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Kim, C. H.

Publications and source records attributed to Kim, C. H..

Laminar Soot Processes (Lsp) Experiment: Findings From Ground-Based Measurements

Processes of soot formation and oxidation must be understood in order to achieve reliable computational combustion calculations for nonpremixed (diffusion) flames involving hydrocarbon fuels. Motivated by this observation, the present investigation extended earlier work on soot formation and oxidation in laminar jet ethylene/air and methane/oxygen premixed and acetylene-nitrogen/air diffusion flames at atmospheric pressure in this laboratory, emphasizing soot surface growth and early soot surface oxidation in laminar diffusion flames fueled with a variety of hydrocarbons at pressures in the range 0.1 - 1.0 atm.

Kim, C. H.

Soot Surface Growth in Laminar Hydrocarbon/Air Diffusion Flames

The structure and soot surface growth properties of round laminar jet diffusion flames were studied experimentally. Measurements were made along the axes of ethylene-, propylene-propane- and acetylene-benzene-fueled flames burning in coflowing air at atmospheric pressure with the reactants at normal temperature. The measurements included soot structure, soot concentrations, soot temperatures, major gas species concentrations, some radial species (H, OH and 0) concentrations, and gas velocities. These measurements yielded the local flame properties that are thought to affect soot surface growth as well as local soot surface growth rates. When present results were combined with similar earlier observations of acetylene-fueled laminar jet diffusion flames, the results suggested that soot surface growth involved decomposition of the original fuel to form acetylene and H, which were the main reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. Thus, as the distance increased along the axes of the flames, soot formation (which was dominated by soot surface growth) began near the cool core of the flow once acetylene and H appeared together and ended near the flame sheet when acetylene disappeared. Species mainly responsible for soot oxidation - OH and 02 were present throughout the soot formation region so that soot surface growth and oxidation proceeded at the same time. Present measurements of soot surface growth rates (corrected for soot surface oxidation) in laminar jet diffusion flames were consistent with earlier measurements of soot surface growth rates in laminar premixed flames and exhibited good agreement with existing Hydrogen-Abstraction/Carbon-Addition (HACA) soot surface growth mechanisms in the literature with steric factors in these mechanisms having values on the order of unity, as anticipated.

El-Leathy, A. M.

Soot Surface Oxidation in Laminar Hydrocarbon/Air Diffusion Flames at Atmospheric Pressure

Soot surface oxidation was studied experimentally in laminar hydrocarbon/air diffusion flames at atmospheric pressure. Measurements were carried out along the axes of round fuel jets burning in coflowing dry air considering acetylene-nitrogen, ethylene, propyiene-nitrogen, propane and acetylene-benzene-nitrogen in the fuel stream. Measurements were limited to the initial stages of soot oxidation (carbon consumption less than 70%) where soot oxidation occurs at the surface of primary soot particles. The following properties were measured as a function of distance above the burner exit: soot concentrations by deconvoluted laser extinction, soot temperatures by deconvoluted multiline emission, soot structure by thermophoretic sampling and analysis using Transmission Electron Microscopy (TEM), concentrations of major stable gas species (N2, H2O, H2, O2, CO, CO2, CH4, C2H2, C2H6, C3H6, C3H8, and C6H6) by sampling and gas chromatography, concentrations of some radical species (H, OH, O) by deconvoluted Li/LiOH atomic absorption and flow velocities by laser velocimetry. For present test conditions, it was found that soot surface oxidation rates were not affected by fuel type, that direct rates of soot surface oxidation by O2 estimated from Nagle and Strickland-Constable (1962) were small compared to observed soot surface oxidation rates because soot surface oxidation was completed near the flame sheet where O2 concentrations were less than 3% by volume, and that soot surface oxidation rates were described by the OH soot surface oxidation mechanism with a collision efficiency of 0.14 and an uncertainty (95% confidence) of +/- 0.04 when allowing for direct soot surface oxidation by O2, which is in reasonably good agreement with earlier observations of soot surface oxidation rates in both premixed and diffusion flames at atmospheric pressure.

Xu, F.

Laminar Soot Processes (LSP)

This is the final report of a research program considering the structure and the soot surface reaction properties of laminar nonpremixed (diffusion) flames. The study was limited to ground-based measurements of buoyant laminar jet diffusion flames at pressures of 0.1-1.0 atm. The motivation for the research is that soot formation in flames is a major unresolved problem of combustion science that influences the pollutant emissions, durability and performance of power and propulsion systems, as well as the potential for developing computational combustion. The investigation was divided into two phases considering the structure of laminar soot-containing diffusion flames and the soot surface reaction properties (soot surface growth and oxidation) of these flames, in turn. The first phase of the research addressed flame and soot structure properties of buoyant laminar jet diffusion flames at various pressures. The measurements showed that H, OH and O radical concentrations were generally in superequilibrium concentrations at atmospheric pressure but tended toward subequilibrium concentrations as pressures decreased. The measurements indicated that the original fuel decomposed into more robust compounds at elevated temperatures, such as acetylene (unless the original fuel was acetylene) and H, which are the major reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. The second phase of the research addressed soot surface reaction properties, e.g., soot surface growth and surface oxidation. It was found that soot surface growth rates in both laminar premixed and diffusion flames were in good agreement, that these rates were relatively independent of fuel type, and that these rates could be correlated by the Hydrogen-Abstraction/Carbon-Addition (HACA) mechanisms of Colket and Hall (1994), Frenklach et al. (1990,1994), and Kazakov et al. (1995). It was also found that soot surface oxidation rates were relatively independent of fuel type, were not correlated with O2, CO2, H2O and O collision rates but were correlated with the collision rates of OH with a collision efficiency of 0.14, in agreement with the early measurements in premixed flames of Neoh et al. (1980), after allowing for oxidation by O2 via the classical rate expression of Nagle and Strickland-Constable (1962).

Dai, Z.

Soot Surface Growth in Laminar Hydrocarbon/Air Diffusion Flames

The structure and soot surface growth properties of round laminar jet diffusion flames were studied experimentally. Measurements were made along the axes of ethylene-, propylene-propane- and acetylene-benzene-fueled flames burning in coflowing air at atmospheric pressure with the reactants at normal temperature. The measurements included soot structure, soot concentrations, soot temperatures, major gas species concentrations, some radial species (H, OH and O) concentrations, and gas velocities. These measurements yielded the local flame properties that are thought to affect soot surface growth as well as local soot surface growth rates. When present results were combined with similar earlier observations of acetylene-fueled laminar jet diffusion flames, the results suggested that soot surface growth involved decomposition of the original fuel to form acetylene and H, which were the main reactants for soot surface growth, and that the main effect of the parent fuel on soot surface growth involved its yield of acetylene and H for present test conditions. Thus, as the distance increased along the axes of the flames, soot formation (which was dominated by soot surface growth) began near the cool core of the flow once acetylene and H appeared together and ended near the flame sheet when acetylene disappeared. Species mainly responsible for soot oxidation - OH and O2 were present throughout the soot formation region so that soot surface growth and oxidation proceeded at the same time. Present measurements of soot surface growth rates (corrected for soot surface oxidation) in laminar jet diffusion flames were consistent with earlier measurements of soot surface growth rates in laminar premixed flames and exhibited good agreement with existing Hydrogen-Abstraction/Carbon-Addition (HACA) soot surface growth mechanisms in the literature with steric factors in these mechanisms having values on the order of unity, as anticipated.

El-Leathy, A. M.

Test results for rotordynamic coefficients of anti-swirl self-injection seals

Test results are presented for rotordynamic coefficients and leakage for three annular seals which use anti-swirl self-injection concept to yield significant improvement in whirl frequency ratios as compared to smooth and damper seals. A new anti-swirl self-inection mechanism is achieved by deliberately machining self-injection holes inside the seal stator mechanism which is used to achieve effective reduction of the tangential flow which is considered as a prime cause of rotor instability in high performance turbomachinery. Test results show that the self-injection mechanism significantly improves whirl frequency ratios; however, the leakage performance degrades due to the introduction of the self-injection mechanism. Through a series of the test program, an optimum anti-swirl self-injection seal which uses a labyrinth stator surface with anti-axial flow injections is selected to obtain a significant improvement in the whirl frequency ratio as compared to a damper seal, while showing moderate leakage performance. Best whirl frequency ratio is achieved by an anti-swirl self-injection seal of 12 holes anti-swirl and 6 degree anti-leakage injection with a labyrinth surface configuration. When compared to a damper seal, the optimum configuration outperforms the whirl frequency ratio by a factor of 2.

Kim, C. H.

The effects of surface finish and grain size on the strength of sintered silicon carbide

The effects of surface treatment and microstructure, especially abnormal grain growth, on the strength of sintered SiC were studied. The surfaces of sintered SiC were treated with 400, 800 and 1200 grit diamond wheels. Grain growth was induced by increasing the sintering times at 2050 C. The beta to alpha transformation occurred during the sintering of beta-phase starting materials and was often accompanied by abnormal grain growth. The overall strength distributions were established using Weibull statistics. The strength of the sintered SiC is limited by extrinsic surface flaws in normal-sintered specimens. The finer the surface finish and grain size, the higher the strength. But the strength of abnormal sintering specimens is limited by the abnormally grown large tabular grains. The Weibull modulus increases with decreasing grain size and decreasing grit size for grinding.

You, Y. H.

Analysis and testing for rotordynamic coefficients of turbulent annular seals with different, directionally homogeneous surface-roughness treatment for rotor and stator elements

A theory is presented, based on a simple modification of Hirs' turbulent lubrication equations, to account for different but directionally-homogeneous surface roughness treatments for the rotor and stator of annular seals. The theoretical results agree with von Pragenau's predictions that a damper seal which uses a smooth rotor and a rough stator yields more net damping than a conventional seal which has the same roughness for both the rotor and stator. Experimental results for four stators confirm that properly-designed roughened stators yield higher net damping values and substantially less leakage than seals with smooth surfaces. The best seal from both damping and leakage viewpoints uses a round-hole-pattern stator. Initial results for this stator suggest that, within limits, seals can be designed to yield specified ratios of stiffness to damping.

Childs, D. W.

Input frequency requirements for identification through Liapunov methods

A theorem is derived which specifies a sufficient number of input frequencies to guarantee identification of an unknown noise free linear plant. Since all of the referenced work relates to sufficient conditions for nulling of the parameter error vector, it is to be expected that various conditions on the system to be identified will have been imposed. It was found that some of these conditions appear to be necessary while others do not. The main contribution is to provide a theorem which considers the effect of unknown parameters in the state equation upon the frequency requirements.

Kim, C. H.