Engineering topics

Mckay, D. S.

Publications and source records attributed to Mckay, D. S..

At least 37 records · Page 2

NASA NTRS1993

Carbon abundances, major element chemistry, and mineralogy of hydrated interplanetary dust particles

Hydrated interplanetary dust particles (IDP's) comprise a major fraction of the interplanetary dust particles collected in the stratosphere. While much is known about the mineralogy and chemistry of hydrated IDP's, little is known about the C abundance in this class of IDP's, the nature of the C-bearing phases, and how the C abundance is related to other physical properties of hydrated IDP's. Bulk compositional data (including C and O) for 11 hydrated IDP's that were subsequently examined by the transition electron microscopy (TEM) to determine their mineralogy and mineral chemistry are reported. Our analysis indicates that these hydrated IDP's are strongly enriched in C relative to the most C-rich meteorites. The average abundance of C in these hydrated IDP's is 4X CI chondrite values. The bulk compositions (including C and O) of 11 hydrated IDP's were determined by thin-window, energy-dispersive x ray (EDX) spectroscopy of the uncoated IDP's on Be substrates in the scanning electron microscopy (SEM). As a check on our C measurements, one of the IDP's (L2006H5) was embedded in glassy S, and microtome thin sections were prepared and placed onto Be substrates. Thin-film EDX analyses of multiple thin sections of L2006H5 show good agreement with the bulk value determined in the SEM. Following EDX analysis, the mineralogy and mineral chemistry of each IDP was determined by analyzing ultramicrotome thin sections in a TEM equipped with an EDX spectrometer.

Keller, L. P.↗

NASA NTRS1993

Impact glasses from the ultrafine fraction of lunar soils

The chemical compositions of microscopic glasses produced during meteoroid impacts on the lunar surface provide information regarding the various fractionation processes which accompany these events. To learn more about these fractionation processes, we studied the compositions of submicrometer glass spheres from two Apollo 17 sampling sites using electron microscopy. The majority of the analyzed glasses show evidence for varying degrees of impact induced chemical fractionation. Among these are HASP glasses (High-Al, Si-Poor) which are believed to represent the refractory residuum left after the loss of volatile elements (e.g. Si, Fe, N) from the precursor material. In addition to HASP-type glasses, we also observed a group of VRAP glasses (volatile-rich, Al-poor) that represent condensates of vaporized volatile constituents and are complementary to the HASP compositions. High-Ti glasses were also found during the course of the study, and are documented here for the first time.

Norris, J. A.↗

NASA NTRS1993

Cometary interplanetary dust particles? An update on carbon in anhydrous IDPS

Chondritic anhydrous interplanetary dust particles (IDP's) are widely considered to be the most pristine samples available for the study of the early solar system because of their primitive mineralogy, chemistry, and isotopic characteristics. Previously, anhydrous IDP's were analyzed quantitatively for light elements and found that these particles have significantly higher bulk carbon abundances than known chondritic meteorites. A relationship between carbon abundance and silicate mineralogy was also identified which, in general, shows that particles dominated by pyroxenes have a higher carbon abundance than those dominated by olivines. Particles containing equal amounts of olivine and pyroxene show a range of carbon contents and can be grouped with either the pyroxene- or olivine-dominated particles based on their carbon abundance. It was suggested that high carbon pyroxene-rich IDP's are derived from cometary sources. Bulk compositions and mineralogy of our additional IDP's were determined; one particle has the highest carbon abundance reported in IDP's or any other chondritic material, with the possible exception of the carbon-rich Halley particles.

Thomas, K. L.↗

NASA NTRS1993

Petrology and geochemistry of VLT glasses from double drive tube 79001/2

As a part of more general studies of soils from Apollo 17 double drive tube 79001/2, glasses from the 79001/2 core are being analyzed by a multidisciplinary approach including SEM/EDS and INAA. Efforts are currently focused on VLT (very low-Ti; TiO2 less than 1 wt%) mare glasses, which are common in 79001/2 and have also been found in other Apollo 17 soils. One of the primary objectives is to determine whether any or all of the Apollo 17 VLT glasses represent pristine volcanic compositions. In addition, the range of VLT glass compositions and possible relationships between the glasses and VLT lithic samples, for which some geochemical data have been obtained previously, is being defined.

Wentworth, Susan J.↗

NASA NTRS1992

Lunar resources: Oxygen from rocks and soil

The first set of hydrogen reduction experiments to use actual lunar material was recently completed. The sample, 70035, is a coarse-grained vesicular basalt containing 18.46 wt. percent FeO and 12.97 wt. percent TiO2. The mineralogy includes pyroxene, ilmenite, plagioclase, and minor olivine. The sample was crushed to a grain size of less than 500 microns. The crushed basalt was reduced with hydrogen in seven tests at temperatures of 900-1050 C and pressures of 1-10 atm for 30-60 minutes. A capacitance probe, measuring the dew point of the gas stream, was used to follow reaction progress. Experiments were also conducted using a terrestrial basalt similar to some lunar mare samples. Minnesota Lunar Simulant (MLS-1) contains 13.29 wt. percent FeO, 2.96 wt. percent Fe2O3, and 6.56 wt. percent TiO2. The major minerals include plagioclase, pyroxene, olivine, ilmenite, and magnetite. The rock was ground and seived, and experiments were run on the less than 74- and 500-1168-micron fractions. Experiments were also conducted on less than 74-micron powders of olivine, pyroxene, synthetic ilmenite, and TiO2. The terrestrial rock and mineral samples were reduced with flowing hydrogen at 1100 C in a microbalance furnace, with reaction progress monitored by weight loss. Experiments were run at atmospheric pressure for durations of 3-4 hr. Solid samples from both sets of experiments were analyzed by Mossbauer spectroscopy, petrographic microscopy, scanning electron microscopy, tunneling electron microscopy, and x-ray diffraction. Apollo 17 soil 78221 was examined for evidence of natural reduction in the lunar environment. This sample was chosen based on its high maturity level (I sub s/FeO = 93.0). The FeO content is 11.68 wt. percent and the TiO2 content is 3.84 wt. percent. A polished thin section of the 90-150 micron size fraction was analyzed by petrographic microscopy and scanning electron microscopy.

Allen, C. C.↗

NASA NTRS1992

Geochemistry of HASP, VLT, and other glasses from double drive tube 79001/2

The Apollo 17 double drive tube 79001/2 (station 9, Van Serg Crater) is distinctive because of its extreme maturity, abundance, and variety of glass clasts. It contains mare glasses of both high Ti and very low Ti (VLT) compositions, and highland glasses of all compositions common in lunar regolith samples: highland basalt (feldspathic; Al2O3 greater than 23 wt percent), KREEP (Al2O3 less than 23 wt percent, K2O greater than 0.25 wt percent), and low-K Fra Mauro (LKFM; Al2O3 less than 23 wt percent, K2O less than 0.25 wt percent). It also contains rare specimens of high-alumina, silica-poor (HASP), and ultra Mg glasses. HASP glasses contain insufficient SiO2 to permit the calculation of a standard norm, and are thought to be the product of volatilization during impact melting. They have been studied by electron microprobe major-element analysis techniques but have not previously been analyzed for trace elements. The samples analyzed for this study were polished grain mounts of the 90-160 micron fraction of four sieved samples from the 79001/2 core (depth range 2.3-11.5 cm). A total of 80 glasses were analyzed by SEM/EDS and electron microprobe, and a subset of 33 of the glasses, representing a wide range of compositional types, was chosen for high-sensitivity INAA. A microdrilling device removed disks (mostly 50-100 micron diameter, weighing approx. 0.1-0.5 micro-g) for INAA. Preliminary data reported here are based only on short counts done within two weeks of irradiation.

Lindstrom, D. J.↗

NASA NTRS1991

Lunar neutron leakage fluxes as a function of composition and hydrogen content

Areas of the moon that might have enhanced concentrations of hydrogen are discussed. The fluxes of thermal, epithermal, and fast neutrons escaping from the lunar surface were calculated for eight different compositions and several hydrogen contents. These flux ratios depend on composition and are very sensitive to the hydrogen content. Their measurement using flight-proven techniques from lunar orbit should allow detection and identification of hydrogen residing in either permanently shaded cold traps near the lunar poles or mature regoliths. Knowledge of composition, especially of Fe and Ti, improves the thresholds for hydrogen detection and also could allow identification of Gd and Sm.

Feldman, W. C.↗

NASA NTRS1991

Apollo 14 glasses and the origin of lunar soils

Electron microprobe for comparison with soil glass data were used to analyze homogeneous and heterogeneous glass clasts in four Apollo 14 regolith breccias (14042, 14301, 14313, and 14315). Glass types in the Apollo 14 samples were found to be dominated by highland compositions, which include KREEP, LKFM and highland basalt varieties. Only 14042 has a highland glass population similar to those of local Apollo 14 soils. Breccia 14301 stands out in that it is enriched in KREEP glasses with high K2O content, which are similar in composition to Apollo 12 ropy glasses. Only 14042 could be made from local present-day soils. Some of the ancient soils did not undergo breccia formation and closure, and they evolved by meteorite impact processing, by mixing together in various proportions, and by changes made by the addition of lithic fragments and other components. It is suggested that the Apollo 14 soils are made from mixtures of comminuted regolith breccias. A likely age sequence is presented.

Wentworth, S. J.↗

NASA NTRS1991

Petrology and provenance of Apollo 15 Station 6 core 15009 and its bearing on site geology

Petrographic and microprobe studies were conducted of six soil samples from six different levels of the 30-cm-deep single-drive tube core 15009 obtained from the regolith of the Apennine Front at Station 6 of the Apollo 15 site. A model for the near-surface stratigraphy of the site is constructed, with due account for the results of previous studies of surface and core soils. Highland rocks were found to account for 9 percent of the mineral and lithic fragments in core 15009. The observed correlation between crystalline breccia fragments and green glass indicate that the primitive regolith on the premare Apennine Front contained abundant crystalline breccia fragments that were mixed with puroclastic green glass added to that regolith early in the mare eruptive sequence. KREEP basalts were found to be the parent rocks for 40 percent of the core fragments. It is inferred that KREEP basalts of the Apennine Bench Formation underlie mare basalts at the site. Olivine-normative mare basalt fragments comprise only 14 percent of the core-15009 source rocks but are much more abundant away from the Front.

Basu, A.↗

NASA NTRS1990

Mineralogical comparison of the Y86032-type lunar meteorites to feldspathic fragmental breccia 67016

Mineralogical characteristics of lunar meteorites Y82193 and Y86032 were compared to those of Apollo-16 fieldspathic fragmental breccia 67016, using results from electron microprobe analysis and TEM. It was found that the pyroxene mineralogy and chemistry of granulitic clasts in 67016 breccia and the Y86032-type lunar meteorites were much alike, suggesting that the formation processes of the fieldspathic fragmental breccias are also important in the genesis of lunar meteorites. There were differences in matrix microtextures, however, implying that 67016 and Y86032-type breccia formation temperatures were different.

Takeda, H.↗

NASA NTRS1989

Unusual olivine and pyroxene composition in interplanetary dust and unequilibrated ordinary chondrites

The presence, in both a number of interplanetary dust particles (IDPs) and in meteorite matrices, of olivine and orthopyroxene grains, low in FeO but containing up to 5 wt pct MnO, is reported. The majority of olivines and pyroxenes in meteorites contain less than 0.5 wt pct MnO. The presence of these low-iron, manganese-enriched (LIME) olivines and pyroxenes in IDPs and meteorites may indicate a link between the origin and history of IDPs and the matrix material of primitive meteorites. The origin of the LIME silicates could be explained by condensation from a gas of solar composition. Forsterite is the first major silicate phase to condense from a solar nebula gas, and Mn, which is not stable as a metal under solar nebula conditions, would condense at about 1100 K as Mn2SiO4 in solid solution with forsterite.

Klock, W.↗

NASA NTRS1989

Apollo 15 regolith breccias - Window to a KREEP regolith

The characteristics of 28 regolith breccias returned from the Apollo 15 site have been compared with those of Apollo 15 soils, Apollo 15 rock types, and Apollo 16 regolith breccias. The results suggest that KREEP basalts are not exotic to the site, and that the site is underlain by KREEP basalts which were converted to a KREEP-rich regolith full of small KREEP basalt fragments and KREEP composition glass. A possible implication of the present model is that agglutinate production was not significant in the time interval from 3.9-3.3 Gy.

Mckay, D. S.↗

NASA NTRS1989

Identification of solar nebula condensates in interplanetary dust particles and unequilibrated ordinary chondrites

Orthopyroxene and olivine grains, low in FeO, but containing MnO contents up to 5 wt percent were found in interplanetary dust particles (IDP) collected in the stratosphere. The majority of olivines and pyroxenes in meteorites contain less than 0.5 wt percent MnO. Orthopyroxenes and olivines high in Mn and low in FeO have only been reported from a single coarse grained chondrule rim in the Allende meteorite and from a Tieschitz matrix augite grain. The bulk MnO contents of the extraterrestrial dust particles with high MnO olivines and pyroxenes are close to CI chondrite abundances. High MnO, low FeO olivines and orthopyroxenes were also found in the matrix of Semarkona, an unequilibrated ordinary chondrite. This may indicate a related origin for minerals in extraterrestrial dust particles and in the matrix of unequilibrated ordinary chondrites.

Kloeck, W.↗

NASA NTRS1989

Asteroidal regoliths - What we do not know

Most of the knowledge of asteroidal regoliths is based on extensive studies of the lunar regolith and the meteorite regolith breccias and on theoretical models designed to match some characteristics of these two types of samples. Two major factors that affect the production and evolution of regolith and make these efforts problematical are changes of regolith properties with time, because of changes in the flux and velocity of impactors, and changes due to the location of the object in the solar system and the strength of the local gravity field. It is emphasized that, at present, not enough data are available on the processes operating on asteroids to be able to define the asteroidal regolith properties; such data can be obtained by missions to individual asteroids.

Mckay, D. S.↗

NASA NTRS1988

Microbeam analysis of four chondritic interplanetary dust particles for major elements, carbon and oxygen

Chemical compositions determined using electron excited X-rays are reported for four interplanetary dust particles collected in the stratosphere. These analyses include measurements of carbon and oxygen abundances which are important elements in these primitive materials. Spot analyses show very heterogeneous compositions on a micrometer scale although average composition approaches that of C1 carbonaceous chondrites. While the spot analyses show intermediate compositions between cometary dust and carbonaceous chondrites, the heterogeneity more closely resembles that of comet Halley dust particles.

Blanford, G. E.↗

NASA NTRS1988

Meteorites on Mars

Four types of meteoritic material should be found on Mars: (1) micrometeorites, many of which will survive atmospheric entry unmelted, which should fall relatively uniformly over the planet's surface, (2) ablation products from larger meteorites which ablate, break up and burn up in the Mars atmosphere, (3) debris from large, crater forming objects, which, by analogy to terrestrial and lunar impact events, will be concentrated in the crater ejecta blankets (except for rare, large events, such as the proposed C-T event on earth, which can distribute debris on a planetary scale), and (4) debris from the early, intense bombardment, which, in many areas of the planet, may now be incorporated into rocks by geologic processes subsequent to the intense bombardment era. To estimate the extent of meteoritic addition to indigenous Martian material, the meteoritic flux on Mars must be known. It is estimated that the overall flux is twice that for the Moon and 1.33 that for Earth. For small particles, whose orbital evolution is dominated by Poynting Robertson drag, the flux at Mars can be estimated from the Earth flux. The smaller Martian gravitational enhancement as well as the decrease in the spatial density of interplanetary dust with increasing heliocentric distance should reduce the flux of small particles at Mars to about 0.33 times the flux at Earth. Because of the smaller planetary cross-section the total infalling mass at Mars is then estimated to be 0.09 time the infalling mass in the micrometeorite size range at Earth.

Flynn, G. J.↗

NASA NTRS1986

Apollo 16 regolith breccias - Characterization and evidence for early formation in mega-regolith

The Apollo 16 regolith breccias were characterized in terms of petrography, grain-size distribution, porosity, major and trace element composition, noble gas contents, and ferromagnetic resonance properties. Significant variation was found with respect to density and porosity; the more dense breccias displayed substantial shock damage. The breccias resembled the soils in grain-size distribution and in petrological components, though many were found to be compositionally different from the Apollo 16 soils in that a mafic component was lacking. Nearly all breccias showed evidence of irradiation at the lunar surface, and analyses of disaggregated breccias indicated that this irradiation occurred before compaction. The concentration of surface irradiation parameters were far less than those of lunar soils or breccias of other Apollo missions. Observations with respect to the argon isotope ratio and Xe presence have led to the possibility that breccia-surface irradiation occurred as early as four billion years ago, and that most Apollo 16 regolith breccias were not formed from any known Apollo 16 soil.

Mckay, D. S.↗

NASA NTRS1986

Workshop on Past and Present Solar Radiation: The Record in Meteoritic and Lunar Regolith Material

The principal question addressed in the workshop was the extent to which asteroidal and lunar regoliths have collected and preserved, in meteoritic regolith breccias and in lunar soils and regolith breccias, a record of the flux, energy, and compositional history of the solar wind and solar flares. Six central discussion topics were identified. They are: (1)Trapped solar wind and flare gases, tracks, and micrometeorite pits in regolith components; (2)Comparison between lunar regolith breccias, meteoritic regolith breccias, and the lunar soil; (3)The special role of regolith breccias and the challenge of dating their times of compaction; (4)Implications of the data for the flux and compositional history of solar particle emission, composition, and physical mechanisms in the solar source regions, and the composition of the early nebula; (5)How and to what extent have records of incident radiation been altered in various types of grains; (6)Future research directions

Pepin, R. O.↗