Engineering Papers⌕ Search

Engineering topics

Liu, Z.

Publications and source records attributed to Liu, Z..

At least 145 records · Page 8

Eliminating Voltage Decay of Lithium-Rich Li 1.14 Mn 0.54 Ni 0.14 Co 0.14 O 2 Cathodes by Controlling the Electrochemical Process

Lithium-rich material owns a particularly high capacity owing to the activation of electrochemical inactive Li 2 MnO 3 phase. But at the same time, MnO 2 phase formed after Li 2 MnO 3 activation confronts a severe problem of converting to spinel phase, and resulting in voltage decay. To our knowledge, this phenomenon is inherent property of layered manganese oxide materials and can hardly be overcome. Based on this, unlike previous reports, herein we design a method for the first time to accelerate the phase transformation by tuning the charge upper-limit voltage at a high value, so the phase transformation process can be finished in a few cycles. Then material structure remains stable while cycling at a low upper-limit voltage. By this novel method voltage decay is eliminated significantly.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Evaluation of CALIOP 532-nm Aerosol Optical Depth Over Opaque Water Clouds

With its height-resolved measurements and near global coverage, the CALIOP lidar onboard the CALIPSO satellite offers a new capability for aerosol retrievals in cloudy skies. Validation of these retrievals is difficult, however, as independent, collocated and co-temporal data sets are generally not available. In this paper, we evaluate CALIOP aerosol products above opaque water clouds by applying multiple retrieval techniques to CALIOP Level 1 profile data and comparing the results. This approach allows us to both characterize the accuracy of the CALIOP above-cloud aerosol optical depth (AOD) and develop an error budget that quantifies the relative contributions of different error sources. We focus on two spatial domains: the African dust transport pathway over the tropical North Atlantic and the African smoke transport pathway over the southeastern Atlantic. Six years of CALIOP observations (2007-2012) from the northern hemisphere summer and early fall are analyzed. The analysis is limited to cases where aerosol layers are located above opaque water clouds so that a constrained retrieval technique can be used to directly retrieve 532 nm aerosol optical depth and lidar ratio. For the moderately dense Sahara dust layers detected in the CALIOP data used in this study, the mean/median values of the lidar ratios derived from a constrained opaque water cloud (OWC) technique are 45.1/44.4 +/- 8.8 sr, which are somewhat larger than the value of 40 +/- 20 sr used in the CALIOP Level 2 (L2) data products. Comparisons of CALIOP L2 AOD with the OWC-retrieved AOD reveal that for nighttime conditions the L2 AOD in the dust region is underestimated on average by approx. 26% (0.183 vs. 0.247). Examination of the error sources indicates that errors in the L2 dust AOD are primarily due to using a lidar ratio that is somewhat too small. The mean/median lidar ratio retrieved for smoke is 70.8/70.4 +/- 16.2 sr, which is consistent with the modeled value of 70 +/- 28 sr used in the CALIOP L2 retrieval. Smoke AOD is found to be underestimated, on average, by approx. 39% (0.191 vs. 0.311). The primary cause of AOD differences in the smoke transport region is the tendency of the CALIOP layer detection scheme to prematurely assign layer base altitudes and thus underestimate the geometric thickness of smoke layers.

Liu, Z.↗

Positive temperature coefficient of coercivity in Sm{sub 1−x}Dy{sub x}(Co{sub 0.695}Fe{sub 0.2}Cu{sub 0.08}Zr{sub 0.025}){sub 7.2} magnets with spin-reorientation-transition cell boundary phases

Positive temperature coefficients of coercivity are first obtained in the series of Sm{sub 1−x}Dy{sub x} (Co{sub 0.695}Fe{sub 0.2}Cu{sub 0.08}Zr{sub 0.025}){sub 7.2} magnets. The temperature range with a positive temperature coefficient of coercivity is gradually moving to higher temperature with the increase of x. Thermal magnetic analysis shows a spin reorientation transition of cell boundary phase in these magnets. It is interesting to find the abnormal coercivity is controlled by the spin-reorientation-transition cell boundary phases, and the spin reorientation temperature of cell boundary phase is consisted with the start point of the temperature range with abnormal behavior. The different temperature coefficients are discussed in terms of a nucleation model.

36 MATERIALS SCIENCE↗

Global Precipitation Measurement (GPM) Mission Products and Services at the NASA Goddard Earth Sciences Data and Information Services Center (GES DISC)

On February 27, 2014, the NASA Global Precipitation Measurement (GPM) mission was launched to provide the next-generation global observations of rain and snow (http:pmm.nasa.govGPM). The GPM mission consists of an international network of satellites in which a GPM Core Observatory satellite carries both active and passive microwave instruments to measure precipitation and serve as a reference standard, to unify precipitation measurements from a constellation of other research and operational satellites. The NASA Goddard Earth Sciences (GES) Data and Information Services Center (DISC) hosts and distributes GPM data within the NASA Earth Observation System Data Information System (EOSDIS). The GES DISC is home to the data archive for the GPM predecessor, the Tropical Rainfall Measuring Mission (TRMM). Over the past 16 years, the GES DISC has served the scientific as well as other communities with TRMM data and user-friendly services. During the GPM era, the GES DISC will continue to provide user-friendly data services and customer support to users around the world. GPM products currently and to-be available include the following:Level-1 GPM Microwave Imager (GMI) and partner radiometer productsLevel-2 Goddard Profiling Algorithm (GPROF) GMI and partner productsLevel-3 daily and monthly productsIntegrated Multi-satellitE Retrievals for GPM (IMERG) products (early, late, and final) A dedicated Web portal (including user guides, etc.) has been developed for GPM data (http:disc.sci.gsfc.nasa.govgpm). Data services that are currently and to-be available include Google-like Mirador (http:mirador.gsfc.nasa.gov) for data search and access; data access through various Web services (e.g., OPeNDAP, GDS, WMS, WCS); conversion into various formats (e.g., netCDF, HDF, KML (for Google Earth), ASCII); exploration, visualization, and statistical online analysis through Giovanni (http:giovanni.gsfc.nasa.gov); generation of value-added products; parameter and spatial subsetting; time aggregation; regridding; data version control and provenance; documentation; science support for proper data usage, FAQ, help desk; monitoring services (e.g. Current Conditions) for applications.

precipitation↗

Giovanni-4: The Next Generation

This talk discusses the new aspects of Giovanni-4. Covered in the talk are new features in Giovanni-4, including shape fileservices, seasonal analysis services, the Omnibus Portal, navigation among variables, and comparison services.

analysis↗

Excitonic localization in AlN-rich Al{sub x}Ga{sub 1−x}N/Al{sub y}Ga{sub 1−y}N multi-quantum-well grain boundaries

AlGaN/AlGaN multi-quantum-wells (MQW) with AlN-rich grains have been grown by metal organic chemical vapor deposition. The grains are observed to have strong excitonic localization characteristics that are affected by their sizes. The tendency to confine excitons progressively intensifies with increasing grain boundary area. Photoluminescence results indicate that the MQW have a dominant effect on the peak energy of the near-bandedge emission at temperatures below 150 K, with the localization properties of the grains becoming evident beyond 150 K. Cathodoluminescence maps reveal that the grain boundary has no effect on the peak intensities of the AlGaN/AlGaN samples.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The impacts of deglacial meltwater forcing on the South Atlantic Ocean deep circulation since the Last Glacial Maximum

A NCAR-CCSM3 (National Center for Atmospheric Research – Community Climate System Model version 3) state-of-the-art transient paleoclimate simulation with prescribed freshwater inflows is used to investigate the changes and evolution of the South Atlantic water mass structure from the Last Glacial Maximum (LGM) to the present day. Model results show that 21 000 yr ago the water column was substantially stratified due to the presence of a saltier-than-today Antarctic Bottom Water (AABW), forming a salinity barrier that prevented dense waters from the Northern Hemisphere from sinking. This salinity barrier started to erode after the termination of the Heinrich event 1, when its associated meltwater was transported southward, freshening the AABW. The removal of the barrier after 14 ka triggered the production of the North Atlantic Deep Water (NADW), which spread into the deeper layers of the South Atlantic at the onset of the Holocene. At this point, the NADW acquired its modern-day structure, establishing a deeper Atlantic meridional overturning circulation (AMOC).

54 ENVIRONMENTAL SCIENCES↗

Ensemble-Based Parameter Estimation in a Coupled General Circulation Model

Parameter estimation provides a potentially powerful approach to reduce model bias for complex climate models. Here, in a twin experiment framework, the authors perform the first parameter estimation in a fully coupled ocean–atmosphere general circulation model using an ensemble coupled data assimilation system facilitated with parameter estimation. The authors first perform single-parameter estimation and then multiple-parameter estimation. In the case of the single-parameter estimation, the error of the parameter [solar penetration depth (SPD)] is reduced by over 90% after ~40 years of assimilation of the conventional observations of monthly sea surface temperature (SST) and salinity (SSS). The results of multiple-parameter estimation are less reliable than those of single-parameter estimation when only the monthly SST and SSS are assimilated. Assimilating additional observations of atmospheric data of temperature and wind improves the reliability of multiple-parameter estimation. The errors of the parameters are reduced by 90% in ~8 years of assimilation. Finally, the improved parameters also improve the model climatology. With the optimized parameters, the bias of the climatology of SST is reduced by ~90%. Altogether, this study suggests the feasibility of ensemble-based parameter estimation in a fully coupled general circulation model.

54 ENVIRONMENTAL SCIENCES↗