Engineering topics

Lattimer, J. M.

Publications and source records attributed to Lattimer, J. M..

6 records

NASA NTRS1988

Enthalpies of formation of CaAl4O7 and CaAl12O19 (hibonite) by high temperature, alkali borate solution calorimetry

Enthalpies of formation were determined for two calcium aluminate phases, CaAl4O7 and CaAl12O19, using high-temperature alkali borate solution calorimetry. The aluminates were synthesized by multiple-cycle heating and grinding stoichiometric mixtures of CaCO3 and Al2O3, and the products were characteized by X-ray diffraction and SEM microbeam analysis. The data on impurities (CaAl4O7 was found to be about 89.00 percent pure by weight and the CaAl12O19 samples about 91.48 percent pure) were used to correct the heat of solution values of the synthetic products. The enthalpies of formation, at 1063 K, from oxides, were found to be equal to -(25.6 + or - 4.7) kJ/g.f.w. for CaAl4O7 and -(33.0 + or - 9.7) kJ/g.f.w. for CaAl12O19; the respective standard enthalpies of formation from elements, at 298 K, were estimated to be -4007 + or - 5.2 kJ/g.f.w. and -10,722 + or - 12 kJ/g.f.w.

Geiger, C. A.↗

NASA NTRS1979

Silicon in carbonaceous chondrite metal - Relic of high-temperature condensation

Electron microprobe analyses of an extraordinarily large metal grain from the Murchison type 2 carbonaceous chondrite gave 0.24 mole % silicon. Thermodynamic calculations show that this is a natural consequence of condensation of alloys from the solar nebular gas at a total pressure between 10 to the -5th and 10 to the -3rd atm, provided they failed to equilibrate with it after cooling to less than 1200 K

Grossman, L.↗

NASA NTRS1978

Chemical condensation sequences in supernova ejecta

Equilibrium condensation is investigated for composition and pressures representative of supernova (SN) ejecta. The results are compared with those obtained for the solar nebula, and the distribution of elements among the various gaseous species and solid phases is computed for solar and SN-shell condensation sequences. The data are applied to problems concerning the observed mass fractionations of Si, Mg, and O in Allende, as well as to the strong depletion of heavy-element abundances in the interstellar medium. The results indicate that dust grains from a SN could have introduced isotopic anomalies into the solar nebula, that many minerals produced in SN ejecta are the same as those predicted to be stable in the solar nebula, and that the observed depletion of heavy elements in the interstellar gas could be due to dust formation in SN ejecta.

Lattimer, J. M.↗

NASA NTRS1978

Condensation in supernova ejecta and isotopic anomalies in meteorites

An investigation is conducted of the physical and chemical conditions in an expanding supernova envelope, taking into account the likelihood of grain formation and the chemical composition of the grains. An 'onionskin' presupernova model is used to estimate the chemical and isotopic abundance in the various shells of ejected supernova material. Condensation calculations are performed over a range of pressures and chemical compositions for each of these shells in order to determine the type of grains which could be produced in supernova ejecta. Only grains that are stable under the physical conditions encountered in the presolar nebula can survive and retain their anomalous composition. Two regions in the presolar nebula are considered, and the possible surviving grains are deduced from the appropriate condensation sequences.

Lattimer, J. M.↗

NASA NTRS1977

Supernovae, grains and the formation of the solar system

An investigation is conducted concerning the possibility that observed Mg-26 anomalies in meteorites may be related to a nucleosynthetic event which preceded the formation of the solar system by at most a few million years. The Al-26, which decayed to form the observed excess Mg-26, could have been produced in either explosive carbon burning or in a high temperature carbon burning shell source immediately preceding the explosion. The results of supernova grain condensation calculations are presented and related to the hypothesis that a 'last event' supernova was indeed related to the formation of the solar system and thus might have created the observed isotopic anomalies in magnesium, oxygen, neon, and xenon.

Lattimer, J. M.↗

NASA NTRS1977

The decompression of cold neutron star matter

The ejection of cold neutron-star matter is examined, and an attempt is made to determine whether the final composition of this matter may be similar to that normally associated with the hot high-neutron-flux r-process. A semiempirical liquid-drop model is used for the nucleus, and the equilibrium composition of the matter is determined by assuming it to be in its absolute ground state at a given density. Physical mechanisms operating during the expansion are analyzed, and the composition of the ejected matter is found as a function of its density during expansion. The results indicate that it is virtually impossible for deuterium to form, that neutrons can be captured only after beta decay increases the atomic numbers of nuclei, and that no free neutrons can escape. It is concluded that neutron-star ejecta can produce heavy neutron-rich nuclei and may produce somewhat heavier nuclei than a standard r-process.

Lattimer, J. M.↗