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Lee, J. I.

Publications and source records attributed to Lee, J. I..

Subnanosecond phase transition dynamics in laser-shocked iron

Iron is one of the most studied chemical elements due to its sociotechnological and planetary importance; hence, understanding its structural transition dynamics is of vital interest. By combining a short pulse optical laser and an ultrashort free electron laser pulse, we have observed the subnanosecond structural dynamics of iron from high-quality x-ray diffraction data measured at 50-ps intervals up to 2500 ps. We unequivocally identify a three-wave structure during the initial compression and a two-wave structure during the decaying shock, involving all of the known structural types of iron (α-, γ-, and ε-phase). In the final stage, negative lattice pressures are generated by the propagation of rarefaction waves, leading to the formation of expanded phases and the recovery of γ-phase. Our observations demonstrate the unique capability of measuring the atomistic evolution during the entire lattice compression and release processes at unprecedented time and strain rate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Genetic Relationship Between Martian Chassignites and Nakhlites Revealed from Noble Gases

A group called as Martian meteorites is composed of shergottites, nakhlites, chassignites, and orthopyroxenite, and they are thought to be derived from Mars. Among the Martian meteorites nakhlites and chassignites show similar cosmic-ray exposure (CRE) ages of 11-12 million years, although petrologic characteristics are very different between them. Both nakhlites and chassignites indicate similar cooling rates, and would have cooled in identical scale of igneous bodies. However, the relationship between nakhlites and chassignites is still unclear, although they might have ejected at the same time, i.e., by accidentally coincidental impact events which occurred at different places on Mars or by a single impact which excavated both nakhlites and chassignites residing in a relatively small area. Here we propose that the chassignites show a genetically close relationship with nakhlites, i.e., both groups could be located within a relatively narrow area from where a single impact could have launched those meteorites, based on noble gas data obtained in our laboratory. If chassignites were really ejected with nakhlites by a single impact, both types of meteorites will provide us with geological/petrological profile in the area where both pyroxene-rich lava (nakhlites) and dunite-rich rocks (chassignites) are located close to the Martian surface. [i.e. discusses NWA 2737, etc. (Martian meteorites that fell in Northwest Africa)]

Nagao, K.↗

Exchange Coupling in Nano-Textured SmCo5/Fe and Ni/CoFe2O4 Permanent Magnets

The widespread use of magnets in actuators, generators and sensors has driven materials optimization research for decades, aiming to match the desirable properties of high remnant magnetization, and a high coercive field, to maximizing the energy product. Currently, Dy-doped NdFeB offers the best values, but its low operating temperature and the supply challenges of Dy are driving a search for alternatives. One such notion is the development of exchange coupled magnets, which combine a high coercivity (hard) magnet with a less coercive (soft) material which has a higher magnetization and no RE content. The strength of this approach is that exchange coupling between the two phases maintains the anisotropy in the soft material at high coercive fields. The result is a composite material with high energy density that can, theoretically, exceed the performance of the pure hard phase for specific architectures. In this experiment we studied two candidate materials for an exchange coupled magnet: NiFeB coated SmCo 5 , and Ni@CoFe 2 O 4 core shell nanoparticles, using element-specific XMCD hysteresis loops to investigate the magnetisation reversal process in these composite systems.

36 MATERIALS SCIENCE↗

Manipulation of σ{sub y}/κ ratio in single phase FCC solid-solutions

We investigate how to manipulate the ratio between thermal conductivity (κ) and yield strength (σ{sub y}) in face-centered cubic solid-solutions by varying the number of principal elements (NPEs) and temperature. The influence of NPEs on κ and its electronic (κ{sub e}) and lattice (κ{sub l}) contribution is evaluated using the Wiedemann–Franz law. Positive Δκ/ΔT and the highest κ{sub l}/κ{sub e} ratio in high-entropy alloys (HEAs) can be understood by considering severe lattice distortion and compositional complexity. Among the solid-solutions from Ni to quinary alloys, the NiCoFeCrMn HEA exhibits the lowest κ. However, σ{sub y} increases with increasing NPEs and decreasing temperature. Thus, the NiCoFeCrMn HEA exhibits the highest σ{sub y}/κ ratio, higher than those of representative cryogenic alloys, which can be distinctively increased with a decrease in temperature. These results would give us a guideline on how to manipulate properties using HEA design concept in order to develop idealized cryogenic materials.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A physics study for negative void reactivity in compact supercritical CO{sub 2}-cooled fast reactor

A compact S-CO{sub 2}-cooled fast reactor which has negative Coolant Void Reactivity (CVR) has been investigated. A negative CVR is important for the gas cooled fast reactor as an inherent safety mechanism to prevent the sudden positive reactivity insertion when the loss of coolant accident happens. An alternative solution to reduce the CVR is investigated in this study by using O-17 instead of O-16 in UO{sub 2} fuel. By using O-17 in the fuel, it is found that the CVR can even be negative. Impacts of the radial reflector on the CVR are also evaluated for the small SCO{sub 2} cooled fast reactor in this study. We have considered a pure lead (Pb) reflector and a lead magnesium eutectic (LME) reflector as alternative radial reflectors of the S-CO 2-cooled fast reactor. It has been shown that, with the LME radial reflector, the CVR can be negative, while the pure lead reflector provides a slightly positive CVR. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Preliminary studies on the heat exchanger option for S-CO{sub 2} power conversion cycle coupled to water cooled SMR

For more than a half century, the steam Rankine cycle had been the major power conversion cycle for a nuclear power plant. However, as the interest on the next generation reactors grows, a variety of alternative power conversion systems have been studied. Among them, the S-CO{sub 2} cycle (Supercritical carbon dioxide Brayton cycle) is considered as a promising candidate due to several benefits such as 1) Relatively high thermal efficiency at relatively low turbine inlet temperature, 2) High efficiency with simple lay-out 3) Compactness of turbo-machineries. 4) Compactness of total cycle combined with PCHE (Printed Circuit Heat Exchanger). According to the conventional classification of heat exchangers (HE), there are three kind of HE, 1) Tubular HEs, 2) Plate-type HEs, 3) Extended surface HEs. So far, the researcher has mostly assumed PCHE type HE for the S-CO{sub 2} cycle due to its compactness with reasonably low pressure drop. However, PCHE is currently one of the most expensive components in the cycle, which can have a negative effect on the economics of the cycle. Therefore, an alternative for the HE should be seriously investigated. By comparing the operating condition (pressure and temperature) there are three kind of HE in the S-CO{sub 2} cycle, 1) IHX (Intermediate Heat exchanger) 2) Recuperator and 3) Pre-cooler. In each heat exchanger, hot side and cold side coolants are different, i.e. reactor coolant to S-CO{sub 2} (IHX), S-CO{sub 2} to S-CO{sub 2}(Recuperator), S-CO{sub 2} to water (Pre-cooler). By considering all the attributes mentioned above, all existing types of heat exchangers are compared to find a possible alternative to PCHE. The comparing factors are 1) Size(volume), 2) Cost. Plate fin type HEs are considered to be the most competitive heat exchanger regarding the size and the cost after some improvements on the design limit are made. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Preliminary design studies on a nuclear seawater desalination system

Seawater desalination is one of the most promising technologies to provide fresh water especially in the arid region. The most used technology in seawater desalination are thermal desalination (MSF and MED) and membrane desalination (RO). Some developments have been done in the area of coupling the desalination plant with a nuclear reactor to reduce the cost of energy required in thermal desalination. The coupling a nuclear reactor to a desalination plant can be done either by using the co-generation or by using dedicated heat from a nuclear system. The comparison of the co-generation nuclear reactor with desalination plant, dedicated nuclear heat system, and fossil fueled system will be discussed in this paper using economical assessment with IAEA DEEP software. A newly designed nuclear system dedicated for the seawater desalination will also be suggested by KAIST (Korea Advanced Inst. of Science and Technology) research team and described in detail within this paper. The suggested reactor system is using gas cooled type reactor and in this preliminary study the scope of design will be limited to comparison of two cases in different operating temperature ranges. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Fusion Application Targets

Complex target structures are necessary to take full advantage of the unique laboratory environment created by inertial confinement fusion experiments. For example, uses-ofignition targets that contain a thin layer of a low density nanoporous material inside a spherical ablator shell allow placing dopants in direct contact with the DT fuel. The ideal foam for this application is a low-density hydrocarbon foam that is strong enough to survive wetting with cryogenic hydrogen, and low enough in density (density less than ~30 mg/cc) to not reduce the yield of the target. Here, we discuss the fabrication foamlined uses-of-ignition targets, and the development of low-density foams that can be used for this application.

36 MATERIALS SCIENCE↗