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Lin, Yirong

Publications and source records attributed to Lin, Yirong.

34 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Fabrication and characterization of 3D printing induced orthotropic functional ceramics

The orthotropic functional properties of additively manufactured ceramics due to the fabrication process was characterized in this study. Spherical, environmentally benign barium titanate (BaTiO 3 ) powders were fabricated using binder jetting 3D printing. Dielectric and piezoelectric properties of these ceramics were characterized as a function of the printing orientation. The dielectric constant of the samples tested normal to the printing layers was observed to be 20% higher than those tested in the parallel fashion. Similarly, the piezoelectric response was found to be over 35% in the normal orientation. With these results, it was shown that the electroding orientation has a direct influence on the functional properties of additively manufactured ceramics. Overall, with less than 37% of the theoretical density, the average piezoelectric coefficient for the perpendicularly tested ceramics was found to be 152.7 pC N -1 , which is 80% of the theoretical value. Finally, the high piezoelectric response obtained with such low densities can lead to the development of more mass efficient, and cost-effective sensing and energy harvesting devices, as well as structures that can be tuned to respond based on the direction of the loads applied.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Particle size influence on material properties of BaTiO 3 ceramics fabricated using freeze-form extrusion 3D printing

Barium titanate (BaTiO 3 ; BTO) is a well-known lead-free piezoelectric material commonly used for sensors and actuators applications. There are several traditional methods to fabricate bulk BTO ceramics; however, most of those methods have restrictions regarding being able to produce a functional and complex shape for specific application needs. Recently, additive manufacturing techniques such as binder jetting have enabled the fabrication of complex designs of piezoelectric ceramics. However, the density achieved is relatively low thus narrowing their applications. This paper presents the fabrication of high-density BaTiO 3 ceramics using Freeze-form Extrusion Fabrication (FEF). The influence on material properties for different ceramic particle size was assessed. It was found that parts printed using finer BaTiO 3 particle sizes achieved better results in terms of density, piezoelectric, and dielectric properties. For this study, the 100 nm BaTiO 3 samples achieved 85.24% density, a high piezoelectric property of 204.61pC/N and dielectric permittivity of 2551. These results demonstrated the feasibility of using FEF additive manufacturing to fabricate high-quality functional ceramics with designed geometry in a mold-free fashion.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Systems and methods for wireless temperature sensing

Wireless temperature sensing systems and methods include an active sensor for determining temperature parameters in harsh environments, such as in very high temperature conditions, and wireless conveyance of the detected parameters. In an example embodiment, a pyroelectric element can generate a voltage when subjected to a temperature change. A coil is electrically coupled to the pyroelectric element and configured to generate a magnetic field in response to a current induced by the voltage generated by the pyroelectric element. A pickup is electromagnetically coupled with and detects the magnetic field generated by the coil, and the pickup is configured to provide an output corresponding to the detected magnetic field.

Lin, Yirong↗
DOE OSTI2017

Investigation on Smart Parts with Embedded Piezoelectric Sensors via Additive Manufacturing

The goal of this proposed research is to design, fabricate, and evaluate “smart parts” with embedded sensors for energy systems. The “smart parts” will be fabricated using Electron Beam Melting (EBM) 3D printing technique with built-in piezoceramic sensors. The objectives of the proposed project are: 1) Fabricate energy system related components with embedded sensors, 2) Evaluate the mechanical properties and sensing functionalities of the “smart parts” with embedded piezoceramic sensors, and 3) Assess in-situ sensing capability of energy system parts. The second year’s research of the research is centered on fabrication of the “smart parts” with considerations of overall material property as well as demonstration of sensing functionalities. The results for the final report are presented here, including all research accomplishment, project management. Details are included such as: how the design and fabrication of sensor packaging could improve the sensor performance, demonstration of “smart parts” sensing capabilities, analysis on the elements that constitute the “smart sensors”, advanced “stop and go” fabrication process, smart injector fabrication using SLM technology, smart injector testing in combustion environments etc. Research results to date have generated several posters and papers.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2017

Characterization of the pyroelectric coefficient of a high-temperature sensor

Temperature is one of the most important thermodynamic properties measured and controlled in energy generation systems. To operate the energy system at optimum operating conditions for lower emission and higher efficiency, it is important to measure real-time temperatures. Furthermore, temperature sensing in intense environments is necessary since most sensors in energy systems get exposed to elevated temperatures, corrosive environments, and elevated pressures. One of the solutions for developing harsh environment sensors is to use ceramic materials, especially functional ceramics such as pyroelectrics. Pyroelectric ceramics could be used to develop active sensors for both temperature and pressure due to their capabilities in coupling energy among mechanical, thermal, and electrical domains. In this study, Lithium niobate (LiNbO 3 ) pyroelectric ceramic material was used to develop a temperature sensor for high-temperature applications. LiNbO 3 has high Curie temperature (1210°C) compared to other pyroelectric ceramic materials. A high Curie temperature material is important since the polarization properties of the material break down above the Curie temperature. Hence, the use of a material with a higher Curie temperature, such as LiNbO 3 , makes it promising to be used as a sensing material for high-temperature applications. A study was performed to actively measure the temperature up to 500°C using a pyroelectric ceramic lithium niobate (LiNbO 3 ) as a sensor material. Due to the non-linear pyroelectric response of LiNbO 3 , the temperature-dependent pyroelectric coefficient of LiNbO 3 was measured with a dynamic pyroelectric coefficient technique in temperature ranges up to 500°C. Temperature-dependent pyroelectric coefficient of LiNbO 3 was found to increase from −0.5 × 10 −5 to −3.70 × 10 −5 C/m 2 °C from room temperature to 500°C. The LiNbO 3 sensor was then tested for higher temperature sensing at 220°C, 280°C, 410°C, and 500°C and has shown 4.31%, 2.1%, 0.4%, and 0.6% deviation, respectively, compared with thermocouple measurements.

Sarker, Md Rashedul H.↗
DOE OSTI2017

Porous Carbon/CeO2 Nanoparticles Hybrid Material for High-Capacity Super-Capacitors

The increasing demand for energy storage devices has propelled research for developing efficient supercapacitors (SC) with long cycle life and ultrahigh energy density. Carbon-based materials are commonly used as electrode materials for SC. Herein, we report a new approach to improve the SC performance utilizing a Porous Carbon/Cerium Oxide nanoparticle (PC-CON) hybrid as electrode material synthesized via a low temperature hydrothermal method. Through this approach, charges can be stored not only via electrochemical double layer capacitance (EDLC) from PC but also through pseudo-capacitive effect from CeO2 nanoparticles (NPs). The electrode-electrolyte interaction due to the electrochemical properties of the electrolyte provides a enhanced voltage window for the SC. Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), and X-Ray Diffraction (XRD) measurements were used for the characterization of this PC/CeO2 hybrid material system. The testing results have shown that a maximum of 500% higher specific capacitance could be obtained using PC/CeO2 instead of using PC only.

Kim, Hoejin↗
DOE OSTI2015

Microwave exfoliated graphene oxide/TiO{sub 2} nanowire hybrid for high performance lithium ion battery

Lithium ion battery (LIB) is a key solution to the demand of ever-improving, high energy density, clean-alternative energy systems. In LIB, graphite is the most commonly used anode material; however, lithium-ion intercalation in graphite is limited, hindering the battery charge rate and capacity. To date, one of the approaches in LIB performance improvement is by using porous carbon (PC) to replace graphite as anode material. PC's pore structure facilitates ion transport and has been proven to be an excellent anode material candidate in high power density LIBs. In addition, to overcome the limited lithium-ion intercalation obstacle, nanostructured anode assembly has been extensively studied to increase the lithium-ion diffusion rate. Among these approaches, high specific surface area metal oxide nanowires connecting nanostructured carbon materials accumulation have shown promising results for enhanced lithium-ion intercalation. Herein, we demonstrate a hydrothermal approach of growing TiO{sub 2} nanowires (TON) on microwave exfoliated graphene oxide (MEGO) to further improve LIB performance over PC. This MEGO-TON hybrid not only uses the high surface area of MEGO but also increases the specific surface area for electrode–electrolyte interaction. Therefore, this new nanowire/MEGO hybrid anode material enhances both the specific capacity and charge–discharge rate. Scanning electron microscopy and X-ray diffraction were used for materials characterization. Battery analyzer was used for measuring the electrical performance of the battery. The testing results have shown that MEGO-TON hybrid provides up to 80% increment of specific capacity compared to PC anode.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗