Gas-liquid chromatographic resolution of several protein amino acid enantiomers on a packed column.
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Engineering topics
Publications and source records attributed to Khare, B. N..
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The exact calculation of scattering and absorption by various sub-micron sized silicate spheres is presented here, using accurately determined optical constants in the wavelength range from 50 to 0.21 microns. The extinction features near 10 and 20 microns for various samples are discussed. It is found that the ratio of peak extinction at 20 microns to that at 10 microns is constant for small particles up to 0.4-micron radius, but is less for particles of 1-micron radius. The ratio of maximum extinction in the ultraviolet to that at 10 microns decreases with increasing particle size.
Review of the results of some explicit experimental simulation of interstellar organic chemistry consisting in low-temperature high-vacuum UV irradiation of condensed simple gases known or suspected to be present in the interstellar medium. The results include the finding that acetonitrile may be present in the interstellar medium. The implication of this and other findings are discussed.
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UV photochemistry of lower Jovian clouds, using experimental simulation
Cystine synthesis in simulated primitive conditions by UV irradiation of methane, ethane, ammonia, water vapor and hydrogen sulfide in spherical vessel
Long wavelength UV photoproduction of amino acids on primitive earth, using hydrogen sulfide as photon acceptor
In a simulation of interstellar organic chemistry in dense interstellar clouds or on grain surfaces, formaldehyde, water vapor, ammonia and ethane are deposited on a quartz cold finger and ultraviolet-irradiated in high vacuum at 77K. The HCHO photolytic pathway which produces an aldehyde radical and a superthermal hydrogen atom initiates solid phase chain reactions leading to a range of new compounds, including methanol, ethanol, acetaldehyde, acetonitrile, acetone, methyl formate, and possibly formic acid. Higher nitriles are anticipated. Genetic relations among these interstellar organic molecules (e.g., the Cannizzaro and Tischenko reactions) must exist. Some of them, rather than being synthesized from smaller molecules, may be degradation products of larger organic molecules, such as hexamethylene tetramine, which are candidate consitituents of the interstellar grains. The experiments reported here may also be relevant to cometary chemistry.
Thermogravimetric analysis of goethite-rich sample of Mars type limonite, considering sorption process relation to Mars environment and polar caps
Amino acids produced by long UV irradiation of gas mixtures using hydrogen sulfide as initial photon acceptor, simulating prebiological earth conditions
Thermogravimetric study of physically and chemically bound water in ferric oxides of limonite with application to goethite on Mars
IR absorption properties of CO, HCl and sulfur dioxide measured for role in Venus greenhouse effect
Hydrogen bonding in deuterochloroform studied using IR spectra and dielectric constant methods, calculating equilibrium constants and heat of formation