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Kumar, Manoj

Publications and source records attributed to Kumar, Manoj.

Transport, correlations, and chaos in a classical disordered anharmonic chain

Here, we explore transport properties in a disordered nonlinear chain of classical harmonic oscillators, and thereby identify a regime exhibiting behavior analogous to that seen in quantum many-body-localized systems. Through extensive numerical simulations of this system connected at its ends to heat baths at different temperatures, we computed the heat current and the temperature profile in the nonequilibrium steady state as a function of system size $\textit{N}$, disorder strength Δ, and temperature $\textit{T}$. The conductivity $κ_N$, obtained for finite length ($\textit{N}$), saturates to a value $κ_∞$ > 0 in the large $\textit{N}$ limit, for all values of disorder strength Δ and temperature $\textit{T}$ > 0. We show evidence that for any Δ > 0 the conductivity goes to zero faster than any power of $\textit{T}$ in the ($\textit{T}$/Δ) → 0 limit, and find that the form $κ_∞$ ~ $e^{{–B|\text{ln}(CΔ/T)|}^{3}}$ fits our data. This form has earlier been suggested by a theory based on the dynamics of multioscillator chaotic islands. The finite-size effect can be $κ_N < κ_∞$ due to boundary resistance when the bulk conductivity is high (the weak disorder case), or $κ_N > κ_∞$ due to direct bath-to-bath coupling through bulk localized modes when the bulk is weakly conducting (the strong disorder case). We also present results on equilibrium dynamical correlation functions and on the role of chaos on transport properties. Finally, we explore the differences in the growth and propagation of chaos in the weak and strong chaos regimes by studying the classical version of the out-of-time-ordered commutator.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Electro-analytical method for the quantities evaluation of the silicon solar cell by DC and AC characterization technique

Highlights: • Exact electro-analytical method for evaluation of silicon solar cells. • DC and AC characterization technique to determine the performance limiting parameters of solar cells. • EIS is used to get an insight into the solar cells and parameter optimization. - Abstract: Mono and Poly- crystalline silicon (Si) based solar cell has proven to be the most efficient and matured technology till date. The present work reports an exact electro-analytical method for the evaluation of different performance parameters in the current voltage response of the Si solar cell by DC and AC characterization technique. The extracted solar cell parameters from DC and AC techniques were compared with each other under the proper limiting conditions of low and high forward bias. The DC and AC characterization are used to determine the bias dependence of ideality factor and series resistance, respectively. The current-voltage (J-V) characteristics is combined with the impedance spectroscopy (IS) measurements to reveal the various interfacial, resistive and recombination analysis of the silicon solar cell. Herein the experimentally obtained J-V characteristics under the illumination condition have been reconstructed by individually extracted parameters from DC and AC measurements. Moreover, the present mechanistic provides a simple tool for analysing the commercial Si solar cell with a wide applicability for other solar cells.

14 SOLAR ENERGY↗

Low cost and solution processible sandwiched CH3NH3PbI3-xClx based photodetector

Highlights: • High quality CH{sub 3}NH{sub 3}PbI{sub 3-x}Cl{sub x} thin film is synthesized using low temperature solution processible spin coating technique. • Perovskite based Metal-semiconductor-metal (MSM) photodetector is demonstrated without hole or electron transporting materials or noble metals. • Low cost & simple structured perovskite device exhibits good transient response, responsivity and detectivity. - Abstract: The CH{sub 3}NH{sub 3}PbI{sub 3-x}Cl{sub x} has been emerged as one of the most promising materials for the photodetector based applications. In recent years, many device structures consisting of hole transporting material, electron transporting material, conducting polymers and noble metals as contact electrodes have been investigated which escort to the increased cost and complexity in the fabrication process. Hence, it is essential to explore low cost, simple processed and high-performance photodetectors. The effect of applied external bias on photodetector has been examined in order to investigate performance. It is important to mention that because of the ion migration phenomenon taking place across the junction at higher bias, an unsaturated photocurrent has been observed during ON time of the photoresponse which may be scope of study for furtherance in low cost and highly stable photodetector. Responsivity and detectivity has been increased by 40 and 32 times at 1.2 V. Similarly, LDR is increased by 8 times.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Hydroxyacetone production from C 3 Criegee intermediates

Hydroxyacetone (CH 3 C(O)CH 2 OH) is observed as a stable end product from reactions of the (CH 3 ) 2 COO Criegee intermediate, acetone oxide, in a flow tube coupled with multiplexed photoionization mass spectrometer detection. In the experiment, the isomers at m/z = 74 are distinguished by their different photoionization spectra and reaction times. Hydroxyacetone is observed as a persistent signal at longer reaction times at a higher photoionization threshold of ca. 9.7 eV than Criegee intermediate and definitively identified by comparison with the known photoionization spectrum. Complementary electronic structure calculations reveal multiple possible reaction pathways for hydroxyacetone formation, including unimolecular isomerization via hydrogen atom transfer and –OH group migration as well as self-reaction of Criegee intermediates. Varying the concentration of Criegee intermediates suggests contributions from both unimolecular and self-reaction pathways to hydroxyacetone. As a result, the hydroxyacetone end product can provide an effective, stable marker for the production of transient Criegee intermediates in future studies of alkene ozonolysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Sample preparation methods for scanning electron microscopy of homogenized Al-Mg-Si billets: A comparative study

Characterization of Mg-Si precipitates is crucial for optimizing the homogenization heat treatment of Al-Mg-Si alloys. Although sample preparation is key for high quality scanning electron microscopy imaging, most common methods lead to dealloying of Mg-Si precipitates. In this article we systematically evaluate different sample preparation methods: mechanical polishing, etching with various reagents, and electropolishing using different electrolytes. We demonstrate that the use of a nitric acid and methanol electrolyte for electropolishing a homogenized Al-Mg-Si alloy prevents the dissolution of Mg-Si precipitates, resulting in micrographs of higher quality. This preparation method is investigated in depth and the obtained scanning electron microscopy images are compared with transmission electron micrographs: the shape and size of Mg-Si precipitates appear very similar in either method. The scanning electron micrographs allow proper identification and measurement of the Mg-Si phases including needles with lengths of roughly 200 nm. These needles are β″ precipitates as confirmed by high resolution transmission electron microscopy. - Highlights: •Secondary precipitation in homogenized 6xxx Al alloys is crucial for extrudability. •Existing sample preparation methods for SEM are improvable. •Electropolishing with nitric acid/methanol yields superior quality in SEM. •The obtained micrographs are compared to TEM micrographs.

36 MATERIALS SCIENCE↗

Mathematical foundations of the GraphBLAS

The GraphBLAS standard (GraphBlas.org) is being developed to bring the potential of matrix-based graph algorithms to the broadest possible audience. Mathematically, the GraphBLAS defines a core set of matrix-based graph operations that can be used to implement a wide class of graph algorithms in a wide range of programming environments. This study provides an introduction to the mathematics of the GraphBLAS. Graphs represent connections between vertices with edges. Matrices can represent a wide range of graphs using adjacency matrices or incidence matrices. Adjacency matrices are often easier to analyze while incidence matrices are often better for representing data. Fortunately, the two are easily connected by matrix multiplication. A key feature of matrix mathematics is that a very small number of matrix operations can be used to manipulate a very wide range of graphs. This composability of a small number of operations is the foundation of the GraphBLAS. A standard such as the GraphBLAS can only be effective if it has low performance overhead. Finally, performance measurements of prototype GraphBLAS implementations indicate that the overhead is low.

97 MATHEMATICS AND COMPUTING↗

Band-gap tuning and magnetic properties of heterovalent ions (Ba, Sr and Ca) substituted BiFeO{sub 3} nanoparticles

A Comparative study of heterovalent Ba, Sr and Ca ions substitution on the structural, vibrational, optical and magnetic properties of BiFeO{sub 3} nanoparticles was carried out. The distorted rhombohedral structure was confirmed from both X-ray diffraction and Raman spectroscopy techniques in pure BiFeO{sub 3} and Bi{sub 0.85}A{sub 0.15}FeO{sub 3} (A= Ba, Sr and Ca) samples. UV-Visible spectroscopy results show that the band-gap of BiFeO{sub 3} nanoparticles can be tuned by heterovalent ions substitution from 2.12 eV for BiFeO{sub 3} to 2.10, 2.06 and 2.03 eV for Ca, Sr and Ba substituted BiFeO{sub 3} nanoparticles respectively. The magnetic measurements indicate enhancement in magnetization for heterovalent A{sup 2+} substituted BiFeO{sub 3} samples and the magnetization increases with increase of ionic radius of the substituted ions.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Design and simulation of MEMS vector hydrophone with reduced cross section based meander beams

MEMS based vector hydrophone is being one of the key device in the underwater communications. In this paper, we presented a bio-inspired MEMS vector hydrophone. The hydrophone structure consists of a proof mass suspended by four meander type beams with reduced cross-section. Modal patterns of the structure were studied. First three modal frequencies of the hydrophone structure were found to be 420 Hz, 420 Hz and 1646 Hz respectively. The deflection and stress of the hydrophone is found have linear behavior in the 1 µPa – 1Pa pressure range.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effect of residual stress on modal patterns of MEMS vibratory gyroscope

Deep boron diffusion often induces residual stress in bulk micromachined MEMS structures, which may affect the MEMS devices operation. In this study, we studied the modal patterns of MEMS vibratory gyroscope under the residual stress (100 – 1000 MPa). Modal patterns and modal frequencies of the gyro are found to be dependent on the residual stress values. Without any residual stress, the modal frequencies drive and sense modeswere found to be 20.06 kHz and 20.36 kHz respectively. In presence of 450 MPa residual stress, the modal frequencies of the drive and sense modes were changed to 42.75 kHz and 43.07 kHz respectively.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Quasi-monoenergetic proton beam from a proton-layer embedded metal foil irradiated by an intense laser pulse

A target structure, ion-layer embedded foil (ILEF) is proposed for producing a quasi-monoenergetic proton beam by utilizing a bulk electrostatic field, which is generated by irradiating the target with an ultra-intense laser pulse, inside the plasma. Compared with the case of a single metal foil in which the proton layer is initially present on the surface, in the ILEF target, the proton layer is initially located inside a metal foil. A two-dimensional particle-in-cell (PIC) simulation shows that the target generates a proton beam with a narrow energy spread. With a laser intensity of 2 × 10{sup 19 }W/cm{sup 2}, a 22-MeV proton beam with an energy spread of 8% at the full-width-half-maximum (FWHM) is obtained when the proton layer is located at 0.4 μm inside the rear surface of a 2.4 μm-thick copper foil. When the proton layer moves toward the front side, a proton beam with a flat-top energy distribution ranging from 15 MeV to 35 MeV is obtained. Further, with a higher laser intensity of 10{sup 21 }W/cm{sup 2}, a proton beam with the maximum energy of 345 MeV and FWHM energy spread of 7.2% is obtained. The analysis of the PIC simulation with an aid of a fluid analysis shows that the spectrum is affected by the initial position of the proton layer, its initial spread during the formation of the sheath field, and the space charge effect.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Laser driven terahertz generation in hot plasma with step density profile

An analytical formalism of terahertz (THz) radiation generation by beating of two lasers in a hot plasma with step density profile is developed. The lasers propagate obliquely to plasma surface normal, and the nonlinearity arises through the ponderomotive force. The THz is emitted in the specular reflection direction, and the yield is enhanced due to coupling with the Langmuir wave when the plasma frequency is close to THz frequency. The power conversion efficiency maximizes at an optimum angle of incidence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Performance enhancement of GaN metal–semiconductor–metal ultraviolet photodetectors by insertion of ultrathin interfacial HfO{sub 2} layer

The authors demonstrate improved device performance of GaN metal–semiconductor–metal ultraviolet (UV) photodetectors (PDs) by ultrathin HfO{sub 2} (UT-HfO{sub 2}) layer on GaN. The UT-HfO{sub 2} interfacial layer is grown by atomic layer deposition. The dark current of the PDs with UT-HfO{sub 2} is significantly reduced by more than two orders of magnitude compared to those without HfO{sub 2} insertion. The photoresponsivity at 360 nm is as high as 1.42 A/W biased at 5 V. An excellent improvement in the performance of the devices is ascribed to allowed electron injection through UT-HfO{sub 2} on GaN interface under UV illumination, resulting in the photocurrent gain with fast response time.

42 ENGINEERING↗

Interaction of high intensity laser with non-uniform clusters and enhanced X-ray emission

Laser irradiated clusters with non-uniform density variation are shown to broaden surface plasmon resonance very significantly. As the clusters get heated and expand hydro-dynamically, the Bremsstrahlung X-ray emission yield passes through a maximum in time. The maximum yield decreases with increase in non-uniformity in the electron density inside the clusters. At higher laser intensity, the nonlinearity in laser cluster interaction may arise even prior to electron heating, via the relativistic mass variation and the nonlinear restoration force on electrons. For clusters with radius less than one tenth of the laser wavelength, the restoration force nonlinearity dominates.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Temperature measurement of axisymmetric flames under the influence of magnetic field using Talbot interferometry

Combustion process control is related with ecological improvement and the problem of energy efficiency; hence it has a wide interest at both economical and scientific levels. Application of a magnetic field is one of the most promising methods of combustion control. The presence of magnetic field induces the changes in flame behavior. The effect of uniform magnetic field developed by permanent magnet is studied by Talbot interferometry using circular gratings. Experimental results show a small decrease in flame temperature and increase in flame dimensions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Computationally efficient multibody simulations

Computationally efficient approaches to the solution of the dynamics of multibody systems are presented in this work. The computational efficiency is derived from both the algorithmic and implementational standpoint. Order(n) approaches provide a new formulation of the equations of motion eliminating the assembly and numerical inversion of a system mass matrix as required by conventional algorithms. Computational efficiency is also gained in the implementation phase by the symbolic processing and parallel implementation of these equations. Comparison of this algorithm with existing multibody simulation programs illustrates the increased computational efficiency.

Ramakrishnan, Jayant↗