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Lee, D.

Publications and source records attributed to Lee, D..

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Revisiting Cu 63 NMR evidence for charge order in superconducting La 1.885 Sr 0.115 CuO 4

Here, the presence of charge and spin stripe order in the La 2 CuO 4 -based family of superconductors continues to lead to new insight on the unusual ground-state properties of high- T c cuprates. Soon after the discovery of charge stripe order at T charge ≃65 K in Nd 3+ co-doped La 1.48 Nd 0.4 Sr 0.12 CuO 4 ( T c ≃6 K), Hunt et al. demonstrated that La 1.48 Nd 0.4 Sr 0.12 CuO 4 and superconducting La 2–x Sr x CuO 4 with x~1/8( T c ≃30 K) share nearly identical NMR anomalies near Tcharge of the former. Their inevitable conclusion that La 1.885 Sr 0.115 CuO 4 also undergoes charge order at a comparable temperature became controversial, because diffraction measurements at the time were unable to detect Bragg peaks associated with charge order. Recent advances in x-ray diffraction techniques finally led to definitive confirmations of the charge order Bragg peaks in La 1.885 Sr 0.115 CuO 4 with an onset at as high as T charge ≃80 K. Meanwhile, improved instrumental technology has enabled routine NMR measurements that were not feasible two decades ago. Motivated by these new developments, we revisit the charge order transition of a La 1.885 Sr 0.115 CuO 4 single crystal based on 63 Cu NMR techniques. We demonstrate that 63 Cu NMR properties of the nuclear spin I z =–1/2 to +1/2 central transition below T charge exhibit unprecedentedly strong dependence on the measurement time scale set by the separation time τ between the 90° and 180° radio-frequency pulses; a new kind of anomalous, very broad winglike 63Cu NMR signals gradually emerge below T charge only for extremely short τ≲4μs, while the spectral weight I Normal of the normal NMR signals is progressively wiped out. The NMR linewidth and relaxation rates depend strongly on τ below T charge , and their enhancement in the charge ordered state indicates that charge order turns on strong but inhomogeneous growth of Cu spin-spin correlations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

In-situ probing of coupled atomic restructuring and metallicity of oxide heterointerfaces induced by polar adsorbates

Microscopic understanding of the surface-controlled conductivity of the two dimensional electron gas at complex oxide interfaces is crucial for developing functional interfaces. We observe conductivity and structural modification using in-situ synchrotron surface x-ray diffraction as the surface of a model LaAlO 3 /SrTiO 3 (001) heterostructure is changed by polar adsorbates. We find that polar adsorbate-induced interfacial metallicity reduces polar distortions in the LaAlO 3 layer. First-principles density functional theory calculations show that surface dipoles introduced by polar adsorbates lead to additional charge transfer and the reduction of polar displacements in the LaAlO 3 layer, consistent with the experimental observations. Our study supports that internal structural deformations controlling functionalities can be driven without the application of direct electrical or thermal bias and offers a route to tuning interfacial properties. Furthermore, these results also highlight the important role of in-situ x-ray scattering with atomic resolution in capturing and exploring structural distortions and charge density changes caused by external perturbations such as chemical adsorption, redox reaction, and generation and/or annihilation of surface defects.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2017

Effect of chemical pressure on the electronic phase transition in Ca 1-x Sr x Mn 7 O 12 films

Here, we demonstrate how chemical pressure affects the structural and electronic phase transitions of the quadruple perovskite CaMn 7 O 12 by Sr doping, a compound that exhibits a charge-ordering transition above room temperature making it a candidate for oxide electronics. We also have synthesized Ca 1-x Sr x Mn 7 O 12 (0 ≤ x ≤ 0.6) thin films by oxide molecular beam epitaxy on (LaAlO 3 ) 0.3 (SrAl 0.5 Ta 0.5 O 3 ) 0.7 (LSAT) substrates. The substitution of Sr for Ca results in a linear expansion of the lattice, as revealed by X-ray diffraction. Temperature-dependent resistivity and X-ray diffraction measurements are used to demonstrate that the coupled charge-ordering and structural phase transitions can be tuned with Sr doping. An increase in Sr concentration acts to decrease the phase transition temperature (T*) from 426 K at x = 0 to 385 K at x = 0.6. Furthemore, the presence of a tunable electronic phase transition, above room temperature, points to the potential applicability of Ca 1-x Sr x Mn 7 O 12 in sensors or oxide electronics, for example, via charge doping.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Toward Predictive Theories of Nuclear Reactions Across the Isotopic Chart: Web Report

Recent years have seen exciting new developments and progress in nuclear structure theory, reaction theory, and experimental techniques, that allow us to move towards a description of exotic systems and environments, setting the stage for new discoveries. The purpose of the 5-week program was to bring together physicists from the low-energy nuclear structure and reaction communities to identify avenues for achieving reliable and predictive descriptions of reactions involving nuclei across the isotopic chart. The 4-day embedded workshop focused on connecting theory developments to experimental advances and data needs for astrophysics and other applications. Nuclear theory must address phenomena from laboratory experiments to stellar environments, from stable nuclei to weakly-bound and exotic isotopes. Expanding the reach of theory to these regimes requires a comprehensive understanding of the reaction mechanisms involved as well as detailed knowledge of nuclear structure. A recurring theme throughout the program was the desire to produce reliable predictions rooted in either ab initio or microscopic approaches. At the same time it was recognized that some applications involving heavy nuclei away from stability, e.g. those involving fi ssion fragments, may need to rely on simple parameterizations of incomplete data for the foreseeable future. The goal here, however, is to subsequently improve and refine the descriptions, moving to phenomenological, then microscopic approaches. There was overarching consensus that future work should also focus on reliable estimates of errors in theoretical descriptions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2017

Report on INT Program INT-17-1a

The purpose of the 5-week program was to bring together physicists from the low-energy nuclear structure and reaction communities to identify avenues for achieving reliable and predictive descriptions of reactions involving nuclei across the isotopic chart. The 4-day embedded workshop focused on connecting theory developments to experimental advances and data needs for astrophysics and other applications.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2017

Decay branching ratios of excited Mg 24

Here, the nuclear reactions 12 C( 12 C, α) 20 Ne, 12 C( 12 C, p) 23 Na, and 12 C( 12 C, n) 23 Mg are the primary reactions in carbon burning, which occurs as part of several stellar processes. The Gamow window, which describes the energy range where most of these reactions take place, is typically around 1.5 MeV in the center-of-mass frame. Direct measurements of the cross sections at this energy are difficult due to the large Coulomb barrier present between the carbon nuclei; however, a successful surrogate measurement can provide the branching ratios between these reactions while avoiding the 12 C + 12 C Coulomb barrier. Finally, an experiment was performed using inelastic scattering of 40 MeV α particles on 24 Mg as a possible surrogate for the 12 C + 12 C compound nucleus.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2016

Predicting Baseline for Analysis of Electricity Pricing

To understand the impact of new pricing structure on residential electricity demands, we need a baseline model that captures every factor other than the new price. The standard baseline is a randomized control group, however, a good control group is hard to design. This motivates us to devlop data-driven approaches. We explored many techniques and designed a strategy, named LTAP, that could predict the hourly usage years ahead. The key challenge in this process is that the daily cycle of electricity demand peaks a few hours after the temperature reaching its peak. Existing methods rely on the lagged variables of recent past usages to enforce this daily cycle. These methods have trouble making predictions years ahead. LTAP avoids this trouble by assuming the daily usage profile is determined by temperature and other factors. In a comparison against a well-designed control group, LTAP is found to produce accurate predictions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2016

Utilization of native oxygen in Eu(RE)-doped GaN for enabling device compatibility in optoelectronic applications

The detrimental influence of oxygen on the performance and reliability of V/III nitride based devices is well known. However, the influence of oxygen on the nature of the incorporation of other co-dopants, such as rare earth ions, has been largely overlooked in GaN. Here, we report the first comprehensive study of the critical role that oxygen has on Eu in GaN, as well as atomic scale observation of diffusion and local concentration of both atoms in the crystal lattice. We find that oxygen plays an integral role in the location, stability, and local defect structure around the Eu ions that were doped into the GaN host. Although the availability of oxygen is essential for these properties, it renders the material incompatible with GaN-based devices. However, the utilization of the normally occurring oxygen in GaN is promoted through structural manipulation, reducing its concentration by 2 orders of magnitude, while maintaining both the material quality and the favorable optical properties of the Eu ions. Furthermore, these findings open the way for full integration of RE dopants for optoelectronic functionalities in the existing GaN platform.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Emergence of room-temperature ferroelectricity at reduced dimensions

Thinning films induces ferroelectricity Thin ferroelectric films are needed in computers and medical devices. However, traditional ferroelectric films typically become less and less polarized the thinner the films become. Instead of using a good ferroelectric and making it thinner, Lee et al. started with SrTiO 3 , which in its bulk form is not ferroelectric. This material does have naturally occurring nanosized polarized regions. and when the thickness of the SrTiO 3 films reaches the typical size of these regions, the whole film aligns and becomes ferroelectric. Science , this issue p. 1314

Lee, D.↗
DOE OSTI2015

Study of spin-ordering and spin-reorientation transitions in hexagonal manganites through Raman spectroscopy

Spin-wave (magnon) scattering, when clearly observed by Raman spectroscopy, can be simple and powerful for studying magnetic phase transitions. In this paper, we present how to observe magnon scattering clearly by Raman spectroscopy, then apply the Raman method to study spin-ordering and spin-reorientation transitions of hexagonal manganite single crystal and thin films and compare directly with the results of magnetization measurements. Our results show that by choosing strong resonance condition and appropriate polarization configuration, magnon scattering can be clearly observed and the temperature dependence of magnon scattering can be simple and powerful quantity for investigating spin-ordering as well as spin-reorientation transitions. Especially, the Raman method would be very helpful for investigating the weak spin-reorientation transitions by selectively probing the magnons in the Mn 3+ sublattices, while leaving out the strong effects of paramagnetic moments of the rare earth ions.

Science & Technology - Other Topics↗
NASA NTRS2014

Modeling the Influences of Aerosols on Pre-Monsoon Circulation and Rainfall over Southeast Asia

We conduct several sets of simulations with a version of NASA's Goddard Earth Observing System, version 5, (GEOS-5) Atmospheric Global Climate Model (AGCM) equipped with a two-moment cloud microphysical scheme to understand the role of biomass burning aerosol (BBA) emissions in Southeast Asia (SEA) in the pre-monsoon period of February-May. Our experiments are designed so that both direct and indirect aerosol effects can be evaluated. For climatologically prescribed monthly sea surface temperatures, we conduct sets of model integrations with and without biomass burning emissions in the area of peak burning activity, and with direct aerosol radiative effects either active or inactive. Taking appropriate differences between AGCM experiment sets, we find that BBA affects liquid clouds in statistically significantly ways, increasing cloud droplet number concentrations, decreasing droplet effective radii (i.e., a classic aerosol indirect effect), and locally suppressing precipitation due to a deceleration of the autoconversion process, with the latter effect apparently also leading to cloud condensate increases. Geographical re-arrangements of precipitation patterns, with precipitation increases downwind of aerosol sources are also seen, most likely because of advection of weakly precipitating cloud fields. Somewhat unexpectedly, the change in cloud radiative effect (cloud forcing) at surface is in the direction of lesser cooling because of decreases in cloud fraction. Overall, however, because of direct radiative effect contributions, aerosols exert a net negative forcing at both the top of the atmosphere and, perhaps most importantly, the surface, where decreased evaporation triggers feedbacks that further reduce precipitation. Invoking the approximation that direct and indirect aerosol effects are additive, we estimate that the overall precipitation reduction is about 40% due to the direct effects of absorbing aerosols, which stabilize the atmosphere and reduce surface latent heat fluxes via cooler land surface temperatures. Further refinements of our two-moment cloud microphysics scheme are needed for a more complete examination of the role of aerosol-convection interactions in the seasonal development of the SEA monsoon.

SE Asia Monsoon↗
NASA NTRS2014

A Novel Method for Estimating Shortwave Direct Radiative Effect of Above-Cloud Aerosols Using CALIOP and MODIS Data

This paper describes an efficient and unique method for computing the shortwave direct radiative effect (DRE) of aerosol residing above low-level liquid-phase clouds using CALIOP and MODIS data. It accounts for the overlapping of aerosol and cloud rigorously by utilizing the joint histogram of cloud optical depth and cloud top pressure. Effects of sub-grid scale cloud and aerosol variations on DRE are accounted for. It is computationally efficient through using grid-level cloud and aerosol statistics, instead of pixel-level products, and a pre-computed look-up table in radiative transfer calculations. We verified that for smoke over the southeast Atlantic Ocean the method yields a seasonal mean instantaneous shortwave DRE that generally agrees with more rigorous pixel-level computation within 4. We have also computed the annual mean instantaneous shortwave DRE of light-absorbing aerosols (i.e., smoke and polluted dust) over global ocean based on 4 yr of CALIOP and MODIS data. We found that the variability of the annual mean shortwave DRE of above-cloud light-absorbing aerosol is mainly driven by the optical depth of the underlying clouds.

radiative forcing↗
DOE OSTI2014

Impact of magnetic fields on ram pressure stripping in disk galaxies

Ram pressure stripping can remove significant amounts of gas from galaxies in clusters and massive groups and thus has a large impact on the evolution of cluster galaxies. Recent observations have shown that key properties of ram-pressure-stripped tails of galaxies, such as their width and structure, are in conflict with predictions by simulations. To increase the realism of existing simulations, we simulated for the first time a disk galaxy exposed to a uniformly magnetized wind including radiative cooling and self-gravity of the gas. We find that magnetic fields have a strong effect on the morphology of the gas in the tail of the galaxy. While in the purely hydrodynamical case the tail is very clumpy, the magnetohydrodynamical case shows very filamentary structures in the tail. The filaments can be strongly supported by magnetic pressure and, wherever this is the case, the magnetic fields vectors tend to be aligned with the filaments. The ram pressure stripping process may lead to the formation of magnetized density tails that appear as bifurcated in the plane of the sky and resemble the double tails observed in ESO 137-001 and ESO 137-002. Such tails can be formed under a variety of situations, both for the disks oriented face-on with respect to the intracluster medium (ICM) wind and for the tilted ones. While this bifurcation is the consequence of the generic tendency for the magnetic fields to produce very filamentary tail morphology, the tail properties are further shaped by the combination of the magnetic field orientation and the sliding of the field past the disk surface exposed to the wind. Despite the fact that the effect of the magnetic field on the morphology of the tail is strong, magnetic draping does not strongly change the rate of gas stripping. For a face-on galaxy, the field tends to reduce the amount of gas stripping compared to the pure hydrodynamical case, and is associated with the formation of a stable magnetic draping layer on the side of the galaxy exposed to the incoming ICM wind. For significantly tilted disks, the situation may be reversed and the stripping rate may be enhanced by the 'scraping' of the disk surface by the magnetic fields sliding past the ISM/ICM interface. Instabilities, such as gravitational instabilities, undo the protective effect of this layer and allow the gas to leak out of the galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Identifying the Critical Role of Li Substitution in P2-Na x [Li y Ni z Mn 1-y-z ]O 2 (0 < x, y, z < 1) Intercalation Cathode Materials for High-Energy Na-Ion Batteries

Li-substituted layered P2–Na 0.80 [Li 0.12 Ni 0.22 Mn 0.66 ]O 2 is investigated as an advanced cathode material for Na-ion batteries. Both neutron diffraction and nuclear magnetic resonance (NMR) spectroscopy are used to elucidate the local structure, and they reveal that most of the Li ions are located in transition metal (TM) sites, preferably surrounded by Mn ions. To characterize structural changes occurring upon electrochemical cycling, in situ synchrotron X-ray diffraction is conducted. It is clearly demonstrated that no significant phase transformation is observed up to 4.4 V charge for this material, unlike Li-free P2-type Na cathodes. The presence of monovalent Li ions in the TM layers allows more Na ions to reside in the prismatic sites, stabilizing the overall charge balance of the compound. Consequently, more Na ions remain in the compound upon charge, the P2 structure is retained in the high voltage region, and the phase transformation is delayed. Ex situ NMR is conducted on samples at different states of charge/discharge to track Li-ion site occupation changes. Surprisingly, Li is found to be mobile, some Li ions migrate from the TM layer to the Na layer at high voltage, and yet this process is highly reversible. Novel design principles for Na cathode materials are proposed on the basis of an atomistic level understanding of the underlying electrochemical processes. These principles enable us to devise an optimized, high capacity, and structurally stable compound as a potential cathode material for high-energy Na-ion batteries.

Xu, Jing↗
DOE OSTI2013

Vibrationally induced center reconfiguration in co-doped GaN:Eu, Mg epitaxial layers: Local hydrogen migration vs. activation of non-radiative channels

Europium doped gallium nitride (GaN:Eu) is a promising candidate as a material for red light emitting diodes. When Mg was co-doped into GaN:Eu, additional incorporation environments were discovered that show high excitation efficiency at room temperature and have been attributed to the coupling of Mg-H complexes to the majority Eu site. Electron beam irradiation, indirect and resonant (direct) laser excitation were found to modify these complexes, indicating that vibrational energy alone can trigger the migration of the H while the presence of additional charges and excess energy controls the type of reconfiguration and the activation of non-radiative decay channels.

36 MATERIALS SCIENCE↗
NASA NTRS2013

A Novel Method for Estimating Shortwave Direct Radiative Effect of Above-cloud Aerosols over Ocean Using CALIOP and MODIS Data

This paper describes an efficient and unique method for computing the shortwave direct radiative effect (DRE) of aerosol residing above low-level liquid-phase clouds using CALIOP and MODIS data. It accounts for the overlapping of aerosol and cloud rigorously by utilizing the joint histogram of cloud optical depth and cloud top pressure. Effects of sub-grid scale cloud and aerosol variations on DRE are accounted for. It is computationally efficient through using grid-level cloud and aerosol statistics, instead of pixel-level products, and a pre-computed look-up table in radiative transfer calculations. We verified that for smoke over the southeast Atlantic Ocean the method yields a seasonal mean instantaneous shortwave DRE that generally agrees with more rigorous pixel-level computation within 4%. We have also computed the annual mean instantaneous shortwave DRE of light-absorbing aerosols (i.e., smoke and polluted dust) over global ocean based on 4 yr of CALIOP and MODIS data. We found that the variability of the annual mean shortwave DRE of above-cloud light-absorbing aerosol is mainly driven by the optical depth of the underlying clouds.

CALIOP and MODIS↗