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Liu, Ning

Publications and source records attributed to Liu, Ning.

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Engineering the Thermoelectric Transport in Half-Heusler Materials through a Bottom-Up Nanostructure Synthesis

Half-Heusler (HH) alloys are among the best promising thermoelectric (TE) materials applicable for the middle-to-high temperature power generation. Despite of the large thermoelectric power factor and decent figure-of-merit ZT (≈1), their broad applications and enhancement on TE performance are limited by the high intrinsic lattice thermal conductivity (κ L ) due to insufficiencies of phonon scattering mechanisms, and the fewer powerful strategies associated with the microstructural engineering for HH materials. This study reports a bottom-up nanostructure synthesis approach for these HH materials based on the displacement reaction between metal chlorides/bromides and magnesium (or lithium), followed by vacuum-assisted spark plasma sintering process. The samples are featured with dense dislocation arrays at the grain boundaries, leading to a minimum κ L of ≈1 W m -1 K -1 at 900 K and one of the highest ZT (≈1) and predicted η (≈11%) for n-type Hf 0.25 Zr 0.75 NiSn 0.97 Sb 0.03 . Further manipulation on the dislocation defects at the grain boundaries of p-type Nb 0.8 Ti 0.2 FeSb leads to enhanced maximum power factor of 47 × 10 -4 W m -1 K -2 and the predicted η of ≈7.5%. Moreover, vanadium substitution in FeNb 0.56 V 0.24 Ti 0.2 Sb significantly promotes the η to ≈11%. This strategy can be extended to a broad range of advanced alloys and compounds for improved properties.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Noble metal free photocatalytic H 2 generation on black TiO 2 : On the influence of crystal facets vs. crystal damage

In this study, we investigate noble metal free photocatalytic water splitting on natural anatase single crystal facets and on wafer slices of the [001] plane before and after these surfaces have been modified by high pressure hydrogenation and hydrogen ion-implantation. Here, we find that on the natural, intact low index planes, photocatalytic H 2 evolution (in the absence of a noble metal co-catalyst) can only be achieved when the hydrogenation treatment is accompanied by the introduction of crystal damage, such as simple scratching and miscut in the crystal, or by implantation damage. X-ray reflectivity, Raman, and optical reflection measurements show that plain hydrogenation leads to a ≈ 1 nm thick black titania surface layer without activity, while a colorless, density modified, and ≈7 nm thick layer with broken crystal symmetry is present on the ion implanted surface. These results demonstrate that (i) the H-treatment of an intact anatase surface needs to be combined with defect formation for catalytic activation and (ii) activation does not necessarily coincide with the presence of black color.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Development of a CO 2 Chemical Sensor for Downhole CO 2 Monitoring in Carbon Sequestration

Geologic storage of carbon dioxide (CO 2 ) has been proposed as a viable means for reducing anthropogenic CO 2 emissions. The means for geological sequestration of CO 2 is injection of supercritical CO 2 underground, which requires the CO 2 to remain either supercritical, or in solution in the water/brine present in the underground formation. However, there are aspects of geologic sequestration that need further study, particularly in regards to safety. To date, none of the geologic sequestration locations have been tested for storage integrity under the changing stress conditions that apply to the sequestration of very large amounts of CO 2 . Establishing environmental safety and addressing public concerns require widespread monitoring of the process in the deep subsurface. In addition, studies of subsurface carbon sequestration such as flow simulations, models of underground reactions and transports require a comprehensive monitoring process to accurately characterize and understand the storage process. Real-time information about underground CO 2 movement and concentration change is highly helpful for: (1) better understanding the uncertainties present in CO 2 geologic storage; (2) improvement of simulation models; and (3) evaluation of the feasibility of geologic CO 2 storage. Current methods to monitor underground CO 2 storage include seismic, geoelectric, isotope and tracer methods, and fluid sampling analysis. However, these methods commonly resulted low resolution, high cost, and the inability to monitor continuously over the long time scales of the CO 2 storage process. A preferred way of monitoring in-situ underground CO 2 migration is to continuous measure CO 2 concentration change in brine during the carbon storage process. An approach to obtain the real time information on CO 2 concentration change in formation solution is highly demanded in carbon storage to understand the CO 2 migration subsurface and to answer the public safety problem. The objective of the study is to develop a downhole CO 2 sensor that can in-situ, continuously monitor CO 2 concentration change in deep saline. The sensor is a Severinghaus-type CO 2 sensor with small size, which renders it can be embedded in monitoring well casing or integrated with pressure/temperature transducers, enabling the development of “smart” wells. The studies included: (1) prepare and characterize metal-oxide electrodes. Test the electrodes response to pH change. Investigate different ions and brine concentration effects on the electrode’s performance. Study the stability of the electrode in brine solution; (2) fabricate a downhole CO 2 sensor with the metal-oxide electrodes prepared in the laboratory. Test the performance of the CO 2 sensor in brine solutions. Study high pressure effects on the performance of the sensor; (3) design and conduct CO 2 /brine coreflooding experiments with the CO2 sensor. Monitor CO 2 movement along the core and test the performance of the sensor in coreflooding tests. Develop a data acquisition system that can digitize the sensor’s output voltage. Our completed research has resulted in deep understanding of downhole CO 2 sensor development and CO 2 monitoring in CO 2 storage process. The developed downhole CO 2 sensor included a metal-oxide electrode, a gas-permeable membrane, a porous steel cup, and a bicarbonate-based internal electrolyte solution. Iridium oxide-based electrode was prepared and used for preparation the CO 2 sensor. The prepared iridium oxide-based electrode displayed a linearly response to pH change. Different factors such as different ions and ions concentration, temperature, and pressure effects on the electrode performance on pH response were investigated. The results indicated that the electrode exhibited a good performance even in high salt concentration of produced water. To improve the electrode performance under high pressure, IrO 2 nanoparticles with the particle size in the range of 1-2 nm were prepared and electrodeposited on stainless steel substrate by cyclic voltammetry. It was observed that the thin film of iridium oxide was formed on the substrate surface and such iridium oxide-based electrode displayed excellent performance under high pressure for longer term. A downhole CO 2 sensor with the iridium oxide-based electrode was prepared. The working principle of the CO 2 sensor is based on the measurement of the pH change of the internal electrolyte solution caused by the hydrolysis of CO 2 and then determination of the CO 2 concentration in water. The prepared downhole CO 2 sensor had the size of diameter of 0.7 in. and length of 1.5 in. The sensor was tested under the pressures of 500 psi, 2,000 psi, and 3,000 psi. A linear correlation was observed between the sensor potential change and dissolved CO 2 concentration in water. The response time of the CO 2 sensor was in the range of 60-100 minutes. Further tests indicated that the CO 2 sensor exhibited good reproducibility under high pressure. A CO 2 /brine coreflooding system was constructed to simulate the real-world CO 2 storage process. The prepared downhole CO 2 sensor was loaded in the system to monitor CO 2 movement during CO 2 /brine coreflooding test. The results indicated that the sensor could detect CO 2 movement in the tests. Further studies showed that the sensor could be recovered by brine flooding after CO 2 /brine flushed the core. The results of the coreflooding tests demonstrated that the sensor had potential application for CO 2 monitoring in carbon sequestration. A data acquisition system for the downhoe CO 2 sensor was developed and coded. The system converted the sensor output signal into digital data and transported the data from downhole to wellhead surface. The data acquisition system was tested and evaluated in the laboratory with the prepared sensor for data collection.

36 MATERIALS SCIENCE↗
DOE OSTI2016

A downhole CO 2 sensor to monitor CO 2 movement in situ for geologic carbon storage

Here this paper describes how a downhole CO 2 chemical sensor was prepared for use in determining the concentration of CO 2 in water, particularly in harsh, high-pressure environments such as those found in geological formations considered for the geologic storage of CO 2 . The sensor consisted of a pair of Ir/IrO x and Ag/AgCl electrodes, a gas-permeable membrane, a bicarbonate-based internal electrolyte solution, and porous stainless steel as supporting material. The sensor was tested in the solution with different concentrations of CO 2 and displayed very good CO 2 sensing performance under pressures of 1000, 2000, and 3000 psi. A linear relationship between the sensor response potential and the logarithm of the CO 2 concentration was obtained for the sensor under different pressures. Reproducibility of the sensor was examined and the results indicated that the sensor displayed excellent reproducibility. CO 2 /brine core flooding tests were carried out to evaluate the performance of the CO 2 sensor in simulate CO 2 storage process. The results indicated that the sensor could detect CO 2 movement in the tests. Further studies showed that the sensor could be reused by brine flooding after CO 2 /brine flushed the core. The results of the core flooding tests demonstrated that the sensor had potential application for CO 2 monitoring in carbon storage.

25 ENERGY STORAGE↗
DOE OSTI2016

Multiporous carbon allotropes transformed from symmetry-matched carbon nanotubes

Carbon nanotubes (CNTs) with homogeneous diameters have been proven to transform into new carbon allotropes under pressure but no studies on the compression of inhomogeneous CNTs have been reported. In this study, we propose to build new carbon allotropes from the bottom-up by applying pressure on symmetry-matched inhomogeneous CNTs. We find that the (3,0) CNT with point group C{sub 3v} and the (6,0) CNT with point group C{sub 6v} form an all sp{sup 3} hybridized hexagonal 3060-Carbon crystal, but the (4,0) CNT with point group D{sub 4h} and the (8,0) CNT with point group D{sub 8h} polymerize into a sp{sup 2}+sp{sup 3} hybridized tetragonal 4080-Carbon structure. Their thermodynamic, mechanical and dynamic stabilities show that they are potential carbon allotropes to be experimentally synthesized. The multiporous structures, excellently mechanical properties and special electronic structures (semiconductive 3060-Carbon and semimetallic 4080-Carbon) imply their many potential applications, such as gases purification, hydrogen storage and lightweight semiconductor devices. In addition, we simulate their feature XRD patterns which are helpful for identifying the two carbon crystals in future experimental studies.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2015

The Machine Protection System for the Fermilab Accelerator Science and Technology Facility

The Machine Protection System (MPS) for the Fermilab Accelerator Science and Technology Facility (FAST) has been implemented and tested. The system receives signals from several subsystems and devices which conveys the relevant status needed to the safely operate the accelerator. Logic decisions are made based on these inputs and some predefined user settings which in turn controls the gate signal to the laser of the photo injector. The inputs of the system have a wide variety of signal types, encoding methods and urgencies for which the system is designed to accommodate. The MPS receives fast shutdown (FSD) signals generated by the beam loss system and inhibits the beam or reduces the beam intensity within a macropulse when the beam losses at several places along the accelerator beam line are higher than acceptable values. TTL or relay contact signals from the vacuum system, toroids, magnet systems etc., are chosen with polarities that ensure safe operation of the accelerator from unintended events such as cable disconnection in the harsh industrial environment of the experimental hall. A RS422 serial communication scheme is used to interface the operation permit generator module and a large number of movable devices each reporting multi-bit status. The system also supports operations at user defined lower beam levels for system conunissioning. The machine protection system is implemented with two commercially available off-the-shelf VMEbus based modules with on board FPGA devices. The system is monitored and controlled via the VMEbus by a single board CPU

Wu, Jinyuan↗
DOE OSTI2015

An improved model to estimate trapping parameters in polymeric materials and its application on normal and aged low-density polyethylenes

Trapping parameters can be considered as one of the important attributes to describe polymeric materials. In the present paper, a more accurate charge dynamics model has been developed, which takes account of charge dynamics in both volts-on and off stage into simulation. By fitting with measured charge data with the highest R-square value, trapping parameters together with injection barrier of both normal and aged low-density polyethylene samples were estimated using the improved model. The results show that, after long-term ageing process, the injection barriers of both electrons and holes is lowered, overall trap depth is shallower, and trap density becomes much greater. Additionally, the changes in parameters for electrons are more sensitive than those of holes after ageing.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Enhancing the pH sensitivity by laterally synergic modulation in dual-gate electric-double-layer transistors

The sensitivity of a standard ion-sensitive field-effect transistor is limited to be 59.2 mV/pH (Nernst limit) at room temperature. Here, a concept based on laterally synergic electric-double-layer (EDL) modulation is proposed in order to overcome the Nernst limit. Indium-zinc-oxide EDL transistors with two laterally coupled gates are fabricated, and the synergic modulation behaviors of the two asymmetric gates are investigated. A high sensitivity of ∼168 mV/pH is realized in the dual-gate operation mode. Laterally synergic modulation in oxide-based EDL transistors is interesting for high-performance bio-chemical sensors.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Nanoparticle-stabilized CO₂ foam for CO₂ EOR application

The purpose of this project was to develop nanoparticle-stabilized CO₂ foam for CO₂ -EOR application, in which nanoparticles instead of surfactants are used for stabilizing CO₂ foam to improve the CO₂ sweep efficiency and increase oil recovery. The studies included: (1) investigation of CO₂ foam generation nanoparticles, such as silica nanoparticles, and the effects of particle concentration and surface properties, CO₂/brine ratio, brine salinity, pressure, and temperature on foam generation and foam stability; (2) coreflooding tests to understand the nanoparticle-stabilized CO₂ foam for waterflooded residual oil recovery, which include: oil-free coreflooding experiments with nanoparticle-stabilized CO₂ foam to understand the transportation of nanoparticles through the core; measurements of foam stability and CO₂ sweep efficiency under reservoir conditions to investigate temperature and pressure effects on the foam performance and oil recovery as well as the sweep efficiency in different core samples with different rock properties; and (3) long-term coreflooding experiments with the nanoparticle- stabilized CO₂ foam for residual oil recovery. Finally, the technical and economical feasibility of this technology was evaluated.

02 PETROLEUM↗
DOE OSTI2015

YARNsim: Simulating Hadoop YARN

Despite the popularity of the Apache Hadoop system, its success has been limited by issues such as single points of failure, centralized job/task management, and lack of support for programming models other than MapReduce. The next generation of Hadoop, Apache Hadoop YARN, is designed to address these issues. In this paper, we propose YARNsim, a simulation system for Hadoop YARN. YARNsim is based on parallel discrete event simulation and provides protocol-level accuracy in simulating key components of YARN. YARNsim provides a virtual platform on which system architects can evaluate the design and implementation of Hadoop YARN systems. Also, application developers can tune job performance and understand the tradeoffs between different configurations, and Hadoop YARN system vendors can evaluate system efficiency under limited budgets. To demonstrate the validity of YARNsim, we use it to model two real systems and compare the experimental results from YARNsim and the real systems. The experiments include standard Hadoop benchmarks, synthetic workloads, and a bioinformatics application. The results show that the error rate is within 10% for the majority of test cases. The experiments prove that YARNsim can provide what-if analysis for system designers in a timely manner and at minimal cost compared with testing and evaluating on a real system.

Hadoop↗
DOE OSTI2014

Large object investigation by digital holography with effective spectrum multiplexing under single-exposure approach

We present a method to investigate large object by digital holography with effective spectrum multiplexing under single-exposure approach. This method splits the original reference beam and redirects one of its branches as a second object beam. Through the modified Mach-Zehnder interferometer, the two object beams can illuminate different parts of the large object and create a spectrum multiplexed hologram onto the focal plane array of the charge-coupled device/complementary metal oxide semiconductor camera. After correct spectrum extraction and image reconstruction, the large object can be fully observed within only one single snap-shot. The flexibility and great performance make our method a very attractive and promising technique for large object investigation under common 632.8 nm illumination.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Aloperine attenuated neuropathic pain induced by chronic constriction injury via anti-oxidation activity and suppression of the nuclear factor kappa B pathway

Highlights: • Aloperine has anti-nociceptive effects on neuropathic pain induced CCI. • Aloperine reduces ROS in neuropathic pain mice. • Aloperine down-regulates the expression of NF-κB and its downstream pro-inflammatory cytokines in neuropathic pain mice. - Abstract: Objective: To investigate whether aloperine (ALO) has antinociceptive effects on neuropathic pain induced by chronic constriction injury, whether ALO reduces ROS against neuropathic pain, and what are the mechanisms involved in ALO attenuated neuropathic pain. Methods: Mechanical and cold allodynia, thermal and mechanical hyperalgesia and spinal thermal hyperalgesia were estimated by behavior methods such as Von Frey filaments, cold-plate, radiant heat, paw pressure and tail immersion on one day before surgery and days 7, 8, 10, 12 and 14 after surgery, respectively. In addition, T-AOC, GSH-PX, T-AOC and MDA in the spinal cord (L4/5) were measured to evaluate anti-oxidation activity of ALO on neuropathic pain. Expressions of NF-κB and pro-inflammatory cytokines (TNF-α, IL-6, IL-1β) in the spinal cord (L4/5) were analyzed by using Western blot. Results: Administration of ALO (80 mg/kg and 40 mg/kg, i.p.) significantly increased paw withdrawal threshold, paw pressure, paw withdrawal latencies, tail-curling latencies, T-AOC, GSH-PX and T-SOD concentration, reduced the numbers of paw lifts and MDA concentration compared to CCI group. ALO attenuated CCI induced up-regulation of expressions of NF-κB, TNF-α, IL-6, IL-1β at the dose of 80 mg/kg (i.p.). Pregabalin produced similar effects serving as positive control at the dose of 10 mg/kg (i.p.). Conclusion: ALO has antinociceptive effects on neuropathic pain induced by CCI. The antinociceptive effects of ALO against neuropathic pain is related to reduction of ROS, via suppression of NF-κB pathway.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2014

Nonlinear buckling analyses of a small-radius carbon nanotube

Carbon nanotube (CNT) was first discovered by Sumio Iijima. It has aroused extensive attentions of scholars from all over the world. Over the past two decades, we have acquired a lot of methods to synthesize carbon nanotubes and learn their many incredible mechanical properties such as experimental methods, theoretical analyses, and computer simulations. However, the studies of experiments need lots of financial, material, and labor resources. The calculations will become difficult and time-consuming, and the calculations may be even beyond the realm of possibility when the scale of simulations is large, as for computer simulations. Therefore, it is necessary for us to explore a reasonable continuum model, which can be applied into nano-scale. This paper attempts to develop a mathematical model of a small-radius carbon nanotube based on continuum theory. An Isotropic circular cross-section, Timoshenko beam model is used as a simplified mechanical model for the small-radius carbon nanotube. Theoretical part is mainly based on modified couple stress theory to obtain the numerical solutions of buckling deformation. Meanwhile, the buckling behavior of the small radius carbon nanotube is simulated by Molecular Dynamics method. By comparing with the numerical results based on modified couple stress theory, the dependence of the small-radius carbon nanotube mechanical behaviors on its elasticity constants, small-size effect, geometric nonlinearity, and shear effect is further studied, and an estimation of the small-scale parameter of a CNT (5, 5) is obtained.

42 ENGINEERING↗
DOE OSTI2013

Site Environmental Report For Calendar Year 2012. DOE Operations at The Boeing Company Santa Susana Field Laboratory, Area IV

This Annual Site Environmental Report (ASER) for 2012 describes the environmental conditions related to work performed for the Department of Energy (DOE) at Area IV of Boeing’s Santa Susana Field Laboratory (SSFL). The Energy Technology Engineering Center (ETEC), a government-owned, company-operated test facility, was located in Area IV. The operations in Area IV included development, fabrication, operation and disassembly of nuclear reactors, reactor fuel, and other radioactive materials. Other activities in the area involved the operation of large-scale liquid metal facilities that were used for testing non-nuclear liquid metal fast breeder reactor components. All nuclear work was terminated in 1988, and all subsequent radiological work has been directed toward environmental restoration and decontamination and decommissioning (D&D) of the former nuclear facilities and their associated sites. Liquid metal research and development ended in 2002. Since May 2007, the D&D operations in Area IV have been suspended by the DOE, but the environmental monitoring and characterization programs have continued. Results of the radiological monitoring program for the calendar year 2012 continue to indicate that there are no significant releases of radioactive material from Area IV of SSFL. All potential exposure pathways are sampled and/or monitored, including air, soil, surface water, groundwater, direct radiation, transfer of property (land, structures, waste), and recycling.

Liu, Ning↗