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Lyons, James R.

Publications and source records attributed to Lyons, James R..

H 2 -induced pressure broadening and pressure shift in the P -branch of the ν 3 band of CH4 from 300 to 655 K

For accurate modelling of observations of exoplanet atmospheres, quantification of the pressure broadening of infrared absorption lines for and by a variety of gases at elevated temperatures is needed. Additionally, high-resolution high-temperature H -pressure-broadened spectra are recorded for the CH 4 ν -band P-branch. Measured linewidths for 143 transitions between 2840 and 3000 cm -1 with temperature and pressures ranging between 300 and 655 K, and 10 and 933 Torr, respectively, were used to find rotation- and tetrahedral-symmetry-dependent coefficients for pressure and temperature broadening and pressure-induced lineshifts. The new pressure-broadening data will be useful in radiative-transfer models for retrieving the properties of observed expolanet atmospheres.

54 ENVIRONMENTAL SCIENCES↗

VULCAN: An Open-source, Validated Chemical Kinetics Python Code for Exoplanetary Atmospheres

We present an open-source and validated chemical kinetics code for studying hot exoplanetary atmospheres, which we name VULCAN. It is constructed for gaseous chemistry from 500 to 2500 K, using a reduced C–H–O chemical network with about 300 reactions. It uses eddy diffusion to mimic atmospheric dynamics and excludes photochemistry. We have provided a full description of the rate coefficients and thermodynamic data used. We validate VULCAN by reproducing chemical equilibrium and by comparing its output versus the disequilibrium-chemistry calculations of Moses et al. and Rimmer and Helling. It reproduces the models of HD 189733b and HD 209458b by Moses et al., which employ a network with nearly 1600 reactions. We also use VULCAN to examine the theoretical trends produced when the temperature–pressure profile and carbon-to-oxygen ratio are varied. Assisted by a sensitivity test designed to identify the key reactions responsible for producing a specific molecule, we revisit the quenching approximation and find that it is accurate for methane but breaks down for acetylene, because the disequilibrium abundance of acetylene is not directly determined by transport-induced quenching, but is rather indirectly controlled by the disequilibrium abundance of methane. Therefore we suggest that the quenching approximation should be used with caution and must always be checked against a chemical kinetics calculation. A one-dimensional model atmosphere with 100 layers, computed using VULCAN, typically takes several minutes to complete. VULCAN is part of the Exoclimes Simulation Platform (ESP; exoclime.net) and publicly available at https://github.com/exoclime/VULCAN.

79 ASTRONOMY AND ASTROPHYSICS↗

Mars dust storms - Interannual variability and chaos

The hypothesis is that the global climate system, consisting of atmospheric dust interacting with the circulation, produces its own interannual variability when forced at the annual frequency. The model has two time-dependent variables representing the amount of atmospheric dust in the northern and southern hemispheres, respectively. Absorption of sunlight by the dust drives a cross-equatorial Hadley cell that brings more dust into the heated hemisphere. The circulation decays when the dust storm covers the globe. Interannual variability manifests itself either as a periodic solution in which the period is a multiple of the Martian year, or as an aperiodic (chaotic) solution that never repeats. Both kinds of solution are found in the model, lending support to the idea that interannual variability is an intrinsic property of the global climate system. The next step is to develop a hierarchy of dust-circulation models capable of being integrated for many years.

Ingersoll, Andrew P.↗

Solar control of the upper atmosphere of Triton

If the upper atmosphere and ionosphere of Triton are controlled by precipitation of electrons from Neptune's magnetosphere as previously proposed, Triton could have the only ionosphere in the solar system not controlled by solar radiation. However, a new model of Triton's atmosphere, in which only solar radiation is present, predicts a large column of carbon atoms. With an assumed, but reasonable, rate of charge transfer between N2(+) and C, a peak C(+) abundance results that is close to the peak electron densities measured by Voyager in Triton's ionosphere. These results suggest that Triton's upper atmospheric chemistry may thus be solar-controlled. Measurement of key reaction rate constants, currently unknown or highly uncertain at Triton's low temperatures, would help to clarify the chemical and physical processes occurring in Triton's atmosphere.

Lyons, James R.↗

Theoretical comparison of maser materials for a 32-GHz maser amplifier

The computational results of a comparison of maser materials for a 32 GHz maser amplifier are presented. The search for a better maser material is prompted by the relatively large amount of pump power required to sustain a population inversion in ruby at frequencies on the order of 30 GHz and above. The general requirements of a maser material and the specific problems with ruby are outlined. The spin Hamiltonian is used to calculate energy levels and transition probabilities for ruby and twelve other materials. A table is compiled of several attractive operating points for each of the materials analyzed. All the materials analyzed possess operating points that could be superior to ruby. To complete the evaluation of the materials, measurements of inversion ratio and pump power requirements must be made in the future.

Lyons, James R.↗

Hypercube matrix computation task

A major objective of the Hypercube Matrix Computation effort at the Jet Propulsion Laboratory (JPL) is to investigate the applicability of a parallel computing architecture to the solution of large-scale electromagnetic scattering problems. Three scattering analysis codes are being implemented and assessed on a JPL/California Institute of Technology (Caltech) Mark 3 Hypercube. The codes, which utilize different underlying algorithms, give a means of evaluating the general applicability of this parallel architecture. The three analysis codes being implemented are a frequency domain method of moments code, a time domain finite difference code, and a frequency domain finite elements code. These analysis capabilities are being integrated into an electromagnetics interactive analysis workstation which can serve as a design tool for the construction of antennas and other radiating or scattering structures. The first two years of work on the Hypercube Matrix Computation effort is summarized. It includes both new developments and results as well as work previously reported in the Hypercube Matrix Computation Task: Final Report for 1986 to 1987 (JPL Publication 87-18).

Calalo, Ruel H.↗