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Landel, R. F.

Publications and source records attributed to Landel, R. F..

At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Preliminary investigation of elongational flow of dilute polymer solutions

A tubeless siphon apparatus has been set up to measure extensional flow. In this apparatus, the liquid is continuously drawn into a capillary and, after steady flow has been established, the tube is raised above the liquid surface. With viscoelastic liquids, the flow continues and a column can be lifted from the reservoir. At the capillary entrance, an oscillating bead of excess liquid collects which interferes with both the flow and the measurements. This can be minimized by careful control of the liquid-column height. For homogeneous solutions, the column is symmetrical and tapers steadily from the liquid surface to the capillary entrance, with no bulging. Preliminary results show tensile viscosities 1000 times that of the Trouton coefficient and having a very strong dependence on deformation rate. A concentration-stretch rate-reduced variable scheme is proposed.

Peng, S. T. J.↗
NASA NTRS1976

An experimental method to obtain the elastic strain energy function from torsion-tension tests

It is shown that by employing a torsion-tension test, it is possible to have a complete mapping near the origin of the two principal strain invariants associated with the rate of change of the strain energy function. However, the mathematical representation of the twist moment and normal forces vs strain and the strain energy function are complex. This problem is solved by using a set of solid cylindrical bars with different diameters such that the difference in diameter of two successive bars is small. The stress-strain equations can be grossly oversimplified by considering differences in twist moment and normal force as a function of difference in radius.

Peng, S. T. J.↗
NASA NTRS1976

A simple approach to metal hydride alloy optimization

Certain metals and related alloys can combine with hydrogen in a reversible fashion, so that on being heated, they release a portion of the gas. Such materials may find application in the large scale storage of hydrogen. Metal and alloys which show high dissociation pressure at low temperatures, and low endothermic heat of dissociation, and are therefore desirable for hydrogen storage, give values of the Hildebrand-Scott solubility parameter that lie between 100-118 Hildebrands, (Ref. 1), close to that of dissociated hydrogen. All of the less practical storage systems give much lower values of the solubility parameter. By using the Hildebrand solubility parameter as a criterion, and applying the mixing rule to combinations of known alloys and solid solutions, correlations are made to optimize alloy compositions and maximize hydrogen storage capacity.

Lawson, D. D.↗
NASA NTRS1976

A generalization of the Boltzmann superposition principle to polymer networks undergoing scission

Methods reported by Moacanin et al. (1975) and Moacanin and Aklonis (1971) are generalized with the objective to include strains (or stress) applied in an arbitrary manner to linearly viscoelastic materials. An imposition of changes in both the strain and the density of elastically effective chains in discrete increments is considered. In accordance with the Boltzmann superposition principle, each strain increment may be treated as a new independent experiment which adds linearly to the total response of the system.

Moacanin, J.↗
NASA NTRS1976

A description of the mechanical behavior of composite solid propellants based on molecular theory

Both the investigation and the representation of the stress-strain response (including rupture) of gum and filled elastomers can be based on a simple functional statement. Internally consistent experiments are used to sort out the effects of time, temperature, strain and crosslink density on gum rubbers. All effects are readily correlated and shown to be essentially independent of the elastomer when considered in terms of non-dimensionalized stress, strain and time. A semiquantitative molecular theory is developed to explain this result. The introduction of fillers modifies the response, but, guided by the framework thus provided, their effects can be readily accounted for.

Landel, R. F.↗
NASA NTRS1976

A simple approach to metal hydride alloy optimization

Hildebrand-Scott (1950) solubility parameters can be obtained for metals and alloys by calculating the cohesive energy density (CED), equal to the square of the solubility parameter, and a function of the heat of sublimation and the atomic volume. It is suggested that the solubility parameter permits estimation of the hydrogen storage capacity of an alloy and that alloys with a solubility parameter approximately equal to the parameter for hydrogen will have greater hydrogen storage capacity than other alloys. Equilibrium pressure - temperature relationships for some metal hydrides are presented in conjunction with the calculated solubility parameter and correlated with characteristics which would be useful in hydrogen-powered vehicles. Alloy properties which increase the amount of nonstoichiometric reversible hydrogen absorption are discussed.

Lawson, D. D.↗
NASA NTRS1975

Stored energy function and compressibility of compressible rubberlike materials under large strain

By using new invariants in the theory of finite elasticity an expression is obtained for the stored energy function of slightly compressible materials in which the effects of the distortional change (change of shape) and of the volume change are clearly separated. The volume-related terms are expressed as a function of the third invariant, the classical compressibility, and an induced anisotropy of the effective compressibility which is due to the large deformations. After evaluating the terms, using data on pressure, volume, uniaxial strain, and fractional volume change vs strain data on natural rubber from the literature, it is shown that the volume change contribution to the total stress observed in a simple tensile experiment can be clearly separated from the distortional contribution, even at finite strains.

Peng, S. T. J.↗
NASA NTRS1975

Induced anisotropy of thermal conductivity of polymer solids under large strains

A simple analytical form of induced anisotropy of heat conductivity of initially isotropic polymer solids results from employing the simplified theory of the three-chain model of the non-Gaussian network. The analytical form appears to be valid up to a stretch ratio of 2.65, which is the limit of existing experimental data. The effect of induced anisotropy on the temperature distribution, due to the large deformations, is illustrated for a highly expanded spherical shell and a cylindrical tube under a steady-state heat flow using the derived analytical form of the strain-dependent heat conductivity.

Peng, S. T. J.↗
NASA NTRS1974

Miniature load cell instrumentation for finite deformation biaxial testing of elastomers

Accuracy of biaxial test equipment to examine the nonlinear mechanical behavior of thin sheet specimens of elastomeric materials has been hampered by lack of precise determination of the force distribution along the sides of the specimen. It has been necessary to use an effective width established by approximate means to obtain the stress from the overall force applied along the edges. To avoid this experimental difficulty, individual miniature proof-ring load cells utilizing semiconductor strain gages have been developed and applied to the support hooks for the thin sheet specimens. Typical results are shown for time-dependent stress distributions for all degrees of biaxiality. An accurate evaluation of the effective specimen width is now possible.

Arenz, R. J.↗
NASA NTRS1973

Recent advances in elastomer service-life prediction

The mechanical properties of an elastomer, including rupture and its time dependence, are defined uniquely by a tensile property surface in normalized stress-strain-time coordinates. In practice, the property surface is determined from short-time constant strain-rate uniaxial tests. By using the time reduction properties of both temperature and cross-link density, an effective time scale of over ten decades of log time can be covered. Changes in cross-link density, filler content, or swelling do not affect the limits of the property surface when plotted in logarithmic coordinates but merely shift their positions. The shape, however, may be modified in certain cases. The service life of an elastomer in the absence of aging reactions can be estimated from the property surface and expected in-use conditions such as strains (static or dynamic).

Landel, R. F.↗
NASA NTRS1972

Parallel-plate viscometer

Viscometer consists of movable vertical rod with one optical flat fixed to its lower end and centered over second optical flat held rigidly parallel to moveable flat. Two perforated diaphragms of thin metal permit limited amount of vertical movement of rod carrying movable flat, but resist lateral movement.

Fearnehough, H. T.↗
NASA NTRS1972

Stored energy function of rubberlike materials derived from simple tensile data.

An explicit formulation is developed to obtain the stored energy function, based on the Valanis-Landel separable symmetric stored energy function. This formulation is applicable to any multiaxial stress state, from simple tensile data alone, for those cases in which the stored energy function is a separable function of the stretch ratios. By direct comparison, it is also shown that styrene butadiene rubber, at least over a specific range, follows this postulated separable form.

Peng, T. J.↗
NASA NTRS1972

Polymeric compositions and their method of manufacture

Filled polymer compositions are made by dissolving the polymer binder in a suitable sublimable solvent, mixing the filler material with the polymer and its solvent, freezing the resultant mixture, and subliming the frozen solvent from the mixture from which it is then removed. The remaining composition is suitable for conventional processing such as compression molding or extruding. A particular feature of the method of manufacture is pouring the mixed solution slowly in a continuous stream into a cryogenic bath wherein frozen particles of the mixture result. The frozen individual particles are then subjected to the sublimation.

Moser, B. G.↗