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Kirchhoff, V. W. J. H.

Publications and source records attributed to Kirchhoff, V. W. J. H..

At least 19 records

Variability in Ozone in the Tropical Upper Troposphere-Lower Stratosphere from the 1998-2000 SHADOZ (Southern Hemisphere Additional Ozonesondes) Data

The first view of lower stratospheric and upper tropospheric structure from sondes is provided by a 3-year, 10-site record from the Southern Hemisphere ADditional OZonesondes (SHADOZ) network: . Observations covering 1998-2000 were made over Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Taking the UT/LS (upper troposphere- lower stratosphere) as the region between 12 and 17 km, we examine ozone variability in this region on a week-to-week and seasonal basis. The tropopause is lower in September-October-November than in March-April-May, when ozone is a minimum at most SHADOZ stations. A zonal wave-one pattern (referring to ozone mixing ratios greater over the Atlantic and adjacent continents than over the Pacific and eastern Indian Ocean), persists all year. The wave, predominantly in the troposphere and with variable magnitude, appears to be due to general circulation - with subsidence over the Atlantic and frequent deep convection over the Pacific and Indian Ocean. The variability of deep convection most prominent at Java, Fiji, Samoa and Natal - is explored in time-vs-altitude ozone curtains. Stratospheric incursions into the troposphere are most prominent in soundings at Irene and Reunion Island.

Thompson, A. M.↗

Tropical Tropospheric Ozone from SHADOZ (Southern Hemisphere ADditional Ozonesondes) Network: A Project for Satellite Research, Process Studies, Education

The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone. Prominent features are highly variable tropospheric ozone and a zonal wave-one pattern in total (and tropospheric) column ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole and convective mixing. Pollution transport from Africa and South America is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

Thompson, Anne M.↗

A Characterization of Vertical Ozonesonde Measurements at the Equatorial Locations of SHADOZ

Beginning in 1997 ozonesonde observations have been obtained from Equatorial locations participating in SHADOZ (Southern Hemisphere Additional Ozone) Project. Vertical ozone profiles are available from the western Pacific eastward to Kenya. Presently 10 stations provide vertical ECC ozonesonde measurements at least weekly. Statistical analysis shows the variation that occurs in the level of maximum ozone, the difference between integrated total ozone overburden from ECC and EP-TOMS observations, and with Dobson Spectrophotometers, when data are available.

Schmidlin, F. J.↗

Ozone climatology at Natal, Brazil, from in situ ozonesonde data

A large ozone-profile data set has been obtained through balloon ozonesonde soundings at Natal, Brazil, during 1978-1988. Maximum ozone concentrations occur during local spring (September-October), and minimum concentrations during late autumn (April-May); the seasonal variation is much larger in the troposphere than in the stratosphere. If there were no seasonal variation in the stratosphere, the seasonal variation observed in the troposphere alone would be sufficient to drive a total ozone column variation of about 5 percent. This is about half the size of the variation observed in the Natal Dobson spectrophotometer data.

Kirchhoff, V. W. J. H.↗

Ozone and aerosol distributions over the Amazon Basin during the wet season

Results are presented of O3 and aerosol measurements made in the lower troposphere from April 13 through May 10, 1987, as part of the wet season field experiment. Aircraft flights on the NASA Electra were conducted in the vicinity of Manaus, Brazil and between Manaus and the mouth of the Amazon River. Airborne O3 measurements were made in situ and with a lidar system pointed below the aircraft in nadir mode of operation. Data collection and results concerning the distributions of O3 and aerosols observed during the wet season from within the mixed layer to the middle troposphere over the central Amazon basin and between Manaus and Belem are discussed, and these observations are compared to the measurements obtained in the 1985 dry season. Ozone mixing ratio values are found to be lower than those of the 1985 dry season by 6-8 ppbv, indicating a strong removal process near the surface during wet season. It is also found that within the mixed layer O3 levels appeared to be lower over the forest compared to over the ocean.

Browell, Edward V.↗

Ozone measurements in Amazonia - Dry season versus wet season

Recent ozone measurements taken in the Amazonian rain forest environment during the wet season (April-May 1987) are described, revealling new aspects of the regional atmospheric chemistry. The measurements were part of the Amazon Boundary Layer Experiment (ABLE 2B) mission and utilized UV absorption as a measurement technique to obtain surface ozone data; 20 ozonesondes were launched in order to obtain vertical ozone profiles used to describe the upper troposphere and stratosphere. The major differences in comparison to a previous dry season experiment, which found ozone concentrations to be lower in the whole troposphere by nearly a factor of 2, are stressed.

Kirchhoff, V. W. J. H.↗

The variations of CO and O3 concentrations in a region subject to biomass burning

Carbon monoxide (CO) and ozone (O3) concentrations have been observed in the Brazilian Amazon region, at a site strongly affected by biomass burning (Cuiaba, 16 deg S, 58 deg W). Time variations are described for the first long-term program of studying the effect of biomass burning on O3 and CO over a complete seasonal cycle, including the seasonal maxima of 1987 and 1988. In order to obtain elements for comparison, an identical observational program was maintained at a site totally outside of the direct influence of biomass burning (Natal, 6 deg S, 35 deg W). The biomass burning contribution to the Cuiaba concentrations of CO and O3 is very large. Diurnal maxima concentrations exceeded 90 ppbv O3 in 1987 and 120 ppbv O3 in 1988, in September. For the wet season, the monthly average ozone concentration in March-April is about 10 ppbv. During the month of maxima, September, the O3 concentration average was 41 ppbv for 1987 and 71 ppbv for 1988. The CO concentrations are about 90 ppbv in the wet season. In September, 460 ppbv and 660 ppbv of CO were observed for 1987 and 1988, respectively. At Natal the seasonal variation is of the order of a factor of 2. During the wet season, the concentrations of CO and O3 at both stations are about the same.

Kirchhoff, V. W. J. H.↗

Ozone measurements in the troposphere of an Amazonian rain forest environment

Ozone concentration profiles from the ground to above the stratospheric peak were obtained in an equatorial rain forest environment near Manaus in the Amazon Basin between July and August of 1985. The peak ozone concentration (4.4 x 10 to the 22 molecules/cu cm) was found at 20 mbar (26.6 km). A major pollution (biomass-burning) event which occurred near the end of the experiment was responsible for large changes in ozone concentration.

Kirchhoff, V. W. J. H.↗

Tropospheric ozone and aerosol distributions across the Amazon Basin

As a part of the NASA Global Tropospheric Experiment to study the Amazon boundary layer, ozone and aerosol distributions were made measured in July-August 1985 by a NASA Electra aircraft on several long-range flights spanning different areas between Tabatinga and Belem, Brazil. Both positive and negative correlations were found in PBL between aerosol concentrations and O3 mixing ratios. The negative correlations result from the downward transport of relatively clean O3-rich air from the upper troposphere into PBL (which normally has higher aerosol loading and lower O3 concentrations than troposphere); positive correlations are found in biomass-burning plumes, where the aerosols are emitted into the air and O3 is photochemically produced. It was found that, in the dry season, a significant portion of the ozone over the rain forest is a result of biomass burning and that the distribution of photochemically produced O3 is strongly affected by synoptic-scale transport from large fires to the south/southeast.

Browell, E. V.↗

Seasonal variations of troposheric ozone at Natal, Brazil

An analysis of ozone measurements from Natal, Brazil (6 deg S, 35 W), with a focus on the seasonal behavior in the troposphere, is presented. The amplitude of seasonal cycle at Natal is much larger than at Panama (9 deg N), the only other tropical site for which similar data are available. Concentrations of ozone in the middle troposphere in the southern spring are unexpectedly high, 60-70 ppb, similar to values found at northern midlatitudes in summer, and larger by 20-30 ppb than values found at Panama and at southern midlatitudes. It is suggested that photochemical production of ozone associated with emissions of CO, hydrocarbons, and NO(x) from biomass burning may contribute significantly to the high values of ozone, but note that stratospheric intrusions could also play a role. The data available at present do not permit a definitive evaluation of the relative importance of these two sources of ozone. The data from Natal, in combination with recent aircraft and surface data, show that tropical ozone exhibits strong spatial and temporal inhomogeneities. The distribution of tropospheric ozone appears to be considerably more complex than the traditional view, which suggested a northern midlatitude maximum and north/-south hemispheric asymmetry. The seasonal cycle in the total column of ozone at Natal appears to mirror the behavior of the tropospheric contribution to the ozone column rather than the stratospheric contribution, and this may account for differences in the annual cycle of the total column at Natal versus other tropical locations.

Logan, J. A.↗

Equatorial ozone characteristics as measured at Natal (5.9 deg S, 35.2 deg W)

Ozone density profiles obtained through electrochemical concentration cell (ECC) sonde measurements at Natal were analyzed. Time variations, as expected, are small. Outstanding features of the data are tropospheric densities substantially higher than those measured at other stations, and also a total ozone content that is higher than the averages given by satellite measurements. Previously announced in STAR as A82-29798

Kirchhoff, V. W. J. H.↗

Equatorial ozone characteristics as measured at Natal (5.9 deg S, 35.2 deg W)

Ozone density profiles obtained through electrochemical concentration cell (ECC) sonde measurements at Natal were analyzed. Time variations, as expected, are small. Outstanding features of the data are tropospheric densities substantially higher than those measured at other stations, and also a total ozone content that is higher than the averages given by satellite measurements.

Kirchhoff, V. W. J. H.↗

The day-to-day variability in ionospheric electric fields and currents

The daily variations in ionospheric drift velocities are examined from incoherent scatter measurements at Millstone Hill. The data with summed Kp greater than 24 behave differently from those with low magnetic activity and basically follow the convection pattern but have large day-to-day variations. The influence of the magnetic conjugate point is discussed, and solar cycle variations are examined in conjunction with geomagnetic variations. Ionospheric currents calculated by using a semidiurnal neutral wind model are in good agreement with ground-based magnetograms for low magnetic activity, but the E region neutral wind model appears to be applicable only to this case.

Kirchhoff, V. W. J. H.↗

Calculation of conductivities and currents in the ionosphere

Formulas and procedures to calculate ionospheric conductivities are summarized. Ionospheric currents are calculated using a semidiurnal E-region neutral wind model and electric fields from measurements at Millstone Hill. The results agree well with ground based magnetogram records for magnetic quiet days.

Kirchhoff, V. W. J. H.↗

Electric fields in the ionosphere

F-region drift velocities, measured by incoherent-scatter radar were analyzed in terms of diurnal, seasonal, magnetic activity, and solar cycle effects. A comprehensive electric field model was developed that includes the effects of the E and F-region dynamos, magnetospheric sources, and ionospheric conductivities, for both the local and conjugate regions. The E-region dynamo dominates during the day but at night the F-region and convection are more important. This model provides much better agreement with observations of the F-region drifts than previous models. Results indicate that larger magnitudes occur at night, and that daily variation is dominated by the diurnal mode. Seasonal variations in conductivities and thermospheric winds indicate a reversal in direction in the early morning during winter from south to northward. On magnetic perturbed days and the drifts deviate rather strongly from the quiet days average, especially around 13 L.T. for the northward and 18 L.T. for the westward component.

Kirchhoff, V. W. J. H.↗

Comparison of high-latitude and mid-latitude ionospheric electric fields

Simultaneous measurements of the F region electric field by the incoherent scatter technique have been made at Chatanika, Alaska (65.1 deg N, 147.5 deg W), and Millstone Hill, Massachusetts (42.6 deg N, 71.5 deg W), on July 18-19 and Aug. 7-8, 1973. Good correlation was observed in the time variation of the perpendicular electric field at the two stations. Magnetic conditions for these days were relatively quiet with some variations evident from the high-latitude magnetograms and the Chatanika radar, but no distinct effect appeared on the mid-latitude magnetograms. Since magnetospheric electric fields are thought to be the source of high-latitude electric fields such as those observed at Chatanika, the good correlation in the perpendicular electric field for the two stations indicates that the magnetospheric originated electric fields have an appreciable effect down to at least L equals 3.2.

Carpenter, L. A.↗