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Lee, J. H.

Publications and source records attributed to Lee, J. H..

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Absolute rate constant for the reaction of atomic chlorine with hydrogen peroxide vapor over the temperature range 265-400 K

Rate constants for the reaction of atomic chlorine with hydrogen peroxide were measured from 265-400 K using the flash photolysis-resonance fluorescence technique. Analytical techniques were developed to measure H2O2 under reaction conditions. Due to ambiguity in the interpretation of the analytical results, the data combine to give two equally acceptable representations of the temperature dependence. The results are compared to previous work at 298 K and are theoretically discussed in terms of the mechanism of the reaction. Additional experiments on the H + H2O2 reaction at 298 and 359 K are compared with earlier results from this laboratory and give a slightly revised bimolecular rate constant.

Michael, J. V.↗
NASA NTRS1977

Absolute rate of the reaction of Cl/2P/ with methane from 200-500 K

Rate constants for the reaction Cl + CH4 yields HCl + CH3 were measured in the range 200-500 K by the plot flash photolysis-resonance fluorescence technique. An Arrhenius plot of the mean rate constant observed at 14 equally spaced temperatures is best fit by the expression k = 5.44 times 10 to the minus 19th times T to the exponent 2.50 times exp(-608/T) cu cm per molecule per sec. Appropriate expressions are also given for the rate constant in the two ranges 200-299 K and 299-500 K. These results are compared with a number of other existing determinations of the rate constant by other methods and in different temperature ranges. Most discrepancies are attributed to the nonlinear Arrhenius behavior.

Whytock, D. A.↗
NASA NTRS1977

Production of dense plasmas in a hypocycloidal pinch apparatus

A high-power pinch apparatus consisting of disk electrodes was developed, and diagnostic measurements to study its mechanism of dense plasma production have been made. The collapse fronts of the current sheets are well organized, and dense plasma foci are produced on the axis with radial stability in excess of 5 microsec. A plasma density greater than 10 to the 18th power per cu cm is determined with Stark broadening and CO2 laser absorption. Essentially complete absorption of a high-energy CO2 laser beam has been observed. A plasma temperature of approximately 1 keV is measured with differential transmission of soft X-rays through thin foils. The advantages of this apparatus over the coaxial plasma focus are improvements in (1) plasma volume, (2) stability, (3) containment time, (4) access to additional heating by laser or electron beams, and (5) the possibility of scaling up to a multiple array for high-power operation.

Lee, J. H.↗
NASA NTRS1976

Absolute rate of the reaction of Cl(p-2) with molecular hydrogen from 200 - 500 K

Rate constants for the reaction of atomic chlorine with hydrogen are measured from 200 - 500 K using the flash photolysis-resonance fluorescence technique. The results are compared with previous work and are discussed with particular reference to the equilibrium constant for the reaction and to relative rate data for chlorine atom reactions. Theoretical calculations, using the BEBO method with tunneling, give excellent agreement with experiment.

Whytock, D. A.↗
NASA NTRS1976

Absolute rate of the reaction of C l(2P) with methane from 200-500 K

Rate constants for the reaction of atomic chlorine with methane have been measured from 200-500K using the flash photolysis-resonance fluorescence technique. When the results from fourteen equally spaced experimental determinations are plotted in Arrhenius form a definite curvature is noted. The results are compared to previous work and are theoretically discussed.

Whytock, D. A.↗
NASA NTRS1976

Absolute rate of the reaction of O/3-P/ with hydrogen sulfide over the temperature range 263 to 495 K

The technique of flash photolysis coupled with time resolved detection of O via resonance fluorescence has been used to obtain rate constants for the reaction of O(3-P) with H2S at temperatures from 263 to 495 K and at pressures in the range 10-400 torr. Under conditions where secondary reactions are avoided, the measured rate constants for the primary step obey the Arrhenius equation k = (7.24 plus or minus 1.07) x 10 to the -12th exp(-3300 plus or minus 100/1.987 T) cu cm/molecules/s. Experiments with D2S show that the reaction exhibits a primary isotope effect, in support of a hydrogen abstraction mechanism.

Whytock, D. A.↗
NASA NTRS1976

Uranium plasma emission at gas-core reaction conditions

The results of uranium plasma emission produced by two methods are reported. For the first method a ruby laser was focused on the surface of a pure U-238 sample to create a plasma plume with a peak plasma density of about 10 to the 20th power/cu cm and a temperature of about 38,600 K. The absolute intensity of the emitted radiation, covering the range from 300 to 7000 A was measured. For the second method, the uranium plasma was produced in a 20 kilovolt, 25 kilojoule plasma-focus device. The 2.5 MeV neutrons from the D-D reaction in the plasma focus are moderated by polyethylene and induce fissions in the U-235. Spectra of both uranium plasmas were obtained over the range from 30 to 9000 A. Because of the low fission yield the energy input due to fissions is very small compared to the total energy in the plasma.

Williams, M. D.↗
NASA NTRS1976

Absolute rate parameters for the reaction of ground state atomic oxygen with dimethyl sulfide and episulfide

It is pointed out that the investigated reaction of oxygen with dimethyl sulfide may play an important role in photochemical smog formation and in the chemical evolution of dense interstellar clouds. Kinetic data were obtained with the aid of the flash photolysis-resonance fluorescence method. The photodecomposition of molecular oxygen provided the oxygen atoms for the experiments. The decay of atomic oxygen was studied on the basis of resonance fluorescence observations. Both reactions investigated were found to be fast processes. A negative temperature dependence of the rate constants for reactions with dimethyl sulfide was observed.

Lee, J. H.↗
NASA NTRS1976

Absorption of CO2-laser radiation in a hypocycloidal-pinch plasma

Absorption of a 50-J pulsed CO2 laser beam in the plasma produced in a hypocycloidal-pinch apparatus was studied. The apparatus consists of three disk electrodes with a 5-cm hole on the axis. The current sheets are snow-plowed toward the center of the hole to produce a plasma with a density greater than 10 to the 18th/cu cm and a temperature near 1 keV which emits soft X rays for 5 microsec. IR detectors measured the laser radiation incident onto, transmitted through, and scattered from the plasma as functions of time. For a period up to 70 microsec from the onset of X-ray emission, neither transmitted nor scattered laser radiation was observed above the detector threshold of 0.3% of the incident flux. This indicates effective absorption of the laser beam (greater than 99%) and that the particle confinement time extends far beyond the energy confinement time of 5 microsec. Thus, the plasma in this apparatus appears much more amenable to laser heating than that in a theta pinch.

Lee, J. H.↗
NASA NTRS1975

Dense plasma focus production in a hypocycloidal pinch

A type of high-power pinch apparatus consisting of disk electrodes was developed, and diagnostic measurements to study its mechanism of dense plasma production were made. The collapse fronts of the current sheets are well organized, and dense plasma focuses are produced on the axis with radial stability in excess of 5 microns. A plasma density greater than 10 to the 18th power/cubic cm was determined with Stark broadening and CO2 laser absorption. A plasma temperature of approximately 1 keV was measured with differential transmission of soft X-rays through thin foils. Essentially complete absorption of a high-energy CO2 laser beam was observed. The advantages of this apparatus over the coaxial plasma focus are in (1) the plasma volume, (2) the stability, (3) the containment time, (4) the easy access to additional heating by laser or electron beams, and (5) the possibility of scaling up to a multiple array for high-power operation.

Lee, J. H.↗
NASA NTRS1975

Absolute intensity of radiation emitted by uranium plasmas

The absolute intensity of radiation emitted by fissioning and nonfissioning uranium plasmas in the spectral range from 350 nm to 1000 nm was measured. The plasma was produced in a plasma-focus apparatus and the plasma properties are simular to those anticipated for plasma-core nuclear reactors. The results are expected to contribute to the establishment of design criteria for the development of plasma-core reactors.

Jalufka, N. W.↗
NASA NTRS1974

Production of fissioning uranium plasma to approximate gas-core reactor conditions

The intense burst of neutrons from the d-d reaction in a plasma-focus apparatus is exploited to produce a fissioning uranium plasma. The plasma-focus apparatus consists of a pair of coaxial electrodes and is energized by a 25 kJ capacitor bank. A 15-g rod of 93% enriched U-235 is placed in the end of the center electrode where an intense electron beam impinges during the plasma-focus formation. The resulting uranium plasma is heated to about 5 eV. Fission reactions are induced in the uranium plasma by neutrons from the d-d reaction which were moderated by the polyethylene walls. The fission yield is determined by evaluating the gamma peaks of I-134, Cs-138, and other fission products, and it is found that more than 1,000,000 fissions are induced in the uranium for each focus formation, with at least 1% of these occurring in the uranium plasma.

Lee, J. H.↗
NASA NTRS1972

Anisotropy of the neutron fluence from a plasma focus.

The fluence of neutrons from a plasma focus was measured by gamma spectrometry of an activated silver target. This method results in a significant increase in accuracy over the beta-counting method. Multiple detectors were used in order to measure the anisotropy of the fluence of neutrons. The fluence was found to be concentrated in a cone with a half-angle of 30 deg about the axis, and to drop off rapidly outside of this cone; the anisotropy was found to depend upon the total yield of neutrons. This dependence was strongest on the axis. Neither the axial concentration of the fluence of neutrons nor its dependence on the total yield of neutrons is explained by any of the currently proposed models. Some other explanations, including the possibility of an axially distributed source, are considered.

Lee, J. H.↗
NASA NTRS1972

Current sheet collapse in a plasma focus.

Collapse of the current sheets in a plasma focus has been recorded simultaneously through slits parallel and perpendicular to the symmetry axis in the streak mode. The dark period following the collapse is due to the plasma moving out of the field of view. Microdensitometric measurements of intensity variation also support this conclusion. A large anisotropy is also found in the x-ray radiation pattern. Effects of different vacuum vessels were investigated.

Jalufka, N. W.↗
NASA NTRS1971

Neutron production mechanism in a plasma focus.

The neutrons emitted by a plasma focus were analyzed by using a time-of-flight method. Flight paths as large as 80 m were used to obtain better than 10% energy resolution. The energy spectrum of neutrons from d-d reactions in the plasma focus shows a sharp onset with average maximum energies of 2.8 and 3.2 MeV in the radial and the axial directions, respectively. The average half-width of the energy spectrum was 270 keV with a shot-to-shot variation between 150 and 400 keV. Simultaneous measurements in the axial and radial directions showed no appreciable difference in the half-widths and thus indicated randomly oriented ion velocities in the plasma. A converging ion model is described which is found to be in agreement with the measured quantities.

Lee, J. H.↗