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Miller, I. M.

Publications and source records attributed to Miller, I. M..

16 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Catalytic Oxidation of CO for Closed-Cycle CO2 Lasers

Stoichiometric mixture converted completely. High-energy pulsed CO2 lasers have potential for measuring many different features of atmosphere of Earth and particularly useful on airborne or space platforms. For this application, laser must be operated in closed cycle to conserve gas, especially if rare nonradioactive isotopes of carbon and oxygen used. However, laser discharge decomposes fraction of CO2 to CO and O2, causing rapid loss in power leading to erratic behavior. To maintain operation, CO and O2 must be recombined to form CO2.

Miller, I. M.↗
NASA NTRS1987

Characterization of Pt/SnO2 catalysts for CO oxidation

Results are presented of surface characterization of 2% and 1% (w/w) Pt on SnO2 catalysts which are being used in promoting the oxidation of CO in pulsed CO2 lasers. The N2 adsorption BET surface area for both catalysts is 6.9 sq m/g. The CO chemisorbed area at 313K is 0.17 sq m/g and 0.062 sq m/g for the 2% and 1% catalysts, respectively. Monitoring the reaction between CO and O2 by the same technique, at the same temperature yields a turn-over frequency (TOF) for the 2% catalyst of 2.7 x 100 molecules of CO2/site/s and for the 1% catalyst a value of 1.2 x 100. The ratio of the TOFs for the two catalysts is 2.2 which is approximately the ratio of the Pt loading.

Brown, K. G.↗
NASA NTRS1986

Catalytic recombination of dissociation products with Pt/SnO2 for rare and common isotope long-life, closed-cycle CO2 lasers

This paper reports results on recombination of pulsed CO2 laser dissociation products with Pt/SnO2 catalysts, and supporting studies in a surrogate laboratory catalyst reactor. The closed-cycle, pulsed CO2 laser has been continuously operated for one million pulses with an overall power degradation of less than 5 percent by flowing the laser gas mixture through a 2-percent Pt/SnO2 catalyst bed. In the surrogate laboratory reactor, experiments have been conducted to determine isotopic exchange with the catalyst when using rare-isotope gases. The effects of catalyst pretreatment, sample weight, composition, and temperature on catalyst efficiency have also been determined.

Brown, Kenneth G.↗
NASA NTRS1985

Accurate Airborne Particle Sampler

Air inducted isokinetically into centrifugal collector. Cloud drop collector accurately and efficiently samples droplets and rejects aerosol particles. Number of these collectors connected in series, each designed that largest size fraction of droplets captured in first one and successively smaller size fractions captured in others. By analyzing each size fraction, chemical composition of cloud droplets related to drop size.

Miller, I. M.↗
NASA NTRS1985

Optimization of the catalytic oxidation of CO for closed-cycle CO2 laser applications

This report develops a basis for the design of a catalyst bed for the recombination of CO and O2 in a closed-cycle CO2 laser system. The catalyst is 1% Pt on SnO2 having a BET surface area of 6.7 sq m/g and a specific void volume of 0.374 cu cm/g. The design conditions are: a catalyst bed temperature of 100 C and a circulating flow rate of 10 lambda/min. Under these conditions, the required quantity of catalyst for prolonged laser operation of 668g. The rat law for the reaction of a stoichiometric mixture of 1% CO + 1/2% O2 in helium was determined to be overall first order; however, additional experiments with non-stoichiometric gas mixtures of CO and O2 are needed to determine the order of the CO concentration and the order of the O2 concentration in the rate law.

Miller, I. M.↗
NASA NTRS1983

Theoretical performance of a vortex generator type of cloud droplet sampler

One of the goals of the NASA global tropospheric research program is understanding the chemical processes which influence the chemistry of the natural troposphere. An important element of this program is the study of the role of heterogenous chemistry in global tropospheric chemical cycles. Any study of the part which clouds play in the chemistry of tropospheric trace constituents requires a determination of cloud water chemical composition. There exists, therefore, a need for highly efficient collector devices which can obtain unbiased samples of cloud water in sufficient quantities aboard an aircraft platform. A promising concept which could meet the dual requirements of accurate sampling and efficient collection of cloud water droplets in the vortex generator. This concept involves an inertial separator which uses the centrifugal force of a rotating airstream. The separator is built into a commercial device which has been used for many years as a dust separator for air breathing engines. Attention is given to the optimization of the sampler design.

Miller, I. M.↗
NASA NTRS1983

Evaluation of catalyst for closed cycle operation of high energy pulsed CO2 lasers

Several catalyst materials have been tested for efficiency of converting CO and O2 to CO2 for use in a high energy CO2 laser. The composition of the gas mixtures was monitored by mass spectrometry and gas chromatography. A copper/copper oxide catalyst and a platinum/tin oxide catalyst were used for closed cycle operation of a CO2 laser (0.7 joules/pulse), operating at 10 pulses/sec.

Rogowski, R. S.↗
NASA NTRS1980

Pollutant emissions from flat-flame burners at high pressures

Maximum flame temperatures and pollutant emission measurements for NOx, CO, and UHC (unburned hydrocarbons) are reported for premixed methane air flat flames at constant total mass flow rate over the pressure range from 1.9 to 30 atm and for equivalence ratios from 0.84 to 1.12. For any given pressure, maxima typically occur in both the temperature and NOx emissions curves slightly to the lean side of stoichiometric conditions. The UHC emissions show minima at roughly the same equivalence ratios. The CO emissions, however, increase continually with increasing equivalence ratio. Flame temperature and NOx emissions decrease with increasing pressure, while the opposite is true for the CO and UHC emissions. The NOx data correlate reasonably well as a function of flame temperature only. Four flameholders, differing only slightly, were used. In general, the temperature and emissions data from these four flameholders are similar, but some differences also exist. These differences appear to be related to minor variations in the condition of the flameholder surfaces.

Maahs, H. G.↗
NASA NTRS1979

Effect of pressure on structure and NO sub X formation in CO-air diffusion flames

A study was made of nitric oxide formation in a laminar CO-air diffusion flame over a pressure range from 1 to 50 atm. The carbon monoxide (CO) issued from a 3.06 mm diameter port coaxially into a coflowing stream of air confined within a 20.5 mm diameter chimney. Nitric oxide concentrations from the flame were measured at two carbon monoxide (fuel) flow rates: 73 standard cubic/min and 146 sccm. Comparison of the present data with data in the literature for a methane-air diffusion flame shows that for flames of comparable flame height (8 to 10 mm) and pseudoequivalence ratio (0.162), the molar emission index of a CO-air flame is significantly greater than that of a methane-air flame.

Maahs, H. G.↗
NASA NTRS1978

A high-pressure premixed flat-flame burner for chemical process studies

A premixed flat-flame burner was designed and tested with methane-air mixtures at pressures from 1.1 to 20 atm and equivalence ratios from 0.7 to 1.1. Reactant velocity in the burner mixing chamber was used to characterize the range of stable flames at each pressure-equivalence-ratio condition. Color photographs of the flames were used to determine flame zone thickness and flame height. The results show that this burner can be used for chemical process studies in premixed high pressure methane-air flames up to 20 atm.

Miller, I. M.↗
NASA NTRS1977

High pressure flame system for pollution studies with results for methane-air diffusion flames

A high pressure flame system was designed and constructed for studying nitrogen oxide formation in fuel air combustion. Its advantages and limitations were demonstrated by tests with a confined laminar methane air diffusion flame over the pressure range from 1 to 50 atm. The methane issued from a 3.06 mm diameter port concentrically into a stream of air contained within a 20.5 mm diameter chimney. As the combustion pressure is increased, the flame changes in shape from wide and convex to slender and concave, and there is a marked increase in the amount of luminous carbon. The height of the flame changes only moderately with pressure.

Miller, I. M.↗
NASA NTRS1971

Criteria for electrically heated temperature probes in flames.

Measurement techniques proposed by Gilbert and Lobdell (1953) and Rein and O'Laughlin (1967) are considered, giving attention to an apparent paradox. The criteria under which the assumptions made for the measurement techniques apply are specified. If sensors of different diameters are tested and the resultant plots of the parameter ?S' vs the wire temperature intersect below the abscissa, the considered measurement techniques are not applicable.

Miller, I. M.↗