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Keeling, Ralph F.

Publications and source records attributed to Keeling, Ralph F..

Global Carbon Budget 2016

Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere the global carbon budget is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates and consistency within and among components, alongside methodology and data limitations. CO2 emissions from fossil fuels and industry (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models. We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as +/- 1(sigma), reflecting the current capacity to characterize the annual estimates of each component of the global carbon budget. For the last decade available (2006-2015), EFF was 9.3+/-0.5 GtC/yr, ELUC 1.0+/-0.5 GtC/yr,GATM 4.5+/-0.1 GtC/yr, SOCEAN 2.6+/-0.5 GtC/yr, and SLAND 3.1+/-0.9 GtC/yr. For year 2015 alone, the growth in EFF was approximately zero and emissions remained at 9.9+/-0.5 GtC/yr, showing a slowdown in growth of these emissions compared to the average growth of 1.8/yr that took place during 2006-2015.Also, for 2015, ELUC was 1.3+/-0.5 GtC/yr, GATM was 6.3+/-0.2 GtC/yr, SOCEAN was 3.0+/-0.5 GtC/yr, and SLAND was 1.9+/-0.9 GtC/yr. GATM was higher in 2015 compared to the past decade (2006-2015), reflecting a smaller SLAND for that year. The global atmospheric CO2 concentration reached 399.4+/-0.1 ppm averaged over 2015. For 2016, preliminary data indicate the continuation of low growth in EFF with +0.2% (range of -1.0 to +1.8% ) based on national emissions projections for China and USA, and projections of gross domestic product corrected for recent changes in the carbon intensity of the economy for the rest of the world. In spite of the low growth of EFF in 2016, the growth rate in atmospheric CO2 concentration is expected to be relatively high because of the persistence of the smaller residual terrestrial sink (SLAND) in response to El Nino conditions of 2015-2016. From this projection of EFF and assumed constant ELUC for 2016, cumulative emissions of CO2 will reach 565+/-55 GtC (2075+/-205 GtCO2) for 1870-2016, about 75% from EFF and 25% from ELUC. This living data update documents changes in the methods and data sets used in this new carbon budget compared with previous publications of this data set.

Quéré, Corinne Le↗

Southern Ocean Seasonal Net Production from Satellite, Atmosphere, and Ocean Data Sets

A new climatology of monthly air-sea O2 flux was developed using the net air-sea heat flux as a template for spatial and temporal interpolation of sparse hydrographic data. The climatology improves upon the previous climatology of Najjar and Keeling in the Southern Hemisphere, where the heat-based approach helps to overcome limitations due to sparse data coverage. The climatology is used to make comparisons with productivity derived from CZCS images. The climatology is also used in support of an investigation of the plausible impact of recent global warming an oceanic O2 inventories.

Keeling, Ralph F.↗

Continuous Remote Measurements of Atmospheric O2 Concentrations in Relation to Interannual Variations in Biological Production and Carbon Cycling in the Oceans

We successfully initiated a program to obtain continuous time series of atmospheric O2 concentrations at a semi-remote coastal site, in Trinidad, California. The installation, which was completed in September 1999, consists of a commercially-available O2 and CO2 analyzers interfaced to a custom gas handling system and housed in a dedicated building at the Trinidad site. Ultimately, the data from this site are expected to provide constraints, complementing satellite data, on variations in ocean productivity and carbon exchange on annual and interannual time scales, in the context of human-induced changes in global climate and other perturbations. The existing time-series, of limited duration, have been used in support of studies of the O2/CO2 exchange from a wild fire (which fortuitously occurred nearby in October 1999) and to quantify air-sea N2O and O2 exchanges related to coastal upwelling events. More generally, the project demonstrates the feasibility of obtaining semi-continuous O2 time series at moderate cost from strategic locations globally.

Keeling, Ralph F.↗

On the Global Oxygen Anomaly and Air-Sea Flux

A new climatology of monthly air-sea oxygen fluxes throughout the ice-free surface global ocean is presented. The climatology is based on weighted linear least squares regressions using heat flux monthly anomalies for spatial and temporal interpolation of historical O2 data. The seasonal oceanic variations show that the tropical belt (20 S - 20 N) is characterized by relatively small air-sea fluxes when compared to the middle to high latitudes (40 deg - 70 deg). The largest and lowest seasonal fluxes occur during summer and winter in both hemispheres. By means of an atmospheric transport model we show that our climatology is in better agreement with the observed amplitude and phasing of the variations in atmospheric O2/N2 ratios because of seasonal air-sea exchanges at baseline stations in the Pacific Ocean than with previous air-sea O2 climatologies. Our study indicates that the component of the air-sea O2 flux that correlates with heat flux dominates the large-scale air-sea O2 exchange on seasonal timescales. The contribution of each major oceanic basin to the atmospheric observations is described. The seasonal net thermal (SNO(sub T)) and biological (SNO(sub B)) outgassing components of the flux are examined in relation to latitudinal bands, basin-wide, and hemispheric contributions. The Southern Hemisphere's SNO(sub B) (approximately 0.26 Pmol) and SNO(sub T) (approximately 0.29 Pmol) values are larger than the Northern Hemisphere's SNO(sub B) (approximately 0.15 Pmol) and SNO(sub T) (approximately 0.16 Pmol) values (1 Pmol = 10(exp 15) mol). We estimate a global extratropical carbon new production during the outgassing season of 3.7 Pg C (1 Pg = 10(exp 15) g), lower than previous estimates with air-sea O2 climatologies.

Garcia, Hernan E.↗

Development of a model of atmospheric oxygen variations to estimate terrestrial carbon storage and release

Two years of work has been completed towards the development of a model of atmospheric oxygen variations on seasonal to decadal timescales. During the first year we (1) constructed a preliminary monthly-mean climatology of surface ocean oxygen anomalies, (2) began modeling studies to assess the importance of short term variability on the monthly-mean oxygen flux, and (3) conducted preliminary simulations of the annual mean cycle of oxygen in the atmosphere. Most of the second year was devoted to improving the monthly mean climatology of oxygen in the surface ocean.

Najjar, Raymond G.↗