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Lee, S

Publications and source records attributed to Lee, S.

At least 91 records · Page 5

Mode-locking of solid-state lasers by single-walled carbon-nanotube based saturable absorbers

Universal use of single-walled carbon-nanotube based saturable absorber devices for mode-locking of bulk solid-state lasers between 0.8 and 2 {mu}m is discussed. The advantages in comparison to semiconductor saturable absorbers are emphasised. We briefly describe the manufacturing process and the essential optical properties, and review experimental results obtained with various types of femtosecond and picosecond solid-state lasers in the steady-state regime. We also demonstrate that a single hybrid saturable absorber used in transmission can be used to mode-lock four different types of lasers operating between 1 and 2 {mu}m. (control of laser radiation parameters)

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

COMPARISON OF EXPERIMENTS TO CFD MODELS FOR MIXING USING DUAL OPPOSING JETS IN TANKS WITH AND WITHOUT INTERNAL OBSTRUCTIONS

This paper documents testing methods, statistical data analysis, and a comparison of experimental results to CFD models for blending of fluids, which were blended using a single pump designed with dual opposing nozzles in an eight foot diameter tank. Overall, this research presents new findings in the field of mixing research. Specifically, blending processes were clearly shown to have random, chaotic effects, where possible causal factors such as turbulence, pump fluctuations, and eddies required future evaluation. CFD models were shown to provide reasonable estimates for the average blending times, but large variations -- or scatter -- occurred for blending times during similar tests. Using this experimental blending time data, the chaotic nature of blending was demonstrated and the variability of blending times with respect to average blending times were shown to increase with system complexity. Prior to this research, the variation in blending times caused discrepancies between CFD models and experiments. This research addressed this discrepancy, and determined statistical correction factors that can be applied to CFD models, and thereby quantified techniques to permit the application of CFD models to complex systems, such as blending. These blending time correction factors for CFD models are comparable to safety factors used in structural design, and compensate variability that cannot be theoretically calculated. To determine these correction factors, research was performed to investigate blending, using a pump with dual opposing jets which re-circulate fluids in the tank to promote blending when fluids are added to the tank. In all, eighty-five tests were performed both in a tank without internal obstructions and a tank with vertical obstructions similar to a tube bank in a heat exchanger. These obstructions provided scale models of vertical cooling coils below the liquid surface for a full scale, liquid radioactive waste storage tank. Also, different jet diameters and different horizontal orientations of the jets were investigated with respect to blending. Two types of blending tests were performed. The first set of eighty-one tests blended small quantities of tracer fluids into solution. Data from these tests were statistically evaluated to determine blending times for the addition of tracer solution to tanks, and blending times were successfully compared to Computational Fluid Dynamics (CFD) models. The second set of four tests blended bulk quantities of solutions of different density and viscosity. For example, in one test a quarter tank of water was added to a three quarters of a tank of a more viscous salt solution. In this case, the blending process was noted to significantly change due to stratification of fluids, and blending times increased substantially. However, CFD models for stratification and the variability of blending times for different density fluids was not pursued, and further research is recommended in the area of blending bulk quantities of fluids. All in all, testing showed that CFD models can be effectively applied if statistically validated through experimental testing, but in the absence of experimental validation CFD model scan be extremely misleading as a basis for design and operation decisions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The soft x-ray instrument for materials studies at the linac coherent light source x-ray free-electron laser

The soft x-ray materials science instrument is the second operational beamline at the linac coherent light source x-ray free electron laser. The instrument operates with a photon energy range of 480-2000 eV and features a grating monochromator as well as bendable refocusing mirrors. A broad range of experimental stations may be installed to study diverse scientific topics such as: ultrafast chemistry, surface science, highly correlated electron systems, matter under extreme conditions, and laboratory astrophysics. Preliminary commissioning results are presented including the first soft x-ray single-shot energy spectrum from a free electron laser.

43 PARTICLE ACCELERATORS↗

X-ray pulse preserving single-shot optical cross-correlation method for improved experimental temporal resolution

We measured the relative arrival time between an optical pulse and a soft x-ray pulse from a free-electron laser. This femtosecond cross-correlation measurement was achieved by observing the change in optical reflectivity induced through the absorption of a fraction of the x-ray pulse. The main x-ray pulse energy remained available for an independent pump-probe experiment where the sample may be opaque to soft x-rays. The method was employed to correct the two-pulse delay data from a canonical pump-probe experiment and demonstrate 130 {+-} 20 fs (FWHM) temporal resolution. We further analyze possible timing jitter sources and point to future improvements.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Electrochemical activity of glucose oxidase on a poly(ionic liquid) - Au nanoparticle composite.

Glucose oxidase (GOx) adsorbed on an ionic liquid-derived polymer containing internally organized columns of Au nanoparticles exhibits direct electron transfer and bioelectrocatalytic properties towards the oxidation of glucose. The cationic poly(ionic liquid) provides an ideal substrate for the electrostatic immobilization of GOx. The encapsulated Au nanoparticles serve to both promote the direct electron transfer with the recessed enzyme redox centers and impart electronic conduction to the composite, allowing it to function as an electrode for electrochemical detection.

36 MATERIALS SCIENCE↗

Oxidative dehydrogenation of cyclohexene on size selected subnanometer cobalt clusters: improved catalytic performance via structural fluxionality of cluster-assembled nanostructures.

The catalytic activity of oxide-supported metal nanoclusters strongly depends on their size and support. In this study, the origin of morphology transformation and chemical state changes during the oxidative dehydrogenation of cyclohexene was investigated in terms of metal-support interactions. Model catalyst systems were prepared by deposition of size selected subnanometer Co{sub 27{+-}4} clusters on various metal oxide supports (Al{sub 2}O{sub 3}, ZnO and TiO{sub 2} and MgO). The oxidation state and reactivity of the supported cobalt clusters were investigated by temperature programmed reaction (TPRx) and in situ grazing incidence X-ray absorption (GIXAS) during oxidative dehydrogenation of cyclohexene, while the sintering resistance monitored with grazing incidence small angle X-ray scattering (GISAXS). The activity and selectivity of cobalt clusters shows strong dependence on the support. GIXAS reveals that metal-support interaction plays a key role in the reaction. The most pronounced support effect is observed for MgO, where during the course of the reaction in its activity, composition and size dynamically evolving nanoassembly is formed from subnanometer cobalt clusters.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Atmospheric and Wake Turbulence Impacts on Wind Turbine Fatigue Loadings

Large-eddy simulations of atmospheric boundary layers under various stability and surface roughness conditions are performed to investigate the turbulence impact on wind turbines. In particular, the aeroelastic responses of the turbines are studied to characterize the fatigue loading of the turbulence present in the boundary layer and in the wake of the turbines. Two utility-scale 5-MW turbines that are separated by seven rotor diameters are placed in a 3 km by 3 km by 1 km domain. They are subjected to atmospheric turbulent boundary layer flow and data is collected on the structural response of the turbine components. The surface roughness was found to increase the fatigue loads while the atmospheric instability had a small influence. Furthermore, the downstream turbines yielded higher fatigue loads indicating that the turbulent wakes generated from the upstream turbines have significant impact.

17 WIND ENERGY↗

The E2 Domains of APP and APLP1 Share a Conserved Mode of Dimerization

Amyloid precursor protein (APP) is genetically linked to Alzheimer's disease. APP is a type I membrane protein, and its oligomeric structure is potentially important because this property may play a role in its function or affect the processing of the precursor by the secretases to generate amyloid {beta}-peptide. Several independent studies have shown that APP can form dimers in the cell, but how it dimerizes remains controversial. At least three regions of the precursor, including a centrally located and conserved domain called E2, have been proposed to contribute to dimerization. Here we report two new crystal structures of E2, one from APP and the other from APLP1, a mammalian APP homologue. Comparison with an earlier APP structure, which was determined in a different space group, shows that the E2 domains share a conserved and antiparallel mode of dimerization. Biophysical measurements in solution show that heparin binding induces E2 dimerization. The 2.1 {angstrom} resolution electron density map also reveals phosphate ions that are bound to the protein surface. Mutational analysis shows that protein residues interacting with the phosphate ions are also involved in heparin binding. The locations of two of these residues, Arg-369 and His-433, at the dimeric interface suggest a mechanism for heparin-induced protein dimerization.

59 BASIC BIOLOGICAL SCIENCES↗

High-Temperature Stability of Cobalt Grafted on Low-Loading Incorporated Mo-MCM-41 Catalyst for Synthesis of Single-Walled Carbon Nanotubes

Cobalt metal is a good catalyst for CO disproportionation to single-walled carbon nanotubes (SWNT) when particle size is stabilized on the nanometer scale. With reaction temperatures in the range of 973-1123 K, stabilization of nanometer Co particles against sintering requires a chemical bonding and/or occlusion of the Co particles. Catalysts with Co-grafted Mo-incorporated MCM-41 with different Mo loadings (<1 wt %) have been synthesized. Incorporation of Mo cations in the silica framework of MCM-41 provides different species as grafting sites. These grafting sites affect the strength of the metal-support interaction that controls sintering of active Co metal. The stability of Co at high temperature has been investigated by TPR and in situ/ex-situ X-ray absorption spectroscopy. The reduced Co metal particle size, after hydrogen prereduction, is independent of Mo loading. However, the Co particle size after SWNT synthesis is greatly affected by Mo anchoring and varied with loading. The Co particle size of low-Mo-loading samples after SWNT synthesis is little changed (from 0.88 nm after prereduction to 0.85 nm after SWNT synthesis), but the Co particle size difference of high-Mo-loading samples is gradually increased as the Mo loading is increased.

08 HYDROGEN↗

The Crystal Structure of GXGD Membrane Protease FlaK

The GXGD proteases are polytopic membrane proteins with catalytic activities against membrane-spanning substrates that require a pair of aspartyl residues. Representative members of the family include preflagellin peptidase, type 4 prepilin peptidase, presenilin and signal peptide peptidase. Many GXGD proteases are important in medicine. For example, type 4 prepilin peptidase may contribute to bacterial pathogenesis, and mutations in presenilin are associated with Alzheimer's disease. As yet, there is no atomic-resolution structure in this protease family. Here we report the crystal structure of FlaK, a preflagellin peptidase from Methanococcus maripaludis, solved at 3.6 {angstrom} resolution. The structure contains six transmembrane helices. The GXGD motif and a short transmembrane helix, helix 4, are positioned at the centre, surrounded by other transmembrane helices. The crystal structure indicates that the protease must undergo conformational changes to bring the GXGD motif and a second essential aspartyl residue from transmembrane helix 1 into close proximity for catalysis. A comparison of the crystal structure with models of presenilin derived from biochemical analysis reveals three common transmembrane segments that are similarly arranged around the active site. This observation reinforces the idea that the prokaryotic and human proteases are evolutionarily related. The crystal structure presented here provides a framework for understanding the mechanism of the GXGD proteases, and may facilitate the rational design of inhibitors that target specific members of the family.

59 BASIC BIOLOGICAL SCIENCES↗

Hard X-ray Nano Patterning using a Sectioned Multilayer

We report a hard x-ray patterning capable of drawing lines with a width below 100 nm using x-rays at 0.165 nm. A specially prepared mask based on multilayer growth technology was used as an x-ray mask effectively. The x-ray Talbot effect in near field was investigated and utilized in the patterning. Since multilayers with a few nanometer layer spacing are readily available, the proposed hard x-ray nano patterning, free of the limit imposed by the Rayleigh criterion in optical range, can potentially be an ultimate optical lithography technique.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Local Structure of Ba(Ti Zr)O3 Perovskite-like Solid Solutions and its Relation to the Band-gap Behavior

Local structures in BaTi{sub 1-x}Zr{sub x}O{sub 3} solid solutions were analyzed using x-ray absorption fine structure (XAFS) measurements and density-functional theory (DFT) calculations. We demonstrate that for low concentrations of Ti, isolated Ti atoms in the relatively large octahedral sites of the BaZrO{sub 3} lattice acquire centrosymmetric coordination with average Ti-O distances shorter than those in BaTiO{sub 3}. In contrast for higher concentrations of Ti, Ti atoms having one or more Ti as their B-site nearest neighbors undergo polar off-center displacements. Our DFT calculations confirm both effects. These results combined with the previously published data suggest that isolated polarizable ions on the B sites of a relatively expanded host perovskite lattice remain nonpolar by symmetric relaxation of the nearest-neighbor oxygen atoms to yield nearly ideal bond lengths around the dopant species. For neighboring Ti atoms, such symmetric relaxation is impossible, and these atoms are displaced off center. Our XAFS measurements did not detect any significant deviations from a random distribution of Ti and Zr in the present samples except for compositions close to BaTiO{sub 3}. The DFT calculations suggest that the dominant effect of the local displacements on band-gap values for this system is determined by the shortest Ti-O bonds due to strong Ti 3d-O 2p hybridization; however, local displacements have only a secondary effect on the band-gap behavior.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗