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Li, Yongjun

Publications and source records attributed to Li, Yongjun.

41 records · Page 3

Nuclear spin conversion of water inside fullerene cages detected by low-temperature nuclear magnetic resonance

The water-endofullerene H{sub 2}O@C{sub 60} provides a unique chemical system in which freely rotating water molecules are confined inside homogeneous and symmetrical carbon cages. The spin conversion between the ortho and para species of the endohedral H{sub 2}O was studied in the solid phase by low-temperature nuclear magnetic resonance. The experimental data are consistent with a second-order kinetics, indicating a bimolecular spin conversion process. Numerical simulations suggest the simultaneous presence of a spin diffusion process allowing neighbouring ortho and para molecules to exchange their angular momenta. Cross-polarization experiments found no evidence that the spin conversion of the endohedral H{sub 2}O molecules is catalysed by {sup 13}C nuclei present in the cages.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Analysis of Mis-Steered Electron Beam in the NSLS-II Storage Ring

This note reports the analysis of the mis-steered electron in the NSLS-II storage ring for the determination of supplementary shielding. The potential angles and offsets of the mis-steered beam are calculated by implementing the cascaded parameter scan (CPS) along the beam-line. This method is originally developed for the top-off safety analysis, and has been well documented in ref. The basic idea of CPS is to combine the phase space images due to different magnet set-points into one superset, then re-populate virtual particles on a fine grid as the input of the downstream magnet scanning. The purpose of re-population in phase space is to avoid the redundant particle tracking calculation due to the multi-layer overlap of different magnet settings. A parallel python code of implementing the tracking study has been written, and benchmarked with other top-off safety simulators developed in SLAC and LBNL.

36 MATERIALS SCIENCE↗

InGaAs/InP heteroepitaxial Schottky barrier diodes for terahertz applications

This paper explores the feasibility of planar, sub-harmonically pumped, anti-parallel InGaAs/InP heteroepitaxial Schottky diodes for terahertz applications. We present calculations of the (I-V) characteristics of such diodes using a numerical model that considers tunneling. We also present noise and conversion loss predictions of diode mixers operated at 500 GHz, and obtained from a multi-port mixer analysis, using the I-V characteristics predicted by our model. Our calculations indicate that InGaAs/InP heteroepitaxial Schottky barrier diodes are expected to have an I-V characteristic with an ideality factor comparable to that of GaAs Schottky diodes. However, the reverse saturation current of InGaAs/InP diodes is expected to be much greater than that of GaAs diodes. These predictions are confirmed by experiment. The mixer analyses predict that sub-harmonically pumped anti-parallel InGaAs/InP diode mixers are expected to offer a 2 dB greater conversion loss and a somewhat higher single sideband noise temperature than their GaAs counterparts. More importantly, the InGaAs/InP devices are predicted to require only one-tenth of the local oscillator power required by similar GaAs diodes.

Bhapkar, Udayan V.↗