Detection of nitrogen sulfide in Comet Hale-Bopp
We report the first detection of the nitrogen sulfide (NS) radical in a comet. The abundance relative to water is at least a few hundredths of a percent for Comet Hale-Bopp.
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We report the first detection of the nitrogen sulfide (NS) radical in a comet. The abundance relative to water is at least a few hundredths of a percent for Comet Hale-Bopp.
Deuterated hydrogen cyanide (DCN) was detected in a comet, C/1995 O1 (Hale-Bopp), with the use of the James Clerk Maxwell Telescope on Mauna Kea, Hawaii. The inferred deuterium/hydrogen (D/H) ratio in hydrogen cyanide (HCN) is (D/H)HCN = (2.3 +/- 0.4) x 10(-3). This ratio is higher than the D/H ratio found in cometary water and supports the interstellar origin of cometary ices. The observed values of D/H in water and HCN imply a kinetic temperature >/=30 +/- 10 K in the fragment of interstellar cloud that formed the solar system.
Deuterated water (HDO) was detected in comet C/1995 O1 (Hale-Bopp) with the use of the James Clerk Maxwell Telescope on Mauna Kea, Hawaii. The inferred D/H ratio in Hale-Bopp's water is (3.3 +/- 0.8) x 10(-4). This result is consistent with in situ measurements of comet P/Halley and the value found in C/1996 B2 (Hyakutake). This D/H ratio, higher than that in terrestrial water and more than 10 times the value for protosolar H2, implies that comets cannot be the only source for the oceans on Earth.
The Neutral Mass Spectrometer on the Giotto spacecraft measured the gas and ion composition in the coma of comet P/Halley. A detailed model of the ion chemistry inside the contact surface located at 4660 km is used to interpret the measured ion desnity profiles in the 32 to 35 amu/e mass range. The masses 33 and 35 amu/e are dominated by the protonated methanol and hydrogen sulfide ions CH3OH2(+) and H3S(+). Both profiles are essentially compatible with CH3OH and H2S originating from the nucleus only. The production rates relative to water are Y(CH3OH) = Q(CH3OH)/Q(H2O) = 1.7% and Y(H2S) = 0.41%. Our Y(CH3OH) agrees well with a determination from IR spectra obtained about 6 weeks after the Giotto encounter with P/Halley. In 7 other comets IR and microwave observations give Y(CH3OH) values between about 0.7 and 6%, indicating that the methanol abundance shows a strong variability from comet to comet. In three other comets Y(H2S) values between 0.2 and 0.5% have been reported. In addition to H2S(+), only ions containing minor isotopes of H, C, O and S contribute to mass 34 amu/e (e.g. (34)S(+), (13)CH3OH2(+), CH4DO(+)). These contributions can be calculated from the measured densities of the ions containing the major isotopes and the H2S(+) contribution from the measured H3S(+) density. From mass 34 amu/e we can also derive an upper limit of 1% for the abundance of deuterated methanol. This limit is at most marginally compatible with a direct interstellar origin of the CH3OH in P/Halley as the measured interstellar abundance of deuterated methanol is 1 to 6%.
In comet P/Halley the abundances of ammonia relative to water reported in the literature differ by about one order of magnitude from roughly 0.1% up to 2%. Different observational techniques seem to have inherent systematic errors. Using the ion mass channels m/q = 19 amu/e, 18 amu/e and 17 amu/e of the Neutral Mass Spectrometer experiment aboard the spacecraft Giotto, we derive a production rate of ammonia of (1.5(sub -0.7)(sup +0.5))% relative to water. Inside the contact surface we can explain our data by a nuclear source only. The uncertainty in our abundance of ammonia is primarily a result of uncertainties in some key reaction coefficients. We discuss in detail these reactions and the range of error indicated results from extreme assumptions in the rate coefficients. From our data, even in the worst case, we can exclude the ammonia abundance to be only of the order of a few per mill.
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Sidelobe suppression for satellite reflector antennas by heavy taper, blockage compensation and active zone techniques, noting net antenna gain enhancement
Near axis sidelobe suppression techniques for circularly polarized reflector type spacecraft antennas