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Mustard, John F.

Publications and source records attributed to Mustard, John F..

31 records · Page 2

Objective determination of image end-members in spectral mixture analysis

Spectral mixture analysis was shown to be a powerful, multifaceted tool for analysis of multi- and hyper-spectral data. The essence of the first phase of the approach is to determine a set of image end-members that best account for the spectral variance in an image cube within a constrained, linear least squares mixing model. The selection of the image end-member is usually achieved using a priori knowledge and successive trial and error solutions to refine the total number and physical location of the end-members. However, in many situations a more objective method of determining these essential components is desired. The problem of image end-member determination was approached objectively by using the inherent variance of the data. Unlike purely statistical methods such as factor analysis, this approach derives solutions that conform to a physically realistic model.

Tompkins, Stefanie↗

Distribution and geologic history of materials excavated by the lunar crater Bullialdus

The crater Bullialdus is a 61 km, Eratosthenian-age impact crater located on the western edge of Mare Nubium. Previous analysis of the spatial distribution of materials in the area using nine telescopic near-infrared spectra suggested a possible three-layer structure prior to the impact event: two shallow gabbroic layers and one deeper noritic layer (from a potential depth of 5.5 km). The initial interpretation of this stratigraphy was that Bullialdus may have tapped a layered mafic pluton, such as have been invoked to explain the existence of Mg-suite rocks. High-spatial resolution CCD images of Bullialdus were analyzed to better map the spatial distribution of the observed lithologies, and to assess the plausibility of the pluton interpretation.

Tompkins, Stefanie↗

Composition of weakly altered Martian crust: Clues from imaging spectroscopy

Two of the fundamental questions regarding chemical weathering on Mars concern the following topics: the chemical pathways by which pristine crustal rocks are altered to produce observed ferric ironbearing assemblages and inferred clay silicate, sulfate, and magnetic oxide phases; and the timing of the oxidative weathering. High spatial- and spectral-resolution imaging spectrometer data provide a tool to investigate aspects of these questions for material exposed on the surface of Mars. In this study, ISM imaging spectrometer data are used to develop an inventory of least-altered crustal materials and to quantitatively model the mineralogic composition of the weakly altered crustal rocks.

Mustard, John F.↗

Relationships of soil, grass, and bedrock over the Kaweah serpentine melange through spectral mixture analysis of AVIRIS data

A linear mixing model is used to model the spectral variability of an AVIRIS scene from the western foothills of the Sierra Nevada and calibrate these radiance data to reflectance. Five spectral endmembers from the AVIRIS data, plus an ideal 'shade' endmember were required to model the continuum reflectance of each pixel in the image. Three of the endmembers were interpreted to model the surface constituents green vegetation, dry grass, and illumination. These are the main transient surface constituents that are expected to change with shifts in land use or climatic influences and viewing conditions ('shade' only). The spectral distinction between the other three endmembers is very small, yet the spatial distributions are coherent and interpretable. These distributions cross anthropogenic and vegetation boundaries and are best interpreted as different soil types. Comparison of the fraction images to the bedrock geology maps indicates that substrate composition must be a factor contributing to the spectral properties of these endmembers. Detailed examination of the reflectance spectra of the three soil endmembers reveals that differences in the amount of ferric and ferrous iron and/or organic constituents in the soils is largely responsible for the differences in spectral properties of these endmembers.

Mustard, John F.↗

Composition of Syrtis Major volcanic plateau

Syrtis Major, a low-relief volcanic shield centered near 295 degrees 10 degrees N, is an old, well-preserved and exposed volcanic region on Mars which formed at the end of the heavy bombardment period. The composition of these volcanic materials has importance for understanding the thermal and chemical history of Mars. Imaging spectrometer data of the Syrtis Major volcanic plateau are used in this analysis to identify major compositional components. First and second order even channel reflectance spectra between 0.77 and 2.55 microns from four broad classes of materials on Syrtis Major are given. For the volcanic materials, there are three primary classes characterized by albedo, slope, and shape of the 10 micron band. To emphasize the latter, straight line continua were removed from each spectral segment and replotted in another figure. Each spectrum shows a band minima near 0.96 microns and 2.15 microns indicative of pyroxene mineral absorptions. Comparison of these band minima with studies of pyroxene reflectance spectra suggests that the pyroxenes in the volcanics of Syrtis Major are high calcium pyroxene with a Ca/(Mg+Fe+Ca) ratio of 0.2 to 0.3. The most likely pyroxene is an augite.

Mustard, John F.↗

Disk-resolved spectral reflectance properties of Phobos from 0.3-3.2 micron: Preliminary integrated results from Phobos 2

The Phobos 2 mission provided multispectral observations of Phobos over a large wavelength range and with relatively high spectral resolution. Here, researchers integrate results from three multispectral detectors by determining the ultraviolet-visible near infrared spectral properties of color and brightness features recognized in VSK TV images. Researchers present evidence that there are two fundamental spectral units within the region of overlapping coverage by the detectors. They describe the units' spectral and reflectance properties and discuss the implications of these results for the composition of Phobos.

Murchie, Scott L.↗

Photometric phase functions of common geologic minerals and applications to quantitative analysis of mineral mixture reflectance spectra

The mass fractional abundance of components in intimately mixed, particulate surfaces is calculated from laboratory reflectance spectra using Hapke's (1981) model for bidirectional reflectance. It is found that a simplified version of the model is accurate to within 7 percent for mixtures not containing low albedo components. The model is not appropriate for mixtures with very low and high albedo components. Consideration is given to the possible improvement of the method's accuracy by using an empirical single-particle phase function to describe the scattering characteristics of all minerals, or by solving for the single-particle phase function of the minerals involved exactly using extensive bidirectional reflectance measurements and Hapke's equations for bidirectional reflectance. Also, the results are used to examine the general scattering behavior of particulate mineral surfaces.

Mustard, John F.↗

Application of imaging spectrometer data to the Kings-Kaweah ophiolite melange

The Kings-Kaweah ophiolite melange in east-central California is thought to be an obducted oceanic fracture zone and provides the rare opportunity to examine in detail the complex nature of this type of terrain. It is anticipated that the distribution and abundance of components in the melange can be used to determine the relative importance of geologic processes responsible for the formation of fracture zone crust. Laboratory reflectance spectra of field samples indicate that the melange components have distinct, diagnostic absorptions at visible to near-infrared wavelengths. The spatial and spectral resolution of AVIRIS is ideally suited for addressing important scientific questions concerning the Kings-Kaweah ophiolite melange and fracture zones in general.

Mustard, John F.↗

Exploration of crustal/mantle material for the earth and moon using reflectance spectroscopy

Near-infrared reflectance spectra have been acquired (1) for Moses Rock diatreme in SE Utah using an airborne imaging spectrometer (AIS) and (2) for small areas in and around the large lunar impact crater Copernicus using a spectrometer on earth-based telescopes. The high spectral resolution and precision of these data allow several mineral components of surface material to be identified and analyzed in a spatial context. The derived mineralogical information is used to address specific geological problems. For the terrestrial study the distribution of the measured abundance of mantle derived ultramafic microbreccia across Moses Rock dike indicates that flow stabilized into a few channels during the violent eruption. For the lunar study the variety of rock types identified in crustal material of deep-seated origin is distinct from the dominant rock types sampled from the upper lunar crust and suggests a complex crustal evolution.

Pieters, Carle M.↗

Abundance and distribution of ultramafic microbreccia in Moses Rock dike - Quantitative application of mapping spectroscopy

Data from the Airborne Imaging Spectrometer were used to map the distribution and abundance of the serpentized ultramafic microbreccia (SUM) component in the Moses Rock dike, which is a Tertiary diatreme located on the Colorado Plateau in Utah. The geologic setting and composition of Moses Rock dike are discussed together with its texture and the relationship to the bedrock of surface materials. These observations along with laboratory spectroscopic data are used to interpret surface mineralogy of the dike and the surrounding regions from the imaging spectometer data. The spatial distribution and the abundance of the primary surface components were calculated using a nonlinear model for the mixing of spectra from multicomponent surfaces. The derived SUM distribution and abundance data support McGetchin's (1968) model for the emplacement of Moses Rock dike as a fluidized system.

Mustard, John F.↗

Abundance and distribution of ultramafic microbreccia in Moses Rock Dike: Quantitative application of AIS data

Moses Rock dike is a Tertiary diatreme containing serpentinized ultramafic microbreccia (SUM). Field evidence indicates the SUM was emplaced first followed by breccias derived from the Permian strata exposed in the walls of the diatreme and finally by complex breccias containing basement and mantle derived rocks. SUM is found primarily dispersed throughout the matrix of the diatreme. Moses Rock dike was examined with Airborne Imaging Spectrometer (AIS) to map the distribution and excess of SUM in the matrix and to better understand the nature of the eruption which formed this explosive volcanic feature. AIS data was calibrated by dividing the suite of AIS data by data from an internal standard area and then multiplying this relative reflectance data by the absolute bidirectional reflectance of a selected sample from the standard area which was measured in the lab. From the calibrated AIS data the minerals serpentine, gypsum, and illite as well as desert varnish and the lithologies SUM and other sandstones were identified. SUM distribution and abundance in the matrix of the diatreme were examined in detail and two distinct styles of SUM dispersion were observed. The two styles are discussed in detail.

Mustard, John F.↗

Deconvolution of spectra for intimate mixtures

Visible to near infrared reflectance spectra of macroscopic mixtures have been shown to be linear combinations of the reflections of the pure mineral components in the mixture. However, for microscopic mixtures the mixing systematics are in general nonlinear. The systematics may be linearized by conversion of reflectance to single scattering albedo (w), where the equations which relate reflectance to w depend on the method of data collection. Several proposed mixing models may be used to estimate mineral abundances from the reflectance spectra of intimate mixtures. These models are summarized and a revised model is presented. A noniterative (linear) least squares approach was used for curve fitting and the data, measured as bi-directional reflectance with incidence and emergence angles of 30 and 0 deg were converted to w by a simplified version of Hapke's equation for bi-directional reflectance. This model was tested with two mixture series composed of 45 to 75 micron particles: an anorthite-enstatite series and an olivine-magnetite series. The data indicate that the simplified Hapke's equation may be used to convolve reflectance spectra into mineral abundances if appropriate endmembers are known or derived from other techniques. For surfaces that contain a significant component of very low albedo material, a somewhat modified version of this technique will need to be developed. Since the abundances are calculated using a noniterative approach, the application of this method is especially efficient for large spectral data sets, such as those produced by mapping spectrometers.

Mustard, John F.↗

Quantitative abundance estimates from bidirectional reflectance measurements

A simplified approach for estimating mineral abundances in mineral mixtures from bidirectional reflectance measurements is presented. Fundamental to this approach is a priori information concerning reflectance spectra of the individual minerals and an estimate of the particle sizes of the components. Simplified equations for bidirectional reflectance are used to linearize the systematics of spectral mixing. The method was used to determine the relative proportions of olivine, magnetite, enstatite, and anorthite in a mixture; the mass fractions of mixture components were calculated on the basis of known particle diameters. The results indicate that for materials without strongly adsorbing components, the accuracy of abundance determinations is better than 5 percent.

Mustard, John F.↗