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Laul, J. C.

Publications and source records attributed to Laul, J. C..

At least 55 records · Page 3

The Apollo 17 drill core - Chemistry of size fractions and the nature of the fused soil component

It is shown that the Apollo 17 drill core 70009-70001 is heterogeneous with depth, containing five stratigraphic units, and has a bulk soil chemistry governed by the coarse fractions because of their greater weight proportions. The four components (1) KREEP, (2) anorthositic gabbro, (3) mare basalt, and (4) orange glass are used to model the compositions of the coarse and fine fractions of the entire drill core. It is found that the chemistry of the fused soil component in the five stratigraphic units is more similar to the chemistry of the fine, less than 20-micron fractions than the coarse fraction, suggesting that agglutinates may prefferentially meld and replicate the chemistry of the finer size fractions. The sources of Zn are the orange/black glasses, and the Zn profile is anticorrelated with the maturity index of Morris et al (1979), indicating the liberation of Zn during soil maturation.

Laul, J. C.↗

The Apollo 17 drill core - Petrologic systematics and the identification of a possible Tycho component

Modal data support a five-unit stratigraphy for the Apollo 17 drill core. The upper unit E (0-22 cm depth) is marked by high content of fused soil, brown glass, and mare basalt fragments. This unit corresponds with a portion of the core excavated and refilled within the last 2 m.y. The underlying unit D (22071 cm depth) has a low abundance of fused soil (i.e., low maturity) and is rich in coarse (less than 200 microns) mare fragments. A large section of the core, unit C (71-224 cm depth), is finer-grained, more mature (richer in agglutinates), more feldspathic and has more highland lithic, mineral and glass fragments than unit D. The next underlying unit, B (224-256 cm depth), has yellow/colorless KREEP glasses with a high Si, low-alkali composition unlike the common Apollo 15 or Apollo 17 KREEP series. The petrologic (fused soil) and Is/FeO maturity of this layer is also lower than the units above and below. The deepest unit, A (256-284 cm depth), is marked by its relatively higher maturity and lower yellow/colorless KREEP glass content. The most prominent petrographic/stratigraphic indicators are the pyroxene-rich immature mare unit D and the abundance of KREEP glass in unit B. This KREEP glass is distinctive petrographically and compositionally, and is probably exotic to the Apollo 17 site. It is suggested here that the KREEP glass in unit B is derived from Tycho, which implies widespread distribution of KREEP on the lunar nearside.

Vaniman, D. T.↗

The Apollo 17 drill core - Chemical systematics of grain size fractions

Data for 35 major, minor, and trace elements in 40 bulk and size fractions of core 70005-70003 (140-250 cm) are presented. The core is heterogeneous with depth. Moreover, the 1000 to 90 micron coarse fractions are nearly identical but quite different from the less than 20 micron fine fraction. The bulk soil chemistry is governed by the coarse fractions, because of their greater weight proportion in the sample. The 1000-90 micron fraction contains more ilmenite basalt and less orange glass components than the 90-20 micron fraction. The less than 20 micron fraction is consistently enriched in highland material at all depths in the drill core.

Laul, J. C.↗

Chemistry, mineralogy and petrology of seven greater than 1 mm fragments from Mare Crisium

Results are summarized for a consortium study of the chemistry, mineralogy, and petrology of seven Luna 24 fragments greater than 1 mm in size and having a mass of about 2 mg each. The fragments include four samples of mare ferrobasalt composition, one vitrophyre with the composition of a Mg-rich VLT mare basalt, one agglutinate, and one plagioclase fragment. It is found that: (1) the ferrobasalt is a highly fractionated mare rock very low in alkalis and TiO2, is similar to the less fractionate Apollo 17 VLT basalts, and is quite low in large-ion lithophile trace-element content; (2) the rare-earth-element patterns of the ferrobasalts are typical of VLT basalt, but some ophitic basalts have positive Eu anomalies, while others have negative Eu anomalies typical of mare basalts; and (3) the agglutinate is feldspathic and similar in composition to soil fines in Fe, Cr, Ca, and Al.

Laul, J. C.↗

Chemistry and petrology of size fractions of Apollo 17 deep drill core 70009-70006

Instrumental neutron activation analysis was used to examine 34 major, minor and trace elements in 48 bulk soils and size fractions (90-1000 microns, 20-90 microns and less than 20 microns) of the Apollo 17 deep drill core sections 70009-70006 (upper 130 cm). Modal data were also obtained for the less than 20 micron size fraction. Preliminary results indicate that (1) the chemistry of the greater than 90 micron and 20-90 micron coarse fractions is identical but quite different from the less than 20 micron fine fraction; (2) the upper 50 cm of the drill core is highly enriched in mare material; (3) the dominant source of highland material is KREEPy instead of anorthositic; and (4) indigenous volatiles such as Zn are quite high in all size fractions.

Laul, J. C.↗

Lunar regolith dynamics based on analysis of the cosmogenic radionuclides Na-22, Al-26, and Mn-53

Depth profiles of Na-22 and Al-26 in the upper portions of five lunar cores are analyzed. From the analyses, it is concluded that the natural gardening processes on the lunar surface result in mixing of the regolith to a depth of 2-3 cm over a time period which is short compared with the half-life of Al-26 (0.73 m.y.). It is also concluded that the rotary drill processes which were used to obtain the deep drill samples generally resulted in loss and/or mixing of the upper portions of the cores. In contrast, the near-surface regions of the drive tube cores appear to have a well-preserved stratigraphy. Analysis of Mn-53 in samples of six lunar rocks helps substantiate the accuracy of age date estimates by other means, and provides definite information that the total lunar surface exposure of two of these rocks has occurred during a single surface event which continued to their collection.

Fruchter, J. S.↗

Rare earth element abundances in rocks and minerals from the Fiskenaesset Complex, West Greenland

The paper reports activation-analysis determinations of rare-earth-element (REE) and other trace-element concentrations in selected rocks, plagioclase, and mafic separates from the Fiskenaesset Complex. The REE abundances are found to be very low and atypical in comparison with other terrestrial anorthosites. The plagioclases are shown to be characterized by a deficiency in heavy RE elements relative to light ones and a positive Eu anomaly, while the mafic separates are enriched in heavy rare earths and have no Eu anomaly, except in one sample. It is found that the bulk and trace-element abundances of the plagioclases are similar to those observed in some lunar anorthosites, but the degree of Eu anomaly is less in the plagioclases. The data are taken as confirmation of the idea that fractionation processes were involved in the origin of the Complex, and it is concluded that the Complex may have been produced from a magma generated by partial melting of a garnet-bearing source.

Henderson, P.↗

Thorium and uranium variations in Apollo 17 basalts, and K-U systematics

It is found that Apollo 11 low-K and in particular Apollo 17 mare basalts show a wide range of Th/U ratios unlike other rocks; such variations cannot be explained by near surface crystal fractionation. A two-stage fractional crystallization-partial melting model involving a clinopyroxene cumulate as the major phase can explain the variations in Th/U ratios. Due to the Sm-Nd systematics constraint, several source cumulates are invoked to explain the observed Th/U continuum.

Laul, J. C.↗

Some thoughts on the origin of lunar ANT-KREEP and mare basalts

It is suggested that a series of ANT (anorthosite-norite-troctolite)-KREEP type rocks and the source material for mare basalts sampled by Apollo 11, 12, 15, and 17 may have been derived from a common magmatic differentiation. This differentiation is studied on the basis of a model which proposes that, in the early history of the moon, extensive melting occurred in the outer lunar shell and a magma layer of 100-200 km was formed. The presence of a residual liquid which has not yet been sampled is suspected between high-K KREEP and the Apollo 11 basalt materials. This residual liquid would have a FeO/MgO ratio greater than one and would be significantly enriched in apatite, zircon, K-feldspar, and ilmenite minerals.

Wakita, H.↗

Dunite 72417 - A chemical study and interpretation

The rock selected for the study is one of the rare ultrabasic rocks, which seems to have survived early lunar differentiation. The Rb-Sr internal isochron for this dunite gave an age of about 4.55 AE. The dunite was sampled at Apollo 17, Station 2 from a single 10x20-cm clast incorporated into a KREEP-rich blue-gray breccia 72435, Boulder 3. Nine dunite samples were analyzed with the aid of instrumental and radiochemical neutron activation analysis procedures. Data for 27 elements are shown in a table. Attention is given to trapped liquid (magma), a garnet hypothesis, models for the dunite genesis, and magma compositions from which 15415 and 72417 crystallized.

Laul, J. C.↗

Chemical composition of boulder-2 rocks and soils, Apollo 17, Station 2

The bulk and trace element composition of five small samples from four rocks is remarkably similar. This result indicates that the metaclastic rocks studied are relatively uniform in their chemical composition. The elemental abundances found in the study are presented in two tables and the implications of the data are considered, giving attention to siderophiles, atmophile elements, and questions of element correlations. The 'dark mantle' valley soil 75081 at Camelot Crater is low in siderophiles. Since the soil is low in alkalis, a derivation from low-alkali mare basalt is suggested. The identical volatile contents in the surface soil 72461 and the 4 cm depth soil 72441 under a 0.7 m boulder argue against any surficial volatization by galactic and solar particles.

Laul, J. C.↗

Chemical studies of Apollo 16 and 17 samples

Instrumental neutron activation analyses were conducted to nine Apollo 16 samples and 23 Apollo 17 samples. Radiochemical neutron activation analyses were carried out in the case of six Apollo 16 boulder-2 rocks, five Apollo 17 soils, and one Apollo 16 soil. The elemental abundances obtained are presented in tables and the significance of the analytical results is discussed. Attention is also given to interelement correlations.

Laul, J. C.↗

The simultaneous determination of 20 trace elements in terrestrial, lunar and meteoritic material by radiochemical neutron activation analysis

A radiochemical neutron activation method has been developed and applied to determine the content of 20 trace elements (Ag, Au, Bi, Br, Cd, Co, Cs, Cu, Ga, Ge, In, Ir, Ni, Rb, Re, Sb, Te, Tl, and Zn) in 45 terrestrial, 230 lunar, and 70 meteoritic samples. Results obtained for the U.S.G.S. standard basalt BCR-1 indicate that the inherent precision for most elements is 10% or better. The values obtained for the trace elements investigated are compared to those previously reported in the literature. Data for Type I carbonaceous chondrites show their compositions to be far more uniform than previously supposed. The values obtained for several elements represent significant revisions in the accepted cosmic abundances. These new values include: Zn, 1250; Cd, 1.51; and Ir, 0.72 atoms/million Si atoms. Further results have provided insight into the meteoritic material and accretion of the moon, and give evidence of lunar highland vulcanism.

Keays, R. R.↗

A survey of the selenochemistry of major, minor and trace elements.

Average data for igneous and/or metaigneous rocks and soils from seven lunar sites are presented. There are compositional similarities between Apollo 11 and Luna 16 eastern maria, Ap 12 and 15 western maria, and between Ap 16 and L 20 highlands. Subtle differences do exist between the paired mare sites and the two highland sites and striking differences between the eastern and western maria. Chondritic normalized REE (rare earth element) patterns for igneous rocks and soils from all sites range from 7-350 generally with negative Eu anomalies. Anorthositic gabbroes to anorthosites, presumably highland material, exhibit a positive Eu anomaly. The REE patterns or Sr isotopic ratios suggest two lava flows each for the L 16 and Ap 14 sites, at least four lava flows for the Ap 11 and 12 site and about six for the Ap 15 site.

Schmitt, R. A.↗

Chemical composition of Luna 20 rocks and soil and Apollo 16 soils.

Review of the abundances of 24 major, minor, and trace elements measured by instrumental neutron activation analysis in Luna 20 metaigneous rocks, breccia, and soil, and in Apollo 16 soils. The similarities and differences observed are discussed. The bulk compositions of Luna 20 and Apollo 16 rocks and soils show close similarity between the two highland sites. Interelement correlations observed previously for maria are also found in highland samples. Luna 20 and Apollo 16 soils are low in alkalis. Both soils show an apparent Cd-Zn rich component similar to that observed at the mare sites and high Tl abundances relative to mare sites.

Laul, J. C.↗

Inter-element relationships between trace elements in primitive carbonaceous and unequilibrated ordinary chondrites.

The results of a search for significant interelement relationships among 13 trace elements in carbonaceous chondrites and 26 elements and the disequilibrium parameter for silicate phases in unequilibrated ordinary chondrites (UOC) indicate pronounced differences in the formation processes of these two sorts of primitive chondrites. Twenty-six pairs of elements are correlated in carbonaceous chondrites and these correlations lend support to a model involving mixing in different ratios of material differing in thermal history. Comparison of the 26 elements in UOC shows that 39 pairs of elements are significantly related and only very volatile elements are correlated with the disequilibrium parameter. Each of the interelement relationships can be specifically ascribed to a metal-silicate fractionation in the solar nebula or to a thermal fractionation.

Kurimoto, R. K.↗