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Kyte, Frank T.

Publications and source records attributed to Kyte, Frank T..

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NASA NTRS2002

Were Ocean Impacts an Important Mechanism to Deliver Meteoritic Organic Matter to the Early Earth? Some Inferences from Eltanin

Several workers have addressed the potential for extraterrestrial delivery of volatles, including water and complex organic compounds, to the early Earth. For example, Chyba and Sagan (1992) argued that since impacts would destroy organic matter, most extraterrestrial organics must be delivered in the fine-fractions of interplanetary dust. More recent computer simulations (Pierazzo and Chyba, 1999), however, have shown that substantial amounts of amino acids may survive the impacts of large (km-sized) comets and that this may exceed the amounts derived from IDPs or Miller-Urey synthesis in the atmosphere. Once an ocean developed on the early Earth, impacts of small ,asteroids and comets into deep-ocean basins were potentially common and may have been the most likely events to deliver large amounts of organics. The deposits of the late Pliocene impact of the Eltanin asteroid into the Bellingshausen Sea provide the only record of a deep-ocean (approx. 5 km) impact that can be used to constrain models of these events. This impact was first discovered in 1981 as an Ir anomaly in sediment cores collected by the USNS Eltanin in 1965 (Kyte et al., 1981). In 1995, Polarstem expedition ANT XII/4 made the first geological survey of the suspected impact region. Three sediment cores sampled around the San Martin seamounts (approx. 57.5S, 91 W) contained well-preserved impact deposits that include disturbed ocean sediments and meteoritic impact ejecta (Gersonde et al., 1997). The latter is composed of shock- melted asteroidal materials and unmelted meteorites. In 2001, the FS Polarstem returned to the impact area during expedition ANT XVIII/5a. At least 16 cores were recovered that contain ejecta deposits. These cores and geophysical data from the expedition can be used to map the effects of the impact over a large region of the ocean floor.

Kyte, Frank T.↗
NASA NTRS2002

Oceanic Impact: Mechanisms and Environmental Perturbations

The contents include the following: Oceanic impacts-a growing field of fundamental geoscience. Shock metamorphism on the ocean floor (numerical simulations). Numerical modeling of impact-induced modifications of the deep-sea floor. Computer modelling of the water resurge at a marine impact: the Lockne crater, Sweden. Experimental investigation of the role of water in impact vaporization chemistry. Calcareous plankton stratigraphy around the Pliocene Eltanin asteroid impact area (SE Pacific): documentation and application for geological and paleoceanographic reconstruction. Composition of impact melt debris from the Eltanin impact strewn field, Bellingshausen Sea. Iridium concentrations and abundances of meteoritic ejecta from the Eltanin impact in sediment cores from Polarstern expedition ANT XII/4. Unmelted meteoritic debris collected from Eltanin ejecta in Polarstern cores from expedition ANT XII/4. Impact tsunami-Eltanin. Ancient impact structures on modern continental shelves: The Chesapeake Bay, Montagnais, and Toms Canyon craters, Atlantic margin of North America. The Mjolnir marine impact crater porosity anomaly. Kardla (Hiiu-maa Island, Estonia) - the buried and well-preserved Ordovician marine impact structure. Long-term effect of the Kardla crater (Hiiu-maa, Estonia) on Late Ordovician carbonate sedimentation. The middle Devonian Kaluga impact crater (Russia): new interpretation of marine setting.

Gersonde, Rainer↗
NASA NTRS2002

Iridium Concentrations and Abundances of Meteoritic Ejecta from the Eltanin Impact in Sediment Cores from Polarstern Expedition ANT XII/4

The abundances of meteoritic ejecta from the Eltanin asteroid impact have been examined in several sediment cores recovered by the FS Polarstern during expedition ANT XII/4 using elemental concentrations of iridium and weights of coarse ejecta debris. Three cores with well-preserved impact deposits, PS204-1, PS2708-1, and PS2709-1, each contain Ir and ejecta fluences similar to those found in USNS Eltanin core E13-4. Small Ir anomalies and traces of ejecta were found in cores PS2706-1 and PS2710-1, but since these cores lack well-defined deposits, these are considered to be reworked and not representative of the fallout. No evidence of ejecta was found in cores PS2802-1 and PS2705-1. These results confirm earlier speculation that the Eltanin impact resulted in deposits of ejecta with up to 1 gram/sq centimeter of depris over a wide area of the ocean floor. However, there are sill large uncertainties over the actual regional or global extent of this unique sediment deposit.

Kyte, Frank T.↗
NASA NTRS2002

Composition of Impact Melt Debris from the Eltanin Impact Strewn Field, Bellingshausen Sea

The impact of the km-sized Eltanin asteroid into the Bellingshausen Sea produced mm- to cm-sized vesicular impact melt-rock particles found in sediment cores across a large area of the ocean floor. These particles are composed mainly of olivine and glass with minor chromite and traces of NiFe-sulfides. Some particles have inclusions of unmelted mineral and rock fragments from the precursor asteroid. Although all samples of melt rock examined have experienced significant alteration since their deposition in the late Pliocene, a significant portion of these particles have interiors that remain pristine and can be used to estimate the bulk composition of the impact melt. The bulk composition of the melt-rock particles is similar to the composition of basaltic meteorites such as howardites or mesosiderite silicates, with a contribution from seawater salts and a siderophile-rich component. There is no evidence that the Eltanin impact melt contains a significant terrestrial silicate component that might have been incorporated by mixing of the projectile with oceanic crust. If terrestrial silicates were incorporated into the melt, then their contribution must be much less than 10 wt%. Since excess K, Na, and CI are not present in seawater proportions, uptake of these elements into the melt must have been greatest for K and least for CI, producing a K/CI ratio about 4 times that in seawater. After correcting for the seawater component, the bulk composition of the Eltanin impact melt provides the best estimate of the bulk composition of the Eltanin asteroid. Excess Fe in the impact melt, relative to that in howardites, must be from a significant metal phase in the parent asteroid. Although the estimated Fe:Ni:Ir ratios (8:1:4 x 10(exp -5)) are similar to those in mesosiderite metal nodules (10:1:6 x 10(exp -5), excess Co and Au by factors of about 2 and 10 times, respectively, imply a metal component distinct from that in typical mesosiderites. An alternative interpretation, that siderophiles have been highly fractionated from a mesosiderite source, would require loss of about 90% of the original metal from the impact melt and the sediments, and is unsupported by any observational data. More likely, the excess Fe in the melt rocks is 'representative of the amount of metal in the impacting asteroid, which is estimated to be 4+/- 1 wt%.

Kyte, Frank T.↗
NASA NTRS2002

Initial Results on the Meteoritic Component of new Sediment Cores Containing Deposits of the Eltanin Impact Event

The late Pliocene impact of the Eltanin asteroid is the only known asteroid impact in a deep- ocean (-5 km) basin . This was first discovered in 1981 as an Ir anomaly in sediment cores collected by the USNS Eltanin in 1965. In 1995, Polarstern expedition ANT XII/4 made the first geological survey of the suspected impact region. Three sediment cores sampled around the San Martin seamounts (approx. 57.5 S, 91 W) contained well-preserved impact deposits that include disturbed ocean sediments and meteoritic impact ejecta. The latter is composed of shock-melted asteroidal materials and unmelted meteorites. In 2001, the FS Polarstern returned to the impact area during expedition ANT XVIIU5a. At least 16 cores were recovered that contain ejecta deposits. These cores and geophysical data from the expedition can be used to map the effects of the impact over a region of about 80,000 square km. To date we have measured Ir concentrations in sediments from seven of the new cores and preliminary data should be available for a few more by the time of the meeting. Our initial interpretation of these data is that there is a region in the vicinity of the San Martin Seamounts comprising at least 20,000 square km in which the average amount of meteoritic material deposited was more than 1 g per square cm. This alone is enough material to support a 500 m asteroid. Beyond this is a region of about 60,000 square km, mostly to the north and west, where the amount of ejecta probably averages about 0.2 g per square cm. Another 400 km to the east, USNS Eltanin core E10-2 has about 0.05 g per square cm, so we know that ejecta probably occurs across more than a million square km of ocean floor. A key to future exploration of this impact is to find evidence of the ejecta at more sites distant from the seamounts. We currently have almost no data from regions to the west or south of the San Martin seamounts.

Kyte, Frank T.↗
NASA NTRS2001

KT Boundary Impact Debris from DSDP Site 577

The KT boundary at DSDP Site 577 (Shatsky Rise, western North Pacific) is in a calcareous nannofossil ooze. It is bioturbated so Ir and impact debris are smeared across less than 15 cm of core. An absence of sulfides and chalcophile enrichment and the presence of Mn-micronodules indicate that this boundary did not experience anoxic conditions typical of many other calcareous KT sites. Because of its shallow burial (109 m) ejecta is extremely well preserved and has been the subject of numerous studies. Three high-temperature minerals have been identified at this site. Clinopyroxene (cpx), found only at Site 577 may be precursor to diagenetic sanidine in some European sites. Magnesioferrite spinel has the highest Fe2O3/FeO of any locality and can have and trace inclusions of Ni-magnesiowustite, which is known at only one other site (Site 596). Other debris described includes shocked quartz grains less than 200 microns, hollow spherules possibly related to impact melt glasses found near Chicxulub, and irregular Ir-rich particles that may be derived directly from meteoritic materials. The latter may be related to the fossil meteorite found at Site 576, just 500 km to the east. A large-volume (approx. 10 cc) sample was taken to systematically characterize debris. The less than 60 microns fraction of the carbonate-free sediment contained 44 mg of impact debris. 2700 particles less than l00 microns were classified based on color, shape, and morphology. About 55% are generally light colored, composed mostly of clays, and typically lack magnesioferrite spinel. Less than half of these are quite spherical; many have irregular shapes, possibly from fragmentation. Hollow spherules with smooth shiny surfaces are only 2% of the total but many fragments in the 60 - 100 microns fraction suggest that they were more abundant and that some may have been quite large; 800 microns or more. Cpx-bearing spherules, easily identified by green crystals at the surface, constitute only 2.5% of the total. Three cpx spherules are dumbbells. The other 40% of the debris is a complex assemblage of dark-colored particles, most of which have magnesioferrite spinel. We have currently separated these into 6 groups based on color and morphology, but this hardly describes the diversity of this group. They range from smooth and spherical to rough and irregular in shape. Some have a planar cleavage, similar to some broken cosmic spherules. 220 particles were irradiated for trace element analysis, as groups and as individual particles. It appears that every spherule type as at least a few ng/g Ir. Several of the spinel-bearing particles have been identified with high Ir (200-1500 ng/g), Cr (2-5 mg/g), and Ni (2-10 mg/g), consistent with results. It is hoped that some of these will yield potential fragments of the KT bolide. Only five have been sectioned to date and they are characterized by high concentrations of spinel; two contained traces of magnesiowustite. This debris constitutes a complex assemblage of ejecta materials. The light-colored, spinel-free particles likely derive mainly from target materials. A significant fraction of these are probably alteration products of cpx-spherules. The dark-colored debris is more likely to have high siderophile concentrations, and thus a high extraterrestrial component. However, the majority don't. Most of the larger spinel-bearing spherules have modest Ir concentrations (5-30 ng/g).

Kyte, Frank T.↗
NASA NTRS2001

Exploration of the Eltanin Impact Area (Bellingshausen Sea): Expedition ANT XVIII5a

The impact of the Eltanin asteroid into the Bellingshausen Sea (2.15 Ma) is the only known impact in a deep-ocean (approx. 5 km) basin. On 26 March 2001, the FS Polarstern returned to the impact area during expedition ANT XVIII/5a. Over a period of 14 days, this region was explored by detailed bathymetric mapping, acoustic profiling of sediment deposits, and direct sampling with 18 piston cores and four gravity cores. Preliminary shipboard examination of microfossils showed that sixteen of the piston cores and three gravity cores contained sediments at least as old as the impact event and have a high probability of containing a record of the disturbances caused by the impact. During the expedition, portions of eleven piston cores were opened for preliminary examination of the impact deposits. Visual examination of cores and microscopic identification of suspect impact melt particles were were used to identify ejecta and X-ray radiographs of the opened core segments permitted analysis of sediment structures. Impact deposits were found in nine of the eleven opened cores, and a similar success rate is anticipated in the seven cores remaining to be opened. These preliminary observations indicate that the highest concentrations of meteoritic ejecta and the largest particle sizes appear to occur in the region north of the San Martin seamounts. Recovered debris includes cm-sized melt rocks and a 2.5 cm meteorite. This expedition has confirmed the presence of high concentrations of meteoritic ejecta across a region at least as large as 10(exp 5) sq km. Quantitative analyses of ejecta distribution within this region will require further study, but previous estimates of 1 km for the minimum diameter of the Eltanin asteroid, appear safe.

Gersonde, Rainer↗
NASA NTRS2001

Identification of Late Eocene Impact Deposits at ODP Site 1090

Anomalous concentrations of Ir have been found in upper Eocene sediments from Ocean Drilling Program (ODP) Hole 1090B. Clear and dark-colored spherules that are believed to be microtektites and clinopyroxene- bearing microkrystites, respectively, were found in the samples with highest Ir. The peak Ir concentration in Sample 177- 1090B-30X-5,105-106 cm (954 pg/g) and the net Ir fluence (14 ng/cm2) at this site are higher that at most other localities except for Caribbean site RC9-58. The Ir anomaly and impact debris are probably correlative with similar deposits found at ODP Site 689 on the Maude Rise and at other localities around the world.

Kyte, Frank T.↗
NASA NTRS1993

Impact mineralogy and chemistry of the cretaceous-tertiary boundary at DSDP site 576

We have identified the K/T boundary in pelagic clay sediments from cores at DSDP Site 576 in the western North Pacific. Detailed geochemical and trace mineralogical analyses of this boundary section are in progress and initial results indicate similarities and differences relative to the only other clay core investigated in detail; DSDP Site 596, a locality in the western South Pacific. Peak Ir concentrations of 13 ng/g in DSDP Hole 576B are virtually identical with those observed in the South Pacific, but in the North Pacific this peak is much narrower and the integrated Ir fluence of 85 ng cm(exp -2) is 4 times lower (320 in Hole 596). Of the 34 elements measured, only Ir and Cr were found to have anomalous concentrations in K/T boundary samples. Trace mineral residues were obtained by washing away clays and sequential chemical leaches (including HF) to remove typical hydrogenous and biogenous sediment components (e.g., zeolites and radiolarian opal). We attempted to quantitatively recover the entire trace mineral assemblage for grains greater than 30 micrometers in diameter. Our mineral residues were dominated by two phases: quartz and magnesioferrite spinel. Other non-opaque mineral grains we have positively identified were trace K-feldspar, plagioclase, corundum, and muscovite. Of these only K-feldspar exhibited planar deformation features (PDF). We have not found abundant plagioclase, as in the South Pacific suggesting that this phase was either not preserved in the North Pacific, or that in the south, it has a non-impact (i.e., volcanic) source. PDF in quartz were commonly obscured by secondary overgrowths on the surfaces of quartz grains, presumably from diagenetic reprecipitation of silica dissolved from opaline radiolarian tests that are common in these sediments. However, careful examination revealed that most grains had multiple sets of PDF. Of the 133 quartz grains greater than 30 micrometers analyzed, 62 percent showed evidence of shock. The largest shocked grain recovered to date had a maximum diameter of 160 micrometers, consistent with other sites in the Pacific.

Bostwick, Jennifer A.↗
NASA NTRS1992

Noble metal abundances in an early Archean impact deposit

Detailed analyses are reported on the concentrations of the noble metals Pd, Os, Ir, Pt, and Au in an early Archean spherule bed (S4) of probably impact origin from the lower Fig Tree Group, Barberton Greenstone Belt, South Africa. Compared to other sedimentary deposits of known or suspected impact origin, some noble metals are present in exceptionally high concentrations. Noble metal abundances are fractionated relative to abundances in chondrites with ratios of Os/Ir, Pt/Ir, Pd/Ir, and Au/Ir at only 80, 80, 41, and 2 percent of these values on CI chondrites. Although an extraterrestrial source is favored for the noble metal enrichment, the most plausible cause of the fractionation is by regional hydrothermal/metasomatic alteration.

Kyte, Frank T.↗
NASA NTRS1989

Geological and geochemical record of 3400-million-year-old terrestrial meteorite impacts

Beds of sand-sized spherules in the 3400-million-year-old Fig Tree Group, Barberton Greenstone belt, South Africa, formed by the fall of quenched liquid silicate droplets into a range of shallow- to deep-water depositional environments. The regional extent of the layers, their compositional complexity, and lack of included volcanic debris suggest that they are not products of volcanic activity. The layers are greatly enriched in iridium and other platinum group elements in roughly chondritic proportions. Geochemical modeling based on immobile element abundances suggests that the original average spherule composition can be approximated by a mixture of fractionated tholeiitic basalt, komatiite, and CI carbonaceous chondrite. The spherules are thought to be the products of large meteorite impacts on the Archean earth.

Lowe, Donald R.↗
NASA NTRS1988

Accretion rate of extraterrestrial matter: Iridium deposited over the last 70 million years

In order to quantify the accretion rate of extraterrestrial matter during the Cenozoic, Ir concentrations were measured in a continuous series of 450 samples across most of the length of piston core LL44-GPC3. LL44-GPC3 is a 25-meter-long, large-diameter piston core of abyssal clay from the central North Pacific. This core contains a nearly continuous record of sedimentation over the last 70 Ma, as this site migrated from a region near the Equator in the late Cretaceous to its present position north of Hawaii. The first-cut survey across the core is nearing completion, and all of the conclusions of the earlier study, in which was reported the concentrations of Ir, Co, and Sb across 9 meters of this core, remain unchanged. The only strongly enhanced Ir concentrations occur at the Cretaceous-Tertiary (K-T) boundary and outside the K-T boundary Ir correlates well with Co, a terrestrial element which is largely present in hydrogenous ferromanganese oxide precipitates from seawater. Concentrations of both elements appear to be inversely correlated with the sedimentation rate. Although the K-T Ir anomaly is unique in magnitude in this core, there are several small bumps in the Ir profile which may reflect smaller accretionary events. The most promising Ir enhancement was observed in a 30 cm section approximately 1 m below the K-T boundary. Preliminary data suggest deposition of an excess across this interval at a time estimate to be approximate 1 Ma before the K-T impact event, but there is insufficient evidence at present to prove that this reflects enhanced accretion of extraterrestrial matter. A detailed model is being prepared of the chemical record of sedimentation in this core using a combined database of 39 elements in approximately 450 samples across the Cenozoic. Preliminary working model indicates that the only sedimentary sources which contribute significantly to the Ir budget in this core are the hydrogenous precipitates and extraterrestrial particulates.

Kyte, Frank T.↗