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Mahaffy, P.

Publications and source records attributed to Mahaffy, P..

47 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

The Origin of Planetary Nitrogen

The nitrogen found today in planetary atmospheres appears to come from two sources: N2 and condensed, nitrogen-containing compounds. On Jupiter and thus presumably on the other giant planets, the nitrogen is present mainly as ammonia but was apparently delivered primarily in the form of N2, whereas on the inner planets and Titan, the nitrogen is present as N2 but was delivered as condensed compounds, dominated by ammonia. This analysis is consistent with abundance data from the Interstellar Medium and models for the solar nebula. For Jupiter and the inner planets, it is substantiated by measurements of N-l5/N-14 and is supported by investigations of comets and meteorites, soon to be supplemented by solar wind data from the Genesis Mission. The Cassini-Huygens Mission may be able to constrain models for Saturn s ammonia abundance that could test the proportion of N2 captured by the planet. The Titan story is less direct, depending on studies of noble gases. These studies in turn suggest an evolutionary stage of the early Earth s atmosphere that included the ammonia and methane postulated by S. L. Miller (1953) in his classical experiments on the production of biogenic compounds.

Owen, T.↗
NASA NTRS2001

Light Isotopes and Trace Organics Analysis of Mars Samples with Mass Spectrometry

Precision measurement of light isotopes in Mars surface minerals and comparison of this isotopic composition with atmospheric gas and other, well-mixed reservoirs such as surface dust are necessary to understand the history of atmospheric evolution from a possibly warmer and wetter Martian surface to the present state. Atmospheric sources and sinks that set these ratios are volcanism, solar wind sputtering, photochemical processes, and weathering. Measurement of a range of trace organic species with a particular focus on species such as amino acids that are the building blocks of terrestrial life are likewise important to address the questions of prebiotic and present or past biological activity on Mars. The workshop topics "isotopic mineralogy" and "biology and pre-biotic chemistry" will be addressed from the point of view of the capabilities and limitations of insitu mass spectrometry (MS) techniques such as thermally evolved gas analysis (TEGA) and gas chromatography (GC) surface experiments using MS, in both cases, as a final chemical and isotopic composition detector. Insitu experiments using straightforward adaptations of existing space proven hardware can provide a substantial improvement in the precision and accuracy of our present knowledge of isotopic composition both in molecular and atomic species in the atmosphere and those chemically bound in rocks and soils. Likewise, detection of trace organic species with greatly improved sensitivity from the Viking GCMS experiment is possible using gas enrichment techniques. The limits to precision and accuracy of presently feasible insitu techniques compared to laboratory analysis of returned samples will be explored. The insitu techniques are sufficiently powerful that they can provide a high fidelity method of screening samples obtained from a diverse set of surface locations such as the subsurface or the interior of rocks for selection of those that are the most interesting for return to Earth.

Mahaffy, P.↗
NASA NTRS2000

Mars surface gas chromatograph mass spectrometer

A Mars surface lander Gas Chromatograph Mass Spectrometer (GCMS) is described to measure the chemical composition of abundant and trace volatile species and isotope ratios for noble gases and other elements. These measurements are relevant to the study of atmospheric evolution and past climatic conditions. A Micromission plan is under study where a surface package including a miniaturized GCMS would be delivered to the surface by a solar heated hot air balloon based system. The balloon system would be deployed about 8 km above the surface of Mars, wherein it would rapidly fill with Martian atmosphere and be heated quickly by the sun. The combined buoyancy and parachuting effects of the solar balloon result in a surface package impact of about 5 m/sec. After delivery of the package to the surface, the balloon would ascend to about 4 km altitude, with imaging and magnetometry data being taken for the remainder of the daylight hours as the balloon is blown with the Martian winds. Total atmospheric entry mass of this mission is estimated to be approximately 50 kg, and it can fit as an Ariane 5 piggyback payload.

Mahaffy, P.↗
NASA NTRS1999

Mars Solar Balloon Landed Gas Chromatograph Mass Spectrometer

A Mars surface lander Gas Chromatograph Mass Spectrometer (GCMS) is described to measure the chemical composition of abundant and trace volatile species and isotope ratios for noble gases and other elements. These measurements are relevant to the study of atmospheric evolution and past climatic conditions. A Micromission plan is under study where a surface package including a miniaturized GCMS would be delivered to the surface by a solar heated hot air balloon based system. The balloon system would be deployed about 8 km above the surface of Mars, wherein it would rapidly fill with Martian atmosphere and be heated quickly by the sun. The combined buoyancy and parachuting effects of the solar balloon result in a surface package impact of about 5 m/sec. After delivery of the package to the surface, the balloon would ascend to about 4 km altitude, with imaging and magnetometry data being taken for the remainder of the daylight hours as the balloon is blown with the Martian winds. Total atmospheric entry mass of this mission is estimated to be approximately 50 kg, and it can fit as an Ariane 5 piggyback payload. The GCMS would obtain samples directly from the atmosphere at the surface and also from gases evolved from solid phase material collected from well below the surface with a Sample Acquisition and Transport Mechanism (SATM). The experiment envisioned in the Mars Micromission described would obtain samples from a much greater depth of up to one meter below the surface, and would search for organic molecules trapped in ancient stratified layers well below the oxidized surface. Insitu instruments on upcoming NASA missions working in concert with remote sensing measurement techniques have the potential to provide a more detailed investigation of mineralogy and the extent of simple volatiles such as CO2 and H2O in surface and subsurface solid phase materials. Within the context of subsequent mission opportunities such as those provided by the Ariane 5 piggyback payload based Micromissions, it is essential to implement an even broader chemical analysis and to enable a significant extension of previous isotope measurements. Such a development would enhance the presently very active study of questions of atmospheric evolution and loss and past climatic conditions. The method selected to implement this program can be based on well-established mass spectrometry techniques. Sampled gas is chemically and physically processed to separate the gas mixture into components using gas chromatograph and related enrichment techniques. This allows trace species to be identified and reveals isotopic distributions in many cases with improved precision. Samples of interest, such as organic molecules, may lie deep below the highly oxidized surface layer and the suggested program includes enhanced sampling techniques to measure volatiles preserved in solid phase material deep below the surface as well as gas from the well mixed atmosphere.

Mahaffy, P.↗
NASA NTRS1999

The Dipper Satellite: A Medium-Class Explorer Mission to the Threshold of Space

The Dipper satellite will carry out an unprecedented, systematic, and focused in-situ exploration of the Earth's lower ionosphere and thermosphere below 200 km that will produce a pivotal base of knowledge that will significantly advance our understanding of knowledge that will significantly advance our understanding of how our near-space environment works. The satellite will carry comprehensive in-situ probes to measure vector electric and magnetic fields, plasma density and temperature, ion velocities, ion and neutral composition and winds, energetic particles including suprathermal electrons, gravity waves, and lightning bursts. The satellite will include a propulsion system and tapered body that will provide over 10,000 excursions to altitudes below 200 km with over 3000 dips to altitudes below 150 km. With this instrument complement, spacecraft, and orbit, the Dipper mission will gather the necessary combined electrodynamics and neutral dynamics measurements to provide an understanding of the Earth's critical boundary region where the ionized gases of space and the neutral gases of the atmosphere are coupled, and where impinging forces and momentum are deposited from the magnetosphere above and from the troposphere, stratosphere, and mesosphere below. In exploring those physical processes in the lower ionosphere which can only be measured in-situ, the Dipper mission addresses four main science objectives. The Dipper will: 1) reveal how ion-neutral coupling creates a global system of dynamo electric fields and currents; 2) provide first-hand understanding of how magnetospheric currents close in the ionosphere and reveal the effects on the upper atmosphere of magnetospheric energy and momentum deposition; 3) discover the degree of upwards coupling and energy deposition due to thunderstorm electric fields and determine their significance; 4) determine the dynamics and composition of the Earth's lower thermosphere, including its response to gravity, tidal, and planetary waves on a range of spatial scales. A proposal to design, build, operate, and analyze data from instruments on the Dipper spacecraft within the schedule and budget constraints of NASA's MIDEX program was submitted to NASA in 1998. This presentation summarizes the main features of the mission.

Pfaff, R. F., Jr.↗
NASA NTRS1993

Mass Spectrometric Measurement of Martian Krypton and Xenon Isotopic Abundance

The Viking gas chromatograph mass spectrometer experiment provided significant data on the atmospheric composition at the surface of Mars, including measurements of several isotope ratios. However, the limited dynamic range of this mass spectrometer resulted in marginal measurements for the important Kr and Xe isotopic abundance. The Xe-129 to Xe-132 ratio was measured with an uncertainty of 70%, but none of the other isotope ratios for these species were obtained. Accurate measurement of the Xe and Kr isotopic abundance in this atmosphere provides an important data point in testing theories of planetary formation and atmospheric evolution. The measurement is also essential for a stringent test for the Martian origin of the SNC meteorites, since the Kr and Xe fractionation pattern seen in gas trapped in glassy nodules of an SNC (EETA 79001) is unlike any other known solar system resevoir. Current flight mass spectrometer designs combined with the new technology of a high-performance vacuum pumping system show promise for a substantial increase in gas throughput and the dynamic range required to accurately measure these trace species. Various aspects of this new technology are discussed.

Mahaffy, P.↗
NASA NTRS1987

Observations of energetic ions on the nightside of Venus

Ions with energy greater than 40 eV have been measured on the nightside of Venus by the Pioneer Venus orbiter neutral mass spectrometer (ONMS). For periapsis altitudes beyond 1500 km, they are confined to solar zenith angles greater than 120 deg. The nightside energetic ion composition at 2000 km resembles the nightside thermal ion composition occurring at 1000 km with the dominant species being O(+). Postflight laboratory calibrations performed on the ONMS backup unit have been used to estimate the energetic O(+) ambient flux and density. The direction from which the energetic ions appear to be coming can be determined because the ONMS is mounted at an angle with respect to the spin axis of the spacecraft. Both tailward and antitailward components of the apparent ion flow are exhibited when projected into the ecliptic plane. The major component of the apparent ion flow is observed perpendicular to the ecliptic plane.

Kasprzak, W. T.↗