Engineering topics
Kaynak, B.
Publications and source records attributed to Kaynak, B..
Comparison of Weekly Cycle of NO2 Satellite Retrievals and NO(x) Emission Inventories for the Continental United States
Spatially resolved weekly NO2 variations are obtained from 2003 to 2005 Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) tropospheric NO2 columns for three different types of regions: urban, rural, and rural-point (rural with significant electricity generation unit (EGU) emissions). Regions are compared for magnitudes and weekly profiles. Rural regions do not show any weekly pattern, whereas urban areas show a distinct decrease on the weekends. Rural regions with EGUs show a slight decrease on Sundays. When compared with estimated mobile and stationary nitrogen oxides (NO(x)) emissions from the year 2004 for seven cities, the satellite data have greater variation during weekdays (Monday-Friday). Overall comparisons show that SCIAMACHY derived NO2 correlate well with estimated NO(x) emissions for urban and rural but less for rural-point regions.
The Effect of Lightning NOx Production on Surface Ozone in the Continental United States
Lightning NO(x) emissions calculated using the US National Lightning Detection Network data were found to account for 30% of the total NO(x) emissions for July August 2004, a period chosen both for having higher lightning NO(x) production and high ozone levels, thus maximizing the likelihood that such emissions could impact peak ozone levels. Including such emissions led to modest, but sometimes significant increases in simulated surface ozone when using the Community Multi-scale Air Quality Model (CMAQ). Three model simulations were performed, two with the addition of lightning NO(x) emissions, and one without. Domain-wide daily maximum 8-h ozone changes due to lightning NO(x) were less than 2 ppbv in 71 % of the cases with a maximum of 10 ppbv; whereas the difference in 1-h ozone was less than 2 ppbv in 77% of the cases with a maximum of 6 ppbv. Daily maximum 1-h and 8-h ozone for grids containing O3 monitoring stations changed slightly, with more than 43% of the cases differing less than 2 ppbv. The greatest differences were 42 ppbv for both 1-h and 8-h O3 , though these tended to be on days of lower ozone. Lightning impacts on the season-wide maximum 1-h and 8-h averaged ozone decreased starting from the 1 st to 4th highest values (an average of 4th highest, 8-h values is used for attainment demonstration in the US). Background ozone values from the y-intercept of O3 versus NO(z) curve were 42.2 and 43.9 ppbv for simulations without and with lightning emissions, respectively. Results from both simulations with lightning NO(x) suggest that while North American lightning production of NO(x) can lead to significant local impacts on a few occasions, they will have a relatively small impact on typical maximum levels and determination of Policy Relevant Background levels.