Engineering Papers⌕ Search

Engineering topics

Mandell, J. F.

Publications and source records attributed to Mandell, J. F..

Structural characterization of high temperature composites

Glass, ceramic, and carbon matrix composite materials have emerged in recent years with potential properties and temperature resistance which make them attractive for high temperature applications such as gas turbine engines. At the outset of this study, only flexural tests were available to evaluate brittle matrix composites at temperatures in the 600 to 1000 C range. The results are described of an ongoing effort to develop appropriate tensile, compression, and shear test methods for high temperature use. A tensile test for unidirectional composites was developed and used to evaluate the properties and behavior of ceramic fiber reinforced glass and glass-ceramic matrix composites in air at temperatures up to 1000 C. The results indicate generally efficient fiber reinforcement and tolerance to matrix cracking similar to polymer matrix composites. Limiting properties in these materials may be an inherently very low transverse strain to failure, and high temperature embrittlement due to fiber/matrix interface oxidation.

Mandell, J. F.↗

Fibre-matrix bond strength studies of glass, ceramic, and metal matrix composites

An indentation test technique for compressively loading the ends of individual fibers to produce debonding has been applied to metal, glass, and glass-ceramic matrix composites; bond strength values at debond initiation are calculated using a finite-element model. Results are correlated with composite longitudinal and interlaminar shear behavior for carbon and Nicalon fiber-reinforced glasses and glass-ceramics including the effects of matrix modifications, processing conditions, and high-temperature oxidation embrittlement. The data indicate that significant bonding to improve off-axis and shear properties can be tolerated before the longitudinal behavior becomes brittle. Residual stress and other mechanical bonding effects are important, but improved analyses and multiaxial interfacial failure criteria are needed to adequately interpret bond strength data in terms of composite performance.

Grande, D. H.↗

Tensile behavior of glass/ceramic composite materials at elevated temperatures

This paper describes the tensile behavior of high-temperature composite materials containing continuous Nicalon ceramic fiber reinforcement and glass and glass/ceramic matrices. The longitudinal properties of these materials can approach theoretical expectations for brittle matrix composites, failing at a strength and ultimate strain level consistent with those of the fibers. The brittle, high-modulus matrices result in a nonlinear stress-strain curve due to the onset of stable matrix cracking at 10 to 30 percent of the fiber strain to failure, and at strains below this range in off-axis plies. Current fibers and matrices can provide attractive properties well above 1000 C, but composites experience embrittlement in oxidizing atmospheres at 800 to 1000 C due to oxidation of a carbon interface reaction layer.The oxidation effect greatly increases the interface bond strength, causing composite embrittlement.

Mandell, J. F.↗

Test method development for structural characterization of fiber composites at high temperatures

Test methods used for structural characterization of polymer matrix composites can be applied to glass and ceramic matrix composites only at low temperatures. New test methods are required for tensile, compressive, and shear properties of fiber composites at high temperatures. A tensile test which should be useful to at least 1000 C has been developed and used to characterize the properties of a Nicalon/glass composite up to the matrix limiting temperature of 600 C. Longitudinal and transverse unidirectional composite data are presented and discussed.

Mandell, J. F.↗

Structural characteristics of high temperature composites

A progress report is presented for research carried from March 1984 through February 1985. A tensile test method has been developed which should give tensile and simulated shear (+ or - 45 deg) data for fiber composites up to 1000 C. Longitudinal and some transverse stress-strain data have been obtained for a glass matrix/Nicalon fiber system up to the matrix limiting temperature of 600 C. This demonstrates the functioning of the test method and the high temperature test facility which has been established on this grant. Transverse and longitudinal compression tests have been run, mostly in an end loaded configuration. A more satisfactory compression test is still required, and is under development.

Mandell, J. F.↗

Rapid quenching effects in PVC films

Using a specially constructed microbalance for hydrostatic weighing, density changes in PVC thin films (with no additives, 30-100 micrometers thick), due to rapid quenching (approximately 300 C/sec) through the glass transition temperature, have been observed. The more severe the quench, the greater is the free volume content. Isobaric volume recovery of PVC has also been studied by volume dilatometry. Both show aging of relaxing molecular rearrangements takes place as a linear function of logarithmic aging time at room temperature. Distribution of retardation times and Primak's distributed activation energy spectra have been applied to the volume recovery data. The concomitant changes in mechanical properties of PVC after quenching have been monitored by tensile creep and stress-strain to failure. All reflect the presence of excess free volume content, due to rapid quenching.

Lee, H. D.↗

Toughening of thermosetting polyimides

Work directed toward increasing the resistance to crack propagation of thermoset polyimides is described. Rubber modification and Teflon microfiber impregnation techniques for increasing fracture toughness are investigated. Unmodified Kerimid 601 has a fracture surface work value of 0.20 in-lbs/sq in. Dispersed particles of amine terminated butadiene acrylonitrile liquid rubber or of silicone rubber do not raise this value much. By contrast, 5 percent of well fibrillated Teflon produces an eight-fold increase in fracture toughness. Further process improvements should increase this factor to 20-30.

Gollob, D. S.↗

Fatigue crack growth in fiber reinforced plastics

Fatigue crack growth in fiber composites occurs by such complex modes as to frustrate efforts at developing comprehensive theories and models. Under certain loading conditions and with certain types of reinforcement, simpler modes of fatigue crack growth are observed. These modes are more amenable to modeling efforts, and the fatigue crack growth rate can be predicted in some cases. Thus, a formula for prediction of ligamented mode fatigue crack growth rate is available.

Mandell, J. F.↗

Origin of moisture effects on crack propagation in composites

A study has been made of the origin of unexpected moisture effects on crack extension in fiberglass laminates. Water immersion has been found to greatly reduce the rate of crack growth under constant loading, while increasing the rate under cyclic loading, the latter effect being the expected one. Observations were made of the extension of the stable damage zone at the tip of precut notches in wet and dry environments. The damage zone size is postulated as a critical element in the relaxation of high stress concentrations in composites, such as those at notch or crack tips. Under constant load, moisture is shown to greatly expand the interply delamination region in the damage zone, thus reducing the local fiber stresses and increasing crack resistance. Under cyclic loading moisture has little effect on the delamination region, which is large even for dry environments, and the only effect is weakening of the material and acceleration of cracks. Severe hygrothermal conditions can so weaken the material that the crack resistance is reduced under constant loading as well.

Mandell, J. F.↗

Analysis of delamination in unidirectional and crossplied fiber composites containing surface cracks

A two-dimensional hybrid stress finite element analysis is described which was used to study the local stress field around delamination cracks in composite materials. The analysis employs a crack tip singularity element which is embedded in a matrix interlayer between plies of the laminate. Results are given for a unidirectional graphite/epoxy laminate containing a delamination emanating from a surface crack through the outside ply. The results illustrate several aspects of delamination cracks: (1) the localization of the singular stress domain within the interlayer; (2) the local concentration of stress in the ply adjacent to the crack; (3) the nature of the transverse normal and interlaminar shear stress distributions; and (4) the relative magnitudes of K sub 1 and K sub 2 associated with the delamination. A simple example of the use of the analysis in predicting delamination crack growth is demonstrated for a glass/epoxy laminate. The comparisons with experimental data show good agreement.

Wang, S. S.↗

Surface crack growth in fiber composites

The results of an experimental study of damage extension and failure in glass and graphite/epoxy laminates containing partially through-thickness surface cracks are presented. The laminates studied are divided between those containing four plies, 90/0/0/90, 15/-15/-15/15, and 45/-45/-45/45, and those containing 12-16 plies of the general configurations 0/90, + or - 45, and 0/+ or - 60. Most of the results are for surface cracks of various lengths and several depths. Stable damage extension in laminates containing surface cracks is predominantly delamination between plies, and tends to be much more extensive prior to failure than is the case with through-thickness cracks, resulting in approximately notch-insensitive behavior in most cases. A greater tendency for notch-sensitive behavior is found for 0/90 graphite/epoxy laminates for which stable damage extension is more limited. The rate of damage extension with increasing applied stress depends upon the composite system and ply configuration as well as the crack length and depth. An approximate semiempirical method is presented for estimating the growth rate of large damage-regions.

Im, J.↗