Engineering topics
Publications and source records attributed to Margolis, J. S..
The nu-4 band of CH3Cl interacts strongly with the 3 nu-6 band. Levels of both bands are mixed and both appear strongly in absorption. The strengths of both bands have been measured taking into account the mixing of the levels. The absorption strengths of both bands can be related to a single parameter, namely, the strength of the unperturbed nu-4 band. This was calculated to be 41.8 per sq cm/atm at 297 K.
The ClO fundamental absorption band near 850/cm is observed, with a tunable PbSnTe diode laser used as a source of monochromatic radiation. The chlorine monoxide concentration in the absorption tube was measured indirectly via a UV transmission technique. Frequencies and assignments for the ClO lines, and band centers and rotational constants for the ClO fundamental vibration, are tabulated. Diatomic vibration-rotation transitions within and between electronic substates are discussed. The tunable diode laser is valuable for studying the hyperfine structure. The IR spectroscopic technique is developed in order to monitor chlorine monoxide concentration in the stratosphere, since the short-lived ClO is a crucial intermediate participant in reactions involving destruction of stratospheric ozone.
The 6450 A ammonia absorption band in the atmosphere of Jupiter was observed during the summers of 1973 and 1974. High-dispersion spectra of this band were obtained and analyzed on a line-by-line basis to derive ammonia abundances in the Jovian atmosphere. The abundances determined this way show strikingly large fluctuations.
The absorption strengths of the Q-branch manifolds of the nu-1 band of methyl chloride were measured. The results were used to deduce the band strength, which is 32.1 plus or minus 2.9 per sq cm-atm at 297 K. The P-branch absorptions were investigated to assess the possibility of determining a vibration-rotation factor for the band. This factor is approximately 1.026.
An optoacoustic detector or spectrophone has been used to perform detailed measurements of the absorptivity of mixtures of water vapor in air. A (C-12) (O-16)2 laser was used as the source, and measurements were made at forty-nine different wavelengths from 9.2 to 10.7 microns. The details of the optoacoustic detector and its calibration are presented, along with a discussion of its performance characteristics. The results of the measurements of water vapor absorption show that the continuum absorption in the wavelength range covered is 5-10% lower than previous measurements.
The hydrogen- and self-broadened half-widths have been measured for the (nu1 + nu2) and (nu2 + nu3) bands of ammonia at 300 and 207 K. Measurement of hydrogen-broadened widths has been restricted to J and K values not exceeding 6, but that of self-broadened widths is done for a few lines outside that range. Assuming a power-law dependence of half-width on temperature, the average value of the index alpha for the lines measured is found to be 0.57 for hydrogen broadening.
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Results are presented for an experimental investigation, using a vacuum IR spectrometer, of the line positions and strengths of water vapor in the spectral region from 6900 to 7500 kaysers. The line-center frequencies of the vibration-rotation transitions of the five H2O bands in this spectral interval are determined along with the rotational levels of the (101), (200), (021), (120), and (002) states. It is noted that several of the upper-state levels are perturbed by resonance effects involving either Fermi coupling or Coriolis coupling of the near-resonance levels of various states. Tables are provided which list the measured line-center frequencies, upper- and lower-state rotational quantum numbers, ground-state energy levels, line strengths, and band assignments. It is shown that the (101) and (021) bands are type A with origins at 7249.811 and 6871.51 kaysers, respectively, while the (200), (002), and (120) bands are type B with origins at 7201.540, 7445.07, and 6775.10 kaysers, respectively.
The rotational temperature of the 2 nu 3 methane absorptions in the solar/telluric spectrum and the methane abundance in the earth's atmosphere have been measured and are found to be 243.4 plus or minus 5.3 K and 1.137 plus or minus 0.117 cm-atm (STP) in a vertical column, respectively. The data were reduced using the results of laboratory measurements with proper allowance for the fine-structure of the methane absorption manifold and the effects of vibration-rotation interaction (which causes an enhancement of the R-branch of this band).
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Explore the source record for details and available documents.
Explore the source record for details and available documents.
Explore the source record for details and available documents.
Explore the source record for details and available documents.
An up-to-date listing of the spectra obtained in the spectroscopy laboratory and a complete description of the experimental conditions are presented.
For the first time measurements in the multiple scattering regime of the diffuse reflectivity as a function of single scattering albedo have been made in a geometry that may be simulated by a plane parallel atmosphere of large optical depth. A comparison between the measurements and a theoretical computation of the diffuse reflectivity is presented. The measurements are within 1% agreement with the theoretical calculations for two different sizes of scattering particles which are larger than and smaller than the wavelength of the incident light, corresponding to the Mie and Rayleigh regimes, respectively.
Measurements of the intensities and half widths of the lines of the (00 2 - 00 0) band of N2O have been made with a spectral resolution better than 0.06/cm. The band intensity has been determined to be 1.29/sq cm per atm at 296 K. The half widths have been measured for both N2 and self broadening.