satellite of Saturn, continues to be an extremely interesting and baffling object, clearly very different in composition from the bodies familiar with in the inner solar system - which is also true of Ganymede and Callisto. New data on the abundances of methane and hydrogen in the atmospheres of Uranus and Neptune suggest that the values of C/H in these atmospheres may be much lower than had been previously thought. This result reinforces the apparent compositional difference between these two planets and Jupiter and Saturn, whose atmospheres exhibit a near-solar value for this ratio.
Ground based telescopic observations of Titan and outer planet atmospheres are evaluated for their abundances and an effort is made to deduce the various hydrogen-to-carbon ratios. Jupiter and Saturn atmospheres seem to have roughly solar abundances as far as hydrogen and methane are concerned; for Uranus, Titan and Neptune these ratios are way down.
An upper limit to the deuterium-to-hydrogen ratio in the atmosphere of Uranus is reported. It is based on the nonobservance of the P(1) line of the 4-0 band of the HD infrared rotation-vibration spectrum. The relation of this limit to measurements reported for the Jovian atmosphere is discussed.
Explore the source record for details and available documents.
An attempt is made to summarize the current knowledge about the composition and structures of outer planet atmospheres with special emphasis on Jupiter, Saturn, and Titan. The nature of the substances which are responsible for the yellow coloration observed on both Jupiter and Saturn is discussed. The analysis of planetary conditions conducted shows that the outer solar system offers a variety of environments in which natural experiments in prebiotic organic synthesis must be taking place at the present time.