Engineering topics

Leone, Stephen R.

Publications and source records attributed to Leone, Stephen R..

25 records · Page 2

NASA NTRS1993

Laboratory studies of low-temperature reactions of C2H with C2H2 and implications for atmospheric models of Titan

Rate coefficients for the reaction C2H + C2H2 - C4H2 + H are measured over the temperature range 170-350 K. The reactions are carried out in a temperature variable flow cell. C2H radicals are produced by pulsed laser photolysis of C2H2 and a tunable infrared color-center laser is used to probe the transient removal of C2H in absorption to derive the rate coefficients. The rate coefficient is obtained and shown to be independent of temperature over the range 170-350 K. The reaction studied is of central importance for models of the photochemistry of the atmospheres of the outer planets, in particular for the satellite Titan, and the implications of the present results for these models are discussed.

Pedersen, Jens O. P.↗

NASA NTRS1992

Laboratory studies of low temperature rate coefficients: The atmospheric chemistry of the outer planets

The purpose of the project is to perform laboratory measurements of reaction rate coefficients at low temperature. The reactions and temperatures of interest are those that are important in the chemistry of the hydrocarbon rich atmospheres of the outer planets and their satellites. In this stage of the study we are investigating reactions of ethynyl radicals, C2H, with acetylene (C2H2), methane (CH4), and hydrogen (H2). In the previous status report from 24 Jan. 1992, we reported on the development of the experimental apparatus and the first, preliminary data for the C2H + C2H2 reaction.

Leone, Stephen R.↗

NASA NTRS1990

Novel laser gain and time-resolved FTIR studies of photochemistry

Several techniques are discussed which can be used to explore laboratory photochemical processes and kinetics relevant to planetary atmospheres; these include time-resolved laser gain-versus-absorption spectroscopy and time-resolved Fourier transform infrared (FTIR) emission studies. The laser gain-versus-absorption method employed tunable diode and F-center lasers to determine the yields of excited photofragments and their kinetics. The time-resolved FTIR technique synchronizes the sweep of a commercial FTIR with a pulsed source of light to obtain emission spectra of novel transient species in the infrared. These methods are presently being employed to investigate molecular photodissociation, the yields of excited states of fragments, their subsequent reaction kinetics, Doppler velocity distributions, and velocity-changing collisions of translationally fast atoms. Such techniques may be employed in future investigations of planetary atmospheres, for example to study polycyclic aromatic hydrocarbons related to cometary emissions, to analyze acetylene decomposition products and reactions, and to determine spectral features in the near infrared and infrared wavelength regions for planetary molecules and clusters.

Leone, Stephen R.↗

NASA NTRS1987

Innovative methods for the measurement of I* quantum yields and kinetics by diode laser gain-versus-absorption

The quantum yields of a variety of candidate molecules for solar lasant materials to produce I* were tested. The absorption spectrum was measured for each compound and the I* yield determined by the diode laser or by infrared emission, using C3F7I as a standard. The results of these measurements are summarized. A GaAsInP diode laser system was developed to probe I and I* atoms to obtain yields and kinetics. A technique of gain-versus-absorption spectroscopy was investigated to measure quantum yields with high accuracy. The errors in the yield data were reduced to +/- 2% or less. In addition, experiments were set up to measure the rates of F-sublevel changing collisions in both the I ground state and the I* excited state. Finally, experiments and modelling were carried out to explore the possibility of measuring the recombination rates of I* with C3F7 radicals.

Leone, Stephen R.↗

NASA NTRS1987

Absolute I(asterisk) quantum yields for the ICN A state by diode laser gain-vs-absorption spectroscopy

Absolute I(asterisk) quantum yields have been measured as a function of wavelength for room temperature photodissociation of the ICN A state continuum. The yields are obtained by the technique of time-resolved diode laser gain-vs-absorption spectroscopy. Quantum yields are evaluated at seven wavelengths from 248 to 284 nm. The yield at 266 nm is 66.0 + or - 2 percent and it falls off to 53.4 + or - 2 percent and 44.0 + or - 4 percent at 284 and 248 nm, respectively. The latter values are significantly higher than those obtained by previous workers using infrared fluorescence. Estimates of I(asterisk) quantum yields obtained from analysis of CN photofragment rotational distributions, as discussed by other workers, are in good agreement with the I(asterisk) yields reported here. The results are considered in conjunction with recent theoretical and experimental work on the CN rotational distributions and with previous I(asterisk) quantum yield results.

Hess, Wayne P.↗

NASA NTRS1987

Absolute 1* quantum yields for the ICN A state by diode laser gain versus absorption spectroscopy

Absolute I* quantum yields were measured as a function of wavelength for room temperature photodissociation of the ICN A state continuum. The temperature yields are obtained by the technique of time-resolved diode laser gain-versus-absorption spectroscopy. Quantum yields are evaluated at seven wavelengths from 248 to 284 nm. The yield at 266 nm is 66.0 +/- 2% and it falls off to 53.4 +/- 2% and 44.0 +/- 4% at 284 and 248 respectively. The latter values are significantly higher than those obtained by previous workers using infrared fluorescence. Estimates of I* quantum yields obtained from analysis of CN photofragment rotational distributions, as discussed by other workers, are in good agreement with the I* yields. The results are considered in conjunction with recent theoretical and experimental work on the CN rotational distributions and with previous I* yield results.

Hess, Wayne P.↗

NASA NTRS1986

Transient gain-versus-absorption laser probing of spin-orbit states, kinetics and dynamics

The spin-orbit populations of excited (2P1/2) and ground (2P3/2) state Br atoms at 2714 nm and I atoms at 1315 nm are examined using a tunable F-center laser and a diode laser. The transient laser gain-versus-absorption measurements are utilized to estimate quantum yields of the spin-orbit states in the photodissociation of Br- and I-containing compounds; the continuum yields for Br2 are investigated in terms of temperature. The collisional release, Doppler velocity effects, and differing reactivity of the spin-orbit excited and ground state atoms are studied. It is noted that the transient gain versus absorption technique is applicable to the analysis of kinetic phenomena due to its high sensitivity and excellent time resolution.

Smedley, John E.↗