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Maki, A. G.

Publications and source records attributed to Maki, A. G..

High Resolution Wavenumber Standards for the Infrared. (IUPAC Recommendations 1995)

The calibration of high resolution infrared spectra is generally more precise than accurate. This is the case even when they are recorded with Fourier transform interferometers. This presentation aims at improving the accuracy of wavenumber measurements in the infrared by recommending a selection of spectral lines as wavenumber standards for absolute calibration.

Interferometers Infrared Spectra Wavenumbers Fouri

Heterodyne frequency measurements on N2O at 5.3 and 9.0 microns

Heterodyne frequency measurements on the 01(1)1-00(0)0 band of N2O have been made with the use of a tunable-diode laser, CO laser transfer oscillator, and a CO2 laser frequency synthesizer. A beat frequency was measured between a CO laser and tunable-diode laser whose frequency was locked to the peak of N2O absorption features. The frequency of the CO laser was simultaneously determined by neasuring the beat frequency with respect to a reference synthesized from two CO2 lasers. New rovibrational constants are given for the 01(1)1 state of N2O, which are in excellent agreement with previous results, although the band center is 4 MHz higher than in the previous measurements. A table for the line frequencies and their absolute uncertainties is given for the N2O absorption lines in the wave-number region from 1830 to 1920 kaysers. Some additional frequency measurements near the lower-frequency end of the 02(0)0-00(0)0 band have also been made with respect to a C-12)(0-18)2 laser.

Wells, J. S.

Heterodyne frequency measurements and frequency calibration standards for tunable diode lasers

New frequency calibration tables are required to keep abreast of the resolution attainable by currently available tunable lasers. One key to the generation of tables with requisite accuracy involves accurate heterodyne frequency measurements; another key consists of reliable fitting and analysis. Coordinated activity in NBS involves selection of suitable molecular calibration candidates, their frequency measurement and analysis, and dissemination of the results in the form of frequency calibration tables. Current status of these efforts is described.

Wells, J. S.

Heterodyne frequency measurements of 13CO2 laser hot band transitions

Careful measurements by means of stabilized CO2 lasers are presented for the frequencies of 28 lines in the P-branch of the 01 0 0-(11 1 0, 03 1 0)I band of (C-13)(0-16)2, observed in laser emission, and three lines in the R-branch, observed in absorption with a diode laser. A significant improvement in the ro-vibrational constants has been obtained from a least squares fit to these data, demonstrating that the laser lines stabilized by natural absorption techniques provide convenient, accurate frequency references near 11.7 microns with an uncertainty of less than 0.1 MHz.

Petersen, F. R.

AFGL trace gas compilation - 1980 version

A new edition of the AFGL trace gas compilation is now available. Absorption line parameters of positions, intensities, and half-widths are given for the major bands of thirteen gases covering the spectral region from 0 to 10,000/cm. In addition to updating the original gases (NO, SO2, NO2, and NH3), the molecules HNO3, OH, HF, HCl, HBr, HI, ClO, OCS, and H2CO have been added to the compilation. The sources for the additions and modifications are described.

Rothman, L. S.

Accurate frequency and intensity measurements of the infrared spectra of atmospheric molecules

Various problems encountered and solutions found in infrared laboratory measurements on atmospheric molecules are discussed. The advantages and limitations of various measurement techniques and equipment are discussed, with emphasis placed on calibration techniques and measurement accuracy and precision. Frequency calibration aids are presented, including the current and planned tables of absorption frequency standards being developed by the Bureau of Standards for the calibration of high-resolution devices with an accuracy of + or - 3 MHz. It is noted that intensity measurements are highly susceptible to systematic errors and that great care must be taken to obtain accuracies better than + or - 10%. What is even more difficult is knowing the accuracy of a particular measurement. Recent work done on providing accurate intensity data are described.

Maki, A. G.