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Kuhn, W. R.

Publications and source records attributed to Kuhn, W. R..

At least 19 records

A numerical simulation of climate changes during the obliquity cycle on Mars

A one-dimensional seasonal energy balance climate model of the Martian surface is developed. The model shows the importance of using short-period diurnal and seasonal variations of solar irradiance instead of yearly-averaged quantities. The roles of meridional heat transport and greenhouse warming are shown to be important. The possible existence of hysteresis cycles in the formation and sublimation of permanent deposits during the course of the obliquity cycle is demonstrated.

Francois, L. M.

Effect of the greenhouse gases (CO2, H2O, SO2) on Martian paleoclimate

There is general agreement that certain surface features on Mars are indicative of the presence of liquid water at various times in the geologic past. In particular, the valley networks are difficult to explain by a mechanism other than the flow of liquid water. It has been suggested in several studies that a thick CO2 atmosphere on Mars early in its history could have provided a greenhouse warming that would have allowed the flow of water either on the surface or just below the surface. However, this effect was examined with a detailed radiation model, and it was found that if reduced solar luminosity early in the history of the solar system is taken into account, even three bars of CO2 will not provide sufficient greeenhouse warming. The addition of water vapor and sulflur dioxide (both plausible gases that may have been emitted by Martian volcanoes) to the atmosphere also fail to warm the surface above 273 K for reduced solar luminosity conditions. The increase in temperature may be large enough, however, for the formation of these features by brines.

Postawko, S. E.

Trace gas effects on climate

The two primary objectives are to describe the new scientific challenges posed by the trace gas-climate problem and to summarize current strategies, and to make an assessment of the trace gas effects on troposphere-stratosphere temperature trends. Numerous reports on CO2-climate problems are examined with respect to climate modeling issues. The role of the oceans in governing the transient climate response to time varying CO2 concentrations is discussed.

Ramanathan, V.

Temperatures in a runaway greenhouse on the evolving Venus Implications for water loss

Some aspects of the temperature structure of a runaway greenhouse on Venus are examined using one-dimensional radiative transfer techniques. It is found that there generally is a region high in the atmosphere where condensation and cloud formation can occur, while deep in the atmosphere the gas is strongly unsaturated with respect to water vapor. The necessity of including clouds introduces considerably uncertainty into the calculation of surface temperatures. Under reasonable assumptions concerning the clouds, temperatures deep in the atmosphere are high enough to produce a plastic or even molten surface, which may significantly ease the problem of explaining the loss of oxygen.

Watson, A. J.

Effects of increased CO2 concentrations on surface temperature of the early earth

It is pointed out that enhanced levels of CO2 in the atmosphere could have provided the necessary warming to maintain the temperature above freezing. The processes that have been proposed for these larger amounts of CO2 are increased tectonic activity, a decrease in the solubility of CO2 in the oceans, rock weathering, and sediment deposition. It is shown here that large CO2 concentrations are necessary to maintain the early earth's surface temperature at approximately today's level. A thousand times the present atmospheric level of CO2 in the atmosphere would yield a temperature of 292 K, whereas a 100-fold increase in CO2 concentration would give a temperature of 284 K. The surface warming is highly dependent on the amount of water vapor and clouds, and knowledge of both of these during the early history of the earth is scant.

Kuhn, W. R.

Comparison of radiative-convective models with constant and pressure-dependent lapse rates

One of the most commonly used models for studying climatic processes is the convective adjustment radiation model. In current radiation models, stable temperature profiles are maintained with a convective adjustment in which the temperature lapse rate is set equal to a critical lapse rate whenever the computed lapse rates exceed the critical value. First introduced by Manabe and Strickler (1964), a variety of convective adjustment models are now in use. It is pointed out that on a global scale, moist adiabatic processes, and thus moist adiabatic lapse rates, approximate the atmospheric temperature profile. Comparisons of profiles from a one-dimensional-radiative-convective model have been made using the conventional 6.5 K/km as the critical lapse rate and the pressure-dependent moist adiabatic lapse rates. For a clear sky and a single effective cloud the surface temperatures are 1 to 3 K higher with the constant 6.5 K/km critical lapse rate.

Hummel, J. R.

Saturn - Tropospheric ammonia and nitrogen

Photochemical calculations based on recent data on the Saturn temperature structure and Lyman-alpha albedo indicate that detectable amounts of gaseous ammonia may exist between 20 and 35 km above the cloud tops. An instrument that might be able to observe this gas is the spectrometer on board the International Ultraviolet Explorer satellite. The calculations also yield a maximum nitrogen mixing ratio at the cloud tops between 1.8 x 10 to the -10th to 6 x 10 to the -8th by volume, depending upon the degree of supersaturation of ammonia and hydrazine. Even the lower limit could produce intense emissions if electrical discharges such as those observed on Jupiter by Voyager are also present on Saturn, or if high energy particles penetrate to the Saturnian troposphere.

Atreya, S. K.

The influence of ozone on Martian atmospheric temperature

Radiative equilibrium temperature calculations for Mars are presented, using the model of Kuhn et al. (1978). The maximum amount of ozone measured was 57 microns over the polar hood during winter. Results indicate that, although a minor constituent in the Martian atmosphere, ozone may play a significant role in controlling the rate of carbon dioxide deposition and thus the atmospheric pressure.

Kuhn, W. R.

Solar radiation incident on the Martian surface

Calculations indicate that the maximum daily solar radiation reaching the Martian surface is about 325 cal/sq cm during southern hemisphere summer at latitude of about 40 deg S. In the ultraviolet region of the spectrum, the radiation reaching the surface at wavelengths greater than 2800 A is within 10% of the radiation incident on the atmosphere. There is significant extinction of radiation in the spectral region near 2500 A in mid and high latitudes due to absorption of radiation by ozone; radiation reaching the surface may be reduced to one one-thousandth of that incident on the atmosphere during winter. Virtually no radiation of wavelengths less than 1900 A reaches the surface because of absorption by the large column abundance of carbon dioxide. Daily and latitudinal distributions of radiation are presented for wavelengths of 3000, 2500 and 2000 A.

Kuhn, W. R.

Ammonia photolysis and the greenhouse effect in the primordial atmosphere of the earth

Photochemical calculations indicate that in the prebiotic atmosphere of earth ammonia would have been irreversibly converted to N2 in less than 40 years if the ammonia surface mixing ratio were no more than 0.0001. However, if a continuous outgassing of ammonia were maintained, radiative-equilibrium calculations indicate that a surface mixing ratio of ammonia of 0.0001 or greater would provide a sufficient greenhouse effect to keep the surface temperature above freezing. With a 0.0001 mixing ratio of ammonia, 60% to 70% of the present-day solar luminosity would be adequate to maintain surface temperatures above freezing. A lower limit to the time constant for accumulation of an amount of nitrogen equivalent to the present day value is 10 my if the outgassing were such as to provide a continuous surface mixing ratio of ammonia of at least 0.00001.

Kuhn, W. R.

The response of selected terrestrial organisms to the Martian environment - A modeling study

An energy balance model has been developed to investigate how the Martian atmospheric environment could influence a community of photosynthetic microorganisms with properties similar to those of a cyanophyte (blue-green algal mat) and a lichen. Surface moisture and soil nutrients are assumed to be available. The model was developed to approximate equatorial equinox conditions and includes parameters for solar and thermal radiation, convective and conductive energy transport, and evaporative cooling. Calculations include the diurnal variation of organism temperature and transpiration and photosynthetic rates. The influences of different wind speeds and organism size and resistivity are also studied. The temperature of organisms in mats less than a few millimeters thick will not differ from the ground temperature by more than 10 K. Water loss is actually retarded at higher wind speeds, since the organism temperature is lowered, thus reducing the saturation vapor pressure. Typical photosynthetic rates lead to the production of 1 millionth to 100 billionths mole O2 per sq cm/day.

Kuhn, W. R.

Evolution of a nitrogen atmosphere on Titan

Photochemical calculations indicate that if NH3 outgassed from Titan it should have been converted to a dense N2 atmosphere during the lifetime of the satellite. A crucial step in the process involves a gas phase reaction of N2H4 with H. The most favorable conditions for this step would be the intermediate production of a CH4-H2 greenhouse capable of raising the gas temperature to 150 K. Subsequently about 20 bars of N2 could have evolved. The pressure-induced opacity of 20 bars of N2 should suffice to explain the recently measured 200 K surface temperature. Unlike the situation on Jupiter, NH3 is not recycled on Titan by reactions involving N2 or N2H4. This may explain the failure of recent attempts to detect NH3 in the upper atmosphere of Titan.

Atreya, S. K.

Radiative equilibrium temperatures in the stratosphere and mesosphere - A comparison for the stellar occultation and BUV ozone data

Recently published ozone densities in the equatorial stratosphere and mesosphere from satellite stellar occultation measurements are appreciably larger than previous independent midlatitude measurements and ozone densities predicted by photochemical theory. Radiative equilibrium temperature profiles with a stratosphere-mesosphere optimized model have been calculated for each of these ozone profiles; it is found that the stellar occultation studies cannot be discounted on energy balance grounds.

Kuhn, W. R.

Paleoatmospheric temperature structure

Radiative equilibrium and radiative convective temperature profiles for the earth's evolving atmosphere have been calculated. If the atmosphere evolved from one rich in carbon dioxide, and deficient in oxygen, to its present composition, the temperature structure showed considerable change. The models of 3 to 4 billion years ago display steadily decreasing temperatures with altitude, being 185 K at pressures associated with the present-day upper stratosphere. A lapse rate feature similar to the present-day tropopause is not indicated until about 1 billion years ago; but the stratospheric region is approximately 15 K colder than presently found at comparable pressures. Surface temperatures approximately 10 K warmer than at present existed until nearly 1 billion years ago. When the oxygen content exceeded roughly 0.1 times the present level, surface temperatures began to decrease. If biological processes are important to carbon dioxide - ozone variations, such as has been suggested during the Ice Ages, then estimates of surface temperature should include the effects of both gases.

Morss, D. A.

The distribution of ammonia and its photochemical products on Jupiter

Altitude profiles of ammonia and its photochemical products are generated in the light of measurements of the Jovian temperature structure, eddy transport coefficient, improved chemical scheme, and rate constants. Realistic limits are placed on the concentration of hydrazine which may participate in the recycling of ammonia on Jupiter. The maximum hydrazine-ice production rate is calculated to be about 1.3 mg/sq m per Jovian day. The distribution of nitrogen gas is presented with and without supersaturation of hydrazine. The nitrogen mixing ratio near the ammonia cloud top is estimated to be in the range between 10 to the -9th and 10 to the -11th power. An appreciable latitudinal variation in the ammonia concentration is expected.

Atreya, S. K.

The distribution of methylamine in the Jovian atmosphere

An estimate has been made of the methylamine concentration in the Jupiter atmosphere on the basis of the possible overlap between the regions of hydrocarbon and ammonia photochemistry. It was found that the maximum production rate of 6 x 10 to the 4th/cu cm/Jovian day occurs in the vicinity of 60 km above the ammonia cloud layer. The volumetric mixing ratio is 3 x 10 to the -11th, if the downward transport of methylamine equals the production rate.

Kuhn, W. R.