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Knight, R. D.

Publications and source records attributed to Knight, R. D..

The radiative lifetime of the 5S(0)2 metastable level of O(2+)

The radiative lifetime of the 5S(0)2 metastable level of O(2+) was measured as 1.22 + or - 0.08 ms at the 90 percent confidence level by observing the time dependence of the spontaneous emission from metastable ions created and stored in a cylindrical radio-frequency ion trap. The intersystem line emission 2s(2)2p(2) 3P - 2s2p(3) 5S(0) was observed at 1660.8 and 1666.2 A. Discrepancies between measured and calculated values indicate that certain calculated transition probabilities for intersystem lines may be less reliable than previously believed.

Johnson, B. C.

Measurements of transition probabilities for spin-changing lines of atomic ions used in diagnostics of astrophysical plasmas

The intensities of ultraviolet, spin-changing, 'intersystem' lines of low-Z atomic ions are frequently used in determinations of electron densities and temperatures in astrophysical plasmas as well as in measurements of element abundances in the interstellar gas. The transition probabilities (A-values) of these lines, which are about five orders of magnitude weaker than allowed lines, have not been measured heretofore and various calculations produce A-values for these lines that differ by as much as 50 percent A radio-frequency ion trap has been used for the first measurements of transition probabilities for intersystem lines seen in astronomical spectra. The measurement procedure is discussed and results for Si III, O III, N II, and C III are reviewed and compared to calculated values. Discrepancies exist; these indicate that some of the calculated A-values may be less reliable than has been beleived and that revisions to the electron densities determined for some astrophysical plasmas may be required.

Smith, P. L.

Radiative lifetime of the 5S2 metastable state of N/+/

The radiative lifetime of metastable N(+)(5S2) has been measured to be 4.2 + or - 0.6 msec, a value generally in agreement with theory, by direct monitoring of the spontaneous emission from approximately 1,000,000 ions stored in a radio-frequency ion trap. Additional measurements were made of the quenching rate coefficient (2.5 x 10 to the -9th cu cm/sec) and the production cross section (greater than or equal to 10 to the -18th sq cm) of N(+)(5S2) in N2. This work supports the interpretation of the 2145-A feature in the spectrum of aurorae as being due to N(+)(5S2) emission.

Knight, R. D.

Storage of ions from laser-produced plasmas

A method of storing large numbers of metal ions created in laser-produced plasmas is presented. The outer electrode of the electrostatic ion trap is designed to give a harmonic axial potential. The ions trapped by the technique included Be(+), C(+), Al(+), Fe(+), and Pb(+). The initial number of ions stored (2 x 10 to the 8th) appeared to be the trap maximum since increasing the laser power beyond 2-3 MW did not change the ion number. An initial rapid decay in the 30-50 msec range was generally followed by a long tail at the 10% level with times greater than 100 msec. The technique should be valuable for refractory elements which cannot be easily vaporized for electron impact ionization.

Knight, R. D.

Two-dimensional convolute integers for optical image data processing and surface fitting

An approach toward low-pass, high-pass and band-pass filtering is presented. Convolution coefficients possessing the filtering speed associated with a moving smoothing average without suffering a loss of resolution are discussed. Resolution was retained because the coefficients represented the equivalance of applying high order two-dimensional regression calculations to an image without considering the time-consuming summations associated with the usual normal equations. The smoothing (low-pass) and roughing (high-pass) aspects of the filters are a result of being derived from regression theory. The coefficients are universal integer valves completely described by filter size and surface order, and possess a number of symmetry properties. Double convolution lead to a single set of coefficients with an expanded mask which can yield band-pass filtering and the surface normal. For low order surfaces (0,1), the two-dimensional convolute integers were equivalent to a moving smoothing average.

Edwards, T. R.

A digital algorithm for spectral deconvolution with noise filtering and peak picking: NOFIPP-DECON

Noise-filtering, peak-picking deconvolution software incorporates multiple convoluted convolute integers and multiparameter optimization pattern search. The two theories are described and three aspects of the software package are discussed in detail. Noise-filtering deconvolution was applied to a number of experimental cases ranging from noisy, nondispersive X-ray analyzer data to very noisy photoelectric polarimeter data. Comparisons were made with published infrared data, and a man-machine interactive language has evolved for assisting in very difficult cases. A modified version of the program is being used for routine preprocessing of mass spectral and gas chromatographic data.

Edwards, T. R.

Fast digital noise filter capable of locating spectral peaks and shoulders

Experimental data frequently have a poor signal-to-noise ratio which one would like to enhance before analysis. With the data in digital form, this may be accomplished by means of a digital filter. A fast digital filter based upon the principle of least squares and using the techniques of convoluting integers is described. In addition to smoothing, this filter also is capable of accurately and simultaneously locating spectral peaks and shoulders. This technique has been adapted into a computer subroutine, and results of several test cases are shown, including mass spectral data and data from a proportional counter for the High Energy Astronomy Observatory.

Edwards, T. R.