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Mason, E. A.

Publications and source records attributed to Mason, E. A..

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Energy partitioning of gaseous ions in an electric field.

The partitioning of ion energy among thermal energy, drift energy, and random-field energy is studied by solution of the Boltzmann equation. An expansion in powers of the square of the electric field strength is obtained by Kihara's method. Numerical calculations for several ion-neutral force laws show that Wannier's constant mean-free-time model gives a reasonable first approximation. The formal extension to multicomponent mixtures is also given. The matrix elements obtained are tabulated, and can be used to study the field dependence of other moments of the ion-distribution function.

Hahn, H.-S.↗
NASA NTRS1973

Composition dependence of ion transport coefficients in gas mixtures

A simple momentum-transfer theory for the composition dependence of ion mobilities and diffusion coefficients in gas mixtures at arbitrary field strengths is corrected, extended, and compared with a similar theory based on momentum and energy transfer, and with results based on direct solution of the Boltzmann equation by Kihara's method. Final equations are recommended for predicting composition dependences, given only results on ion mobilities and diffusion coefficients in the pure component gases.

Whealton, J. H.↗
NASA NTRS1973

The mobility and diffusion of ions in gases

Experimental and theoretical aspects of the mobility and diffusion of ions in gases are studied in detail. Some of the subjects discussed include ion-ion interaction, boundary condition and ion and electron behavior. Also discussed in separate chapters are the problems of the diffusion coefficients and the afterglow techniques. Finally, a special chapter studies the kinetic theory of diffusion and mobility, stressing the low-, medium- and high-field theory.

Mcdaniel, E. W.↗
NASA NTRS1972

Field dependence of gaseous-ion mobility - Theoretical tests of approximate formulas.

The approximate formulas considered include relations based on the Wannier free-flight theory, the Kihara medium-field expansion, and the Frost-Patterson interpolation formulas. A few accurate theoretical results are available for testing the foregoing formulas. Cases concerning high fields, intermediate fields, and resonant charge transfer are examined. It is found that of the formulas tested, the one based on the Wannier free-flight theory is the most flexible, since it can be used for all fields and all ion-neutral force laws and mass ratios.

Hahn, H.↗
NASA NTRS1972

Physical interpretation of glory undulations in scattering cross sections.

The relation between glory undulations and the detailed nature of the potential energy of interaction of two molecules having a minimum containing one or more bound states is clarified, i.e., a physical interpretation is given to the undulations. Although the number, amplitude, and spacing of the oscillations all give information about the potential, the spacing is most often used because it can be most accurately measured. Results are given which show fairly explicitly just what information on the interaction potential is contained in the spacing of the glory oscillations. Glory oscillations put strong known constraints on any potential model.

Greene, E. F.↗
NASA NTRS1972

Viscosity and thermal conductivity of moderately dense gas mixtures.

Derivation of a simple, semitheoretical expression for the initial density dependence of the viscosity and thermal conductivity of gaseous mixtures in terms of the appropriate properties of the pure components and of their interaction quantities. The derivation is based on Enskog's theory of dense gases and yields an equation in which the composition dependence of the linear factor in the density expansion is explicit. The interaction quantities are directly related to those of the mixture extrapolated to zero density and to a universal function valid for all gases. The reliability of the formulation is assessed with respect to the viscosity of several binary mixtures. It is found that the calculated viscosities of binary mixtures agree with the experimental data with a precision which is comparable to that of the most precise measurements.

Wakeham, W. A.↗
NASA NTRS1972

Thermal conductivity and resonant multipole interactions.

Investigation of the influence of resonant multipole interactions on exchanges of rotational energy in molecular collisions, by means of a simple two-state impact-parameter approximation. It is found that dipole-quadrupole and quadrupole-quadrupole interactions can have a significant effect for molecules with low moments of inertia.

Nyeland, C.↗
NASA NTRS1972

Mobilities of polyatomic ions in gases - Core model.

A core model, consisting of a (12-4) central potential displaced from the origin, is suggested as a representation of the interaction of polyatomic ions with neutral molecules. The diffusion collision integral, which describes ion mobility, is computed and tabulated as a function of temperature and core size. The addition of the core reduces the maximum in the mobility against temperature curve, and eventually reduces the mobility below its polarization limit at all temperatures. These results are in accord with limited available experimental data. Comparison is made with other models of ion-neutral interactions.

Mason, E. A.↗
NASA NTRS1972

Field dependence of gaseous ion mobility: Test of approximate formulas

The accuracies of three approximate formulas were tested by comparison with special cases for which accurate results could be found. The Wannier free flight theory was found to be superior, and can be extended to yield a formula without further adjustable constants that gives an exact result at low electric fields and good results at medium and high fields. It is applicable for any ion neutral force law and mass ratio.

Hahn, H.↗
NASA NTRS1972

Composition dependence of ion diffusion coefficients in gas mixtures at arbitrary field strengths

Expressions for the diffusion coefficient of ions in gas mixtures are obtained from momentum transfer theory, and are given in terms of the diffusion coefficients and drift velocities of the ions in the pure component gases. Blanc's law holds exactly at all field strengths if the mean free time between collisions is independent of velocity (Maxwell model), but otherwise there may be either positive or negative deviations from Blanc's law at high fields. Such deviations are of comparable magnitude for the diffusion coefficients and the mobility, but are not identical. Specific cases of inverse-power potentials are treated in further detail, and some numerical examples are given for rigid-sphere interactions.

Whealton, J. H.↗
NASA NTRS1972

Ion drift velocities in gaseous mixtures at arbitrary field strengths.

A momentum-transfer theory is used to obtain an expression for the drift velocity of an ion in a multicomponent gas mixture. This is combined with an approximate calculation of the partition of the ion energy in the mixture to yield a formula for the drift velocity in terms of the drift velocities in the pure component gases. Positive deviations from Blanc's law at high fields are predicted, of magnitudes that should be easily measured experimentally.

Mason, E. A.↗
NASA NTRS1972

Molecular beams in chemistry.

The molecular-beam technique is a means for producing isolated atoms or molecules within a narrow range of speed and solid angle. The phenomena studied with molecular beams can be classified as single-particle interactions, many-particle interactions, and two particle-interactions. The results of scattering experiments fall into two categories including collisions that do not result in atomic rearrangements and collisions that do. Experimental methods are discussed, giving attention to low-energy beams, high-energy beams, and intermediate-energy beams. Examples are presented to illustrate the information that can be obtained from elastic, inelastic, and reactive scattering.

Jordan, J. E.↗